• Title/Summary/Keyword: Aluminum combustion

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Soot Formation and Oxidation of an Ethylene Laminar Diffusion Flame with Different Radiation Boundary Conditions (에틸렌 층류 확산화염의 복사경계조건에 따른 매연생성 및 산화특성)

  • Lee, Chun-Beom;Nam, Youn-Woo;Lee, Won-Nam;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.11-18
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    • 2003
  • The soot formation and oxidation characteristics with different radiation boundary conditions have been studied experimentally in a co-flow ethylene/air laminar diffusion flame. The boundary conditions are two cases, one is a fully refractive radiation boundary condition by a polished aluminum cylinder(AL) and the other is a fully absorbing radiation boundary condition by a black body cylinder(BB). The AL case compared with BB condition show the lower inception point, denser soot volume fraction, wider and longer annular soot area owing to the reabsorption of radiating energy.

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A Study on the Chemical Compositions of Powdered Sludge of Basalt on Jeju Island (건축용 내화 단열재 개발을 위한 제주도 현무암 석분 슬러지 화학조성에 대한 연구)

  • Kim, Min-Gyun;Kam, Sang-Kyu;Jeon, Yong-Han;Kim, Nam-Jin
    • Journal of the Korea Safety Management & Science
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    • v.21 no.4
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    • pp.45-49
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    • 2019
  • The basalt fiber is expected to become a trend for industrial fibers as they have better properties of heat-resistant, non-combustion, absorbent, soundproof, moistureproof, lightweight, corrosion resistant, and high strength properties. Also, the fiber is found to be non-toxic and harmless to the human body. Therefore, in this study, we analyzed the chemical and mineral compositions of powdered sludge of basalt produced at seven sites on Jeju Island for the development of fire resistance insulating material for a building. The results showed that the basalt stone sludge is made from only sodium calcium aluminum silicate and ferridioside components unlike the basalt rock.

Fabrication of $Ti(Al,\;O)-Al_2O_3$ Powder Feedstock for Thermal Spraying and Evaluation of the Composite Coating

  • Cao, Peng;Gabbitas, Brian;Zheng, Ling;Zhang, Deliang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.49-50
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    • 2006
  • [ $Ti(Al,\;O)-Al_2O_3$ ] composite powders were produced by high energy mechanical milling of a mixture of Al and $TiO_2$ powders followed by a combustion reaction. The powders were subsequently thermally sprayed on H13 steel substrates. Microstructural examination was conducted on the composite powders and thermally sprayed coatings, using X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The performance of the coatings was evaluated in terms of micro-hardness and thermal fatigue. The thermally sprayed coatings performed very well in the preliminary thermal fatigue tests and showed no wetting tendency to molten aluminum.

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The Deterioration of Lubricants in LPG Engine (LPG엔진에서의 윤활유 열화)

  • 류재곤;문우식
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.100-106
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    • 2000
  • Recently, the population of vehicles using LPG as fuel has been increasing due to relatively low fuel price and low tax. Although gasoline engine oils we usually used to lubricate LPG engines, some troubles such as oil thickening and TBN depletion were found in them under severe operating condition. In order to investigate the deterioration mechanism of lubricants in LPG engine, field trials were performed. The results from the field trials showed that the deterioration of oils in LPG engine is different from that in normal gasoline engine. LPG engine oil was deteriorated mainly through oxidation and nitration at high temperature rather than contamination of fuel combustion products.

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A Study on the Preparation of Halogen Free M-P Flame Retardant and Its Application to Composite Material (비할로겐 M-P 난연제 제조 및 복합재료 응용 연구)

  • Lee, Soon-Hong
    • Journal of the Korean Society of Safety
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    • v.24 no.6
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    • pp.63-71
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    • 2009
  • In order to improve flame retardancy, the halogen free organic melamine phosphate(M-P) flame retardant was synthesized from melamine and phosphoric acid by the reaction of precipitation. The ignition test was carried out preparing hybrid flame retardant compound($H_bFRC$) consisting of organic M-P and inorganic Mg$(OH)_2$ as a flame retardant in the polyolefin resins. The flame retardancy and mechanical properties of flame retardant aluminum composite panel($H_bFRC$-ACP) were performed to investigate the possibility of the composite material, which was contained M-P, as a inner core for $H_bFRC$-ACP. For this study, the results of ignition test indicate that a char formation and drip suppressing effect, and combustion time reduced as the content of M-P increased. The limited oxygen index(LOI) values were measured 17.4vol% and 31.5vol% for LDPE only and $H_bFRC$-3(M-P content: 15wt%), respectively. And it was verified that the $H_bFRC$-3 was needed more oxygen quantity with the increase of M-P content when it combustion. Also, the results from thermogravimetric analysis were observed endothermic peak at $350^{\circ}C$ and $550^{\circ}C$, it was confirmed predominant thermal stability though the wide temperature range by the mixture of M-P and Mg$(OH)_2$. The LDPE-ACP (using only LDPE as a inner core), $35.13kW/m^2$ of heat release rate(HRR) and 13.43MJ/m2 of total heat release(THR) were measured while the $H_bFRC$-ACP, $10.44kW/m^2$ of HRR and 1.84MJ/m2 of THR were measured by results of cone calorimeter test. In case of $H_bFRC$-ACP, the average gas emission amount of CO and $CO_2$ could be decreased down to 25% and 20%, respectively, in comparison with LDPE-ACP. The mechanical properties such as tensile strength, bending strength and adhesion strength of $H_bFRC$-ACP were revealed slightly high values $54N/mm^2$, $152N/mm^2$ and 120N/25mm, respectively, compared with LDPE-ACP. It was confirmed that flame retardancy was improved with the synergy effect because of char formation by M-P and hydrolysis by Mg$(OH)_2$. The result of this study suggest that $H_bFRC$ can be applied for an adequate halogen free flame retardant composite material as a inner core for ACP.

A Study on Perpendicular Flame Retardant Characteristic Improvement of Halogen-free Flame Retardant Compounds by Nanoclay Addition (나노클레이 첨가에 따른 할로겐프리 난연컴파운드의 수직난연 특성 향상에 관한 연구)

  • Hwang, Chan-Yun;Yang, Jong-Seok;Seong, Baeg-Yong;Kim, Ji-Yeon;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.51-56
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    • 2015
  • The object of this study is to obtain the optimum mix proportion of halogen free compound with flame resistance and, for the purpose, thermal/electrical characteristics test are conducted using compatibilizing agents, flame resistance agents, hydroxide aluminum, sunscreen, antioxidant and silicon oil on the base resin of linear low density polyethylene (LLDPE), Ethylene vinyl acetate copolymer (EVA). Existing compound method accompanies many requirements to be satisfied including a lot of addition of flame resistance agents, prohibition of impact on mixing capability with base and property and etc. In this study, different from the existing method, the optimum mix proportion is determined and experimented by adding nano clay. Oxygen index test shows no difference between specimens while T-6, T-9 shows oxygen index of 29[%] and 26[%], respectively. This is concluded that hydroxide aluminum, which is a flame resistance agent, leads low oxygen index. From UL94-V vertical flame resistance test, the combustion behavior is determined as V-0, Fail based on UL94-V decision criteria. Viscometry shows low measurements in specimens with separate addition of compatibilizing agents or nano clay. Volume resistivity test shows low measurement mainly in specimens without compatibilizing agents. Therefore, with the flame resistance compound shows better performance for thermal/electrical property and the optimum mix proportion are achieved among many existing materials.

A Study on the Application of Phase Change Material for Electric Vehicle Battery Thermal Management System using Dymola (전기자동차 배터리팩 열관리시스템에서 상변화물질 적용에 관한 고찰)

  • Choi, Chulyoung;Choi, Woongchul
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.12
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    • pp.1889-1894
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    • 2017
  • Global automobile manufacturers are developing electric vehicles (EVs) to eliminate the pollutant emissions from internal combustion vehicles and to minimize fossil fuel consumptions for the future generations. However, EVs have a disadvantage of shorter traveling distance than that of conventional vehicles. To answer this shortfall, more batteries are installed in the EV to satisfy the consumer expectation for the driving range. However, as the energy capacity of the battery mounted in the EV increases, the amount of heat generated by each cell also increases. Naturally, a better battery thermal management system (BTMS) is required to control the temperature of the cells efficiently because the appropriate thermal environment of the cells greatly affects the power output from the battery pack. Typically, the BTMS is divided into an active and a passive system depending on the energy usage of the thermal management system. Heat exchange materials usually include gas and liquid, semiconductor devices and phase change material (PCM). In this study, an application of PCM for a BTMS was investigated to maintain an optimal battery operating temperature range by utilizing characteristics of a PCM, which can accumulate large amounts of latent heat. The system was modeled using Dymola from Dassault Systems, a multi-physics simulation tool. In order to compare the relative performance, the BTMS with the PCM and without the PCM were modeled and the same battery charge/discharge scenarios were simulated. Number of analysis were conducted to compare the battery cooling performance between the model with the aluminum case and PCM and the model with the aluminum case only.

The Effct of SHS Reaction Heat Control on the Microstructure of TiAl (고온 자전 합성시 반응열 제어가 TiAl 미세 조직에 미치는 영향에 관한 연구)

  • Mun, Jong-Tae;Yeom, Jong-Taek;Sin, Bong-Mun;Kim, Yong-Seok;Lee, Yong-Ho
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.869-879
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    • 1995
  • TiAi intermetallic compound has been extensively studied for possible high temperature structural applications because of its high specific strength at high temperature, high creep resistance, and good oxidation resistance at elevated temperatures. In addition to its good properties, an economic manufacturing routes should be developed for this material to be used more extensively. One of the promising route in manufacturing TiAl intermetallics is the Self-propagating High-temperature Synthesis (SHS) method. Thus in this study, an attempt was made to study the mechanism of the SHS process in TiAl synthesis. The composition of the sample was Ti-(45, 50, 53)at% Al and the microstuctures of the products were analyzed using optical microscope and scanning electron microscope. When the phases formed at the main SHS reaction of whicyh combustion temperature is higher than the melting temperature of aluminum were identified as TiAl and Ti$_3$Al ; Ti$_3$Al cores surrounded by TiAl phase. In order to increase the combustion temperature, carbon was added 5 and 10at.%. When the carbon content was 10at.%, the heat of the reaction was large enough to melt the phase formed and that is consistent with the theoretical calculation results of the adiabatic temperature. The combution temperatue, which was measured by a computer data acquisition system, increased with the carbon content. The phases formed from the reaction involving the carbon added were indentified as TiAl and Ti$_2$AlC using XRD. The vickers hardness of the reaction product increased with the carbon content.

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Photoluminescence Characteristics of $Y_3Al_5O_{12}:Ce^{3+},Eu^{3+}$ Phosphors by $Eu^{3+}$ ions ($Eu^{3+}$ 농도에 따른 $Y_3Al_5O_{12}:Ce^{3+},Eu^{3+}$ 형광체의 광학적 특성)

  • Kwak, Hyun-Ho;Kim, Se-Jun;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.441-442
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    • 2008
  • For this study, Yttrium aluminum garnet (YAG) particles co-doped with $Ce^{3+}$ and $Eu^{3+}$ were prepared via the combustion process using the 1:1 ratio of metal ions to reagents. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various YAG peaks, with the (420) main peak, appeared at all Eu concentrationin XRD patterns. The YAG phase crystallized with results that are in good agreement with the JCPDS diffraction file 33-0040. The SEM image showed that the resulting YAG:Ce,Eu powders had uniform sizes and good homogeneity. The grain size was about 50nm. The photoluminescence spectra of the YAG:Ce,Eu nanoparticles were investigated to determine the energy level of electron transition related to luminescence processes. It was composed a broad band of $Ce^{3+}$ activator into the weak line peak of $Eu^{3+}$ in YAG host. The PL intensity of $Ce^{3+}$ has the wavelengths of 480-650 nm and The PL intensity of $Eu^{3+}$ has main peak at 590nm.

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Influence of Charging Condition of Al-dross on Maximum Concentration of Al in Molten Steel : Fundamental study for improvement of chemical energy in EAF process (용강 중 Al 최대 농도에 대한 Al 드로스 장입 조건의 영향: 전기로 공정 내 화학 에너지 향상을 위한 기반 연구)

  • Kim, Gyu-Wan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.4
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    • pp.44-50
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    • 2019
  • In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.