• Title/Summary/Keyword: Aluminum Sulfate

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Studies on ammonium adsorption by and desorption from various soils (I) -Langmuir adsorption isotherm of ammonium (토양별(土壤別) 암모늄의 흡착(吸着) 및 탈착(脫着)에 관(關)한 연구(硏究) (I) -암모늄의 Langmuir 등온흡착(等溫吸着))

  • Shim, Sang-Chil;Kim, Kwang-Rai;Kim, Moo-Sung;Park, Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.10 no.1
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    • pp.1-6
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    • 1977
  • Fifteen soils including volcanic ash, acid sulfate and degraded saline soils were investigated for Languir adsorption isotherm of ammonium using $NH_4H_2PO_4$. The results are as follows. Languir adsorption maxima of ammonium (LAMA) ranged from 2.4me/100g soil to 12.3 and the average was 5.3. Initial concentration of 30 to 60 or 40 to 80 ppm(as N) appears to be suitable for LAMA measurement. There were two LAMA in some soils. Difference between adsorption constants (bonding energy) was mostly greater than that between LAMA. LAMA ranged from 9.4% to 72% of cation exchange capacity and average was 47%. It did not show any clear tendency with CEC, pH, organic matter content, base saturation percent, P, K, Ca, Mg, Na and Si. Except volcanic ash soils which were grouped into two groups according to ammonium adsorption LAMA was significantly (r=0.951 at 1%) correlated with adsorption at 200ppm. This single concentration seems suitable for LAMA measurement. Probable mechanism of ammonium adsorption was discussed, in which the associated anions were combined with iron and aluminum and then ammonium was bound to phosphorus. Applicability of Langmuir adsorption isotherm model to the soils under field condition was also discussed.

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Application of Poultry Industry Using Methods of Environmental Management - A Study on Decreasing Soluble Metals from Poultry Litter with Chemical Additives - (환경경영 기법을 이용한 가금산업에 적용(I) - 화학제재를 첨가한 깔짚으로부터 수용성 중금속 저감에 관한 연구를 중심으로 -)

  • Choi, In-Hag;Choi, Sun;Choi, Jung-Hoon
    • Journal of Environmental Science International
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    • v.18 no.12
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    • pp.1437-1442
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    • 2009
  • Recent studies have shown that alum addition to litter results in many environmental and economic advantages, such as reductions in metal runoff, lower ammonia emission and improved poultry performance. However, no research has been conducted to evaluate the effects of different types of alum on soluble metals in poultry litter. The objective of this study was conducted to investigate changes in soluble metal from poultry litter with different types of aluminum sulfate (alum) under laboratory condition. The treatments used in this study, which were mixed in the upper 1 cm of litter or sprayed onto the litter surface, were 4 g alum, 8 g alum, 8.66 g liquid alum, 17.3 g liquid alum, 11.2 g A7 (high acid alum), and 22.4 g A7 (high acid alum)/100 g litter. Applying different types of alum to poultry litter reduced (P<0.05) concentrations of soluble Fe (9 to 54%), Cu (9 to 49%) and Zn (11 to 40%), relative to untreated litter, whereas it increased Ca and Mg (P<0.05). Mean soluble Fe and Cu levels in poultry litter from different types of alum decreased in the order: 22.4 g A7 (54% and 49%) > 17.3 g liquid alum (48% and 42%) > 8 g alum (48% and 31%) > 4 g alum (28% and 10%) > 8.6 g liquid alum (10% and 9%) > 11.2 g A7 (8.6% and 9%). Additionally, the high reduction in soluble Zn concentration was 4 g alum (40%), followed by 8 g alum (26%), 22.4 g A7 (25%), 17.3 g liquid alum (23%), 8.66 g liquid alum (18%), and 11.2 g A7 (11%), respectively. In conclusion, the current studies suggest that treating poultry litter with different types of alum can be applied to reduce soluble metal (Fe, Cu, and Zn) and to develop a production to merchandise for poultry litter that would result in reduction in pollutants from these materials. Furthermore, in order to improve environmental management in the poultry industry, the use of alum, liquid alum and high acid alum all should be provided a valid means of reducing negative environmental impact.

A Study on Traditional Kimchi made with Heating (가열하여 담그는 전통 김치)

  • Ann, Yong-Geun;Moon, Young-Ja
    • The Korean Journal of Food And Nutrition
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    • v.28 no.6
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    • pp.1033-1044
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    • 2015
  • During the Joseon period, kimchi was mostly made by heating the ingredients. Since salt was pricey at the time, in order to save salt and time, people used a method that involved destroying the cell wall by heating the vegetables. However, this method is no longer passed down. Thus, in this paper, we re-discovered how kimchi was made through heating while analyzing the recipes for kimchi during the Joseon period. There were 27 kinds of kimchi made through blanching. To keep the vegetables from becoming soggy, 2 kinds of kimchi were made by putting the ingredients in potassium aluminum sulfate water and 3 kinds were made through blanching the ingredients in limewater. There were 7 kinds of kimchi made by heating in vinegar, 5 kinds by boiling the ingredients, 6 kinds by stir-frying the ingredients, 2 kinds by stir-frying the ingredients with salt, and 3 kinds by steaming the ingredients. In order to eradicate unwanted germs, leaving only Lactobacillus, 25 kinds of kimchi were made by draining the boiled mixture. A total of 17 kinds of kimchi were made by heating the kimchi pot with compost including that of horses. For elders with weak teeth and poor digestion, 7 kinds of kimchi were made after heating, including 3 kinds of sukkkakdugi (cubed radish kimchi made with boiled radish). 3 kinds of chaekimchi (julienned kimchi) and 3 kinds of chaekkakdugi (kimchi with julienned radish) for elders existed as well.

The Effects of Gamchomahwang-tang extract According to the ratio of 2 compounds on the Ovalbumin-Induced Allergic Asthma in Mice (甘草麻黃湯 추출물의 배합 비율에 따른 투여가 Ovalbumin으로 유발된 천식 생쥐에 미치는 영향)

  • Jo, So-Hyun;Jo, Eun-Hee;Park, Min-Cheol
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.28 no.4
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    • pp.74-91
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    • 2015
  • Background and Objective : Asthma is a chronic inflammatory disease at the mucosa and is associated with excess production of Th2 cytokine and eosinophil accumulation in lung.Gamchomahwang-tangextract(GME) is one of the well known prescription used in oriental medicine for treating asthma. This study was designed to compare the anti-asthmatic effect of GME according to the ratio of 2 compounds.Methods : To examine the effects of GME on asthma, mice were sensitized with 100 ㎍ of OVA and 1 ㎎ of aluminum potassium sulfate(Alum; Sigma) intraperitoneally on day 1 and 15. From day 22, mice were challenged on 3 consecutive days with 5% OVA. The anti-asthmatic effects of GME were evaluated by enhanced pause(Penh), bronchoalveolar lavage fluids (BALF), inflammatory cytokine production and genes expression, serum IgE production. and histological change in lung tissue. GMEⅠ consists of ES and GU in the proportion 2:1(300 ㎎/㎏ group), GMEⅡ consist of ES and GU in the proprtion 4:1(300 ㎎/㎏ group).Results : GMEⅠ,Ⅱ generally inhibited lung inflammation, inflammatory cells infiltration and cytokine production and gene expression such as IL-4, IL-5 and IL-13 in BALF and serum IgE level. GMEⅡ significantly reduced the cytokine production and gene expression such as IL-4, IL-5 and IL-13 in BALF and GMEⅠ decreased cytokine production of IL-4, IL-13 in BALF and gene expression of IL-4, IL-5 in Lung. GMEⅡ potently inhibited the development of Penh and also reduced the number of eosinophil during OVA-induced AHR(airway hyper-reactivity). Overall the results show that GMEⅡ has more effect on inhibiting production, gene expression of cytokine, serum IgE level and development of Penh than GMEⅠ. Consequently, GMEⅡ might be more effective than GMEⅠ at inhibiting allergic asthma on the OVA-induced mice model.Conclusion : These results indicate that GME has a deep inhibitory effects on airway inflammation and hyperresponsiveness in mice model of asthma and that suppression of IL-4, IL-5, IL-13 expression and decrease of IL-4, IL-5, IL-13 production in BALF might contribute this effect. Hence, the results indicate that GME might be useful herbal medicine of allergic asthma. As a result, GMEⅡ mght be superior to GMEⅠ in the aspect of anti-asthmatic effect on the OVA-induced mice model.

Urban Stormwater Runoff Treatment by the RFS (RFS를 이용한 도시유출수처리)

  • Lee, Jun-Ho;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.159-167
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    • 2000
  • In recent years, combined and separated sewer overflows (CSOs, SSOs) have been recognized as a significant pollution problem. To solve this problem a series of experiments were performed in a small scale Rapid Floc Settler (RFS) device to determine its ability in removing micro particles and dissolved materials from polluted waters. The RFS device is a compact physico-chemical wasterwater treatment system. Polyacrylamide (PAM) is used as a coagulant for treating stormwater in the RFS. The results of Jar test showed that PAM could be an excellent coagulant as compared with aluminum sulfate. and ferric chloride. In several experimental conditions, the influence of different variation parameters was tested to measure the efficiency of the RFS. Tests have been carried out with typical CSOs concentrations (50~1.000mg SS/L). The treatment efficiency with regard to SS and COD, which can be obtained at an overflow rate of $130m^3/m^2/day$, are 90% and 80%, respectively. Comparing other sedimentation technologies with RFS, the overflows rate of RFS is ten times faster. The distribution of particle size and number were analyzed. The RFS is suitable for the treatment of CSOs and also the removal of settleable and dissolved materials in urban stormwater runoff.

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Effects of Addition of Three Different Chemicals to Litter on Broiler Performance, Ammonia and Carbon Dioxide Production in Poultry Houses (세 가지 서로 다른 화학제재를 깔짚에 첨가시 육계 생산성, 계사내 암모니아와 이산화탄소 가스 발생에 미치는 영향)

  • Nahm K. H
    • Korean Journal of Poultry Science
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    • v.31 no.4
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    • pp.213-219
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    • 2004
  • The objectives of this study were to investigate the effect of applying three different chemical additives to the litter (rice hull) on broiler performance, ammonia and carbon dioxide gas reduction in a poultry house at 6 weeks. A total of 96 broiler chicks (6 treatments$\times$4 replicates$\times$4 birds) were fed the experimental diets for 6 weeks. The chemical additives were applies as a top dressing to the litter at a rate of 200 g ferrous sulfate $(FeSO_4)$, 200 g aluminum chloride $(AlCl_3)$ + 50 g calcium carbonate $(CaCO_3)$ and 20 g potassium permanganate $(KMnO_4)$ per kg litter, while the control group did not have the three different chemicals added to the litter. There were no significant differences in broiler performance between the three chemical additives and control group. $FeSO_4\;and\;AlCl_3\;+\;CaCO_3$ treatment reduced ammonia production from the litter at 6 weeks by as much as 91 and $53\%$, respectively (P<0.05). $KMnO_4$ treatment decreased ammonia production at 6 weeks up to $69\%$ compared to the controls (P<0.05). Poultry litter amended with $AlCl_3\;+\;CaCO_3\;and\;KMnO_4$ also caused a decrease (P<0.01) in carbon dioxide productions at 6 weeks (59 and $65\%$, respectively). In conclusion, although broiler performance was not affected by the three chemical additives and control group, these results indicate that $FeSO_4,\;AlCl_3\;+\;CaCO_3\;and\;KMnO_4$ application to litter in a poultry house resulted in a significant reduction in atmospheric ammonia and carbon dioxide gas.

Effects of Daminozide Spray and Floral Preservatives on Longevity and Ethylene Production of Cut Lily (Lilium longiflorum Thunb.) (수확전(收穫前) Daminozide의 살포(撒布)와 수확후(收穫後) 절화보존제(切花保存劑)의 처리(處理)가 절화백합(切花百合)의 수명(壽命)과 Ethylene발생(發生)에 미치는 영향(影響))

  • Kim, Young Rae;Lee, Jong Suk
    • Korean Journal of Agricultural Science
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    • v.9 no.2
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    • pp.484-493
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    • 1982
  • This study was conducted to clarify the effects of daminozide (butanedioic acid mono-(2,2 - dimethylhydrazide)) sprayed 2 days be fore harvest and floral preservative solutions on longevity, quality and ethylene production of 'Georgia' cut lily for prolonging vase life and improving quality of cut lily flowers. And also the relation between ethylene production and flower senescence of cut lily was studied. 1. Lilies held in silver nitrate ($AgNO_3$) at 25 and 50 ppm were increased in solution uptake, fresh weight, and flower longevity. The solution of 2.5% sucrose+50 ppm $AgNO_3$+200 ppm aluminum sulfate+10 ppm 6-benzylamino purine prolonged vase life and improved quality of cut lily flowers. 2. Lilies sprayed with 500 ppm daminozide 2 days be fore harvest and then held in the preservative solution (5% sucrose+50 ppm $AgNO_3$+150ppm 8-hydroxyquinoline) after harvest were significantly increased in fresh weight and vase life as compared with non-sprayed (control) flowers. 3. Ethylene production from cut lily was increased by ethephon ((2-chloroethyl) phosphonic acid) treatment. The flowers producing a lot of ethylene, however, were senesced slowly instead of rapid wilting. 4. The preservative solution markedly reduced ethylene production of cut lily but prolonged vase life for only a few days. 5. These results suggest that ethylene be one of the most important factors promoting flower senescence of cut lily, but it be very difficult to prolong vase life remarkably by only inhibition of ethylene production in cut lily.

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The Change of Cell Distribution in the lung and the Expression Pattern of IL-4 and IL-10 in Asthma Induced Mouse (천식유발 마우스에서의 폐 내 세포조성 변화와 IL-4 및 IL-10의 발현 양상)

  • Lee, Soo-Jin;Park, Se-Jong;Li, Tian-Zhu;Jang, Yang-Ho;Choe, Nong-Hoon
    • Journal of Life Science
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    • v.16 no.5
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    • pp.780-787
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    • 2006
  • Asthma is a chronic inflammatory disorder of the airways, which characterized by bronchial hyperresponsiveness, reversible airflow limitation and respiratory symptoms. Internationally, the prevalence of asthma has been increased over last 3 decades. Recently, several studies of asthma have been reported with gradually increasing importance. To tesify the hypothesis that interleukin (IL)-4 and IL-10 may be an important determinant of the severity of airway inflammation, their expression was studied in mouse model of asthma. BALB/c mouse, IL-4 Knockout (KO) mouse and IL-10 KO mouse were sensitized with intraperitoneal injection of ovalbumin adsorbed to aluminum potassium sulfate, followed by challenges with intranasal ovalbumin on 3 consecutive days. The severity of pulmonary inflammation was assessed by eosinophilia in BAL fluid, number of total BAL cells, histopathological changes in lung tissues, and immunohistochemical staining against IL-4 and IL-10. In BAL fluid, the number of total cells was significantly increased in asthma induced mouse compare to the control. In asthma induced mouse, eosinophil was increased to 56% and neutrophil was 0.2%. In H &E stains, eosinophilic infiltration and epithelium hyperplasia were clearly noticed in asthma induced mouse. In immunohistochemical staining for IL-4 and IL-10, there was no positive reaction in control group. However, very strong reactions were appeared in asthma induced group. In this research, IL-4 and IL-10, which seem to play a central role in allergic asthma, KO mouse was utilized to test the causative relationship between airway inflammation and role of specific cytokine. Asthma induced IL-4 and IL-10 KO mice showed much decreased inflammatory reactions in the number of total BAL cells, in eosinophilic infiltration, and in immunohistochemical stains against diverse inflammatory proteins. These results suggest that IL-4 and IL-10 increase the asthmatic reactions in vivo mice model.

A Novel Volumetric Method for Quantitation of Titanium Dioxide in Cosmetics (용량분석법을 이용한 화장품 중 티타늄옥사이드의 정량)

  • Kim, Young-So;Kim, Boo-Min;Park, Sang-Chul;Jeong, Hye-Jin;Chang, Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.4 s.54
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    • pp.289-293
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    • 2005
  • Nowadays there are many sun protection cosmetics including organic or inorganic UV filter as an active ingredient. Chemically stable inorganic sunsEreen agents, usually metal oxides, we widely employed in high SPF products. Titanium dioxide is one of the most frequently used inorganic UV filters. It has been used as pigments for a long period of cosmetic history. With the development of micronization techniques, it becomes possible to incorporate titanium dioxide in sunscreen formulations without whitening effect and it becomes an important research topic. However, there are very few works related to quantitations of titanium dioxide in sunscreen products. In this research, we analyzed amounts of titanium dioxide in sunscreen cosmetics by adapting redof titration, reduction of Ti(IV) to Ti(III) and reoxidation to Ti(IV). After calcification of other organic ingredients of cosmetics, titanium dioxide is dissolved by hot sulfuric acid. The dissolved Ti(IV) is reduced to the Ti(III) by adding aluminum metals. The reduced Ti(III) is titrated against a standard oxidizing agent, Fe(III) (ammonium iron(III) sulfate), with potassium thiocyanate as an indicator In order to test accuracy and applicability of the proposed method, we analyzed the amounts of titanium dioxide in four types of sunscreen cosmetics, such as cream, make-up base, foundation and powder, after adding known amounts of titanium dioxide $(1{\sim}25w/w%)$. The percent recoveries of the titanium dioxide in four types of formulations were in the range between 96 and 105%. We also analyzed 7 commercial cosmetic products labeled titanium dioxide as an ingredient and compared the results with those of obtained from ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry), one of the most powerful atomic analysis techniques. The results showed that the titrated amounts were well coincided with the analyzed amounts of titanium dioxide by ICP-AES. Although instrumental analytical methods, ICP-MS (Inductively Coupled Plasma-Mass Spectrometry) and ICP-AES, are the best for the analysis of titanium, it is hard to adopt because of their high prices for small cosmetic companies. It was found that the volumetric method presented here gat e quantitative and reliable results with routine lab-wares and chemicals.

Conservation Treatment and Study on Manufacturing Techniques of Jija Chongtong Gun in the Middle of Joseon Dynasty (조선 중기 제작된 지자총통의 보존처리와 제작기법 연구 -동아대학교 석당박물관 소장 보물 지자총통을 중심으로-)

  • Nam Dohyeon;Park Younghwan;Lee Jaesung
    • Conservation Science in Museum
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    • v.30
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    • pp.23-46
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    • 2023
  • The Jija Chongtong Gun, owned by Seokdang Museum of Dong-A University, is a tubedstyle heavy weapon of the battlefield in the mid-Joseon Dynasty and is the second largest firearm after Cheonja Chongtong. The original surface color of the Jija Chongtong Gun was obscured by foreign substances and therefore it was judged that its condition requires the conservation treatment. For stable conservation treatment, gamma ray and X-ray non-destructive transmission surveys was conducted to determine the internal structure and conservation condition. And the component analysis on the material components and surface contaminants of Jija Chongtong Gun was conducted by utilizing the p-XRF component analysis, SEM-EDS component analysis, and XRD analysis. As a result of the gamma-ray and X-ray non-destructive transmission investigation, a large amount of air bubbles was observed inside Jija Chongtong Gun, and the part that appeared to be a chaplet by visual observation was not identified. As a result of gamma-ray and p-XRF component analysis, it was confirmed that Jija Chongtong Gun was bronze made of copper (Cu), tin (Sn), and lead (Pb) alloy. As a result of surface analysis of foreign substances using SEM-EDS, it was confirmed that the main components of white foreign substances were calcium (Ca), sulfur (S), and titanium (Ti). Titanium was presumed to be titanium dioxide (TiO2), the main component of white correction fluid. The red foreign substance was confirmed to contain barium (Ba) as its main ingredient, and was presumed to be barium sulfate (BaSO4), an extender pigment in paint. White and red contaminants, mainly composed of titanium and barium, are presumed to have been deposited on the surface in recent years. The yellow foreign substances were confirmed to be aluminum (Al) and silicon (Si), and were presumed to have originated from soil components. As a result of SEM-EDS and XRD component analysis, the white foreign substance was confirmed to be gypsum (CaS). Based on the results of component analysis, surface impurities were removed, stabilization treatment, and strengthening treatment were performed. During the conservation process, unknown inscriptions Woo (右), Byeong (兵), Sang (上), and Yi (二) were discovered through a portable microscope and precise 3D scanning. In addition, the carving method, depth, and width of the inscription were measured. Woo Byeong Sang is located above Happo Fortress in Changwon, and Yi can be identified as the second hill.