• Title/Summary/Keyword: Alpha phase

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Hydrogen photoproduction by the synchronously grown marine unicellular cyanobacterium Synechococcus sp. Miami BG 043511 under extremely high oxygen concentration

  • Yih, Won-Ho;Takeyama, Haruko;Mitsui, Akira
    • Journal of the korean society of oceanography
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    • v.31 no.1
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    • pp.18-22
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    • 1996
  • The effect of exogenous oxygen on hydrogen photoproduction was examined in the synchronously grown cells of marine Synechococcus sp. Miami BG 043511 under conditions of high cell density (0.6-0.8 mg chl-${\alpha}$ $ml^{-1}$) and high light intensity (1000 ${\mu}$E $m^{-2}$ $s^{-1}$). Hydrogen evolution after 20-h incubation did not decline under the initial oxygen concentrations up to 20%, but declined by half under 34% oxygen. 50% and 100% oxygen gas phase did not completely inhibit the hydrogen photoproduction during 40-h incubations. After 2-day pretreatment under 100% exogenous oxygen the hydrogen photoproduction capabilities were not irreversibly inhibited, which was demonstrated in the subsequent 9-day incubation under initial 0, 50 and even under 100% oxygen gas phase. This strain could be useful for developing a hydrogen photoproduction system under atmospheric oxygen concentration.

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Effect of Sn Addition on Creep Resistance of AZ91-0.4%Ca Alloy (AZ91-0.4%Ca 합금의 크립저항성에 미치는 Sn 첨가의 영향)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.4
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    • pp.185-190
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    • 2014
  • The influences of small amount of Sn addition on microstructure and creep resistance of AZ91-0.4%Ca alloy have been investigated. The microstructure of the AZ91-0.4%Ca alloy was characterized by ${\alpha}$-(Mg) dendrite cells surrounded by eutectic ${\beta}(Mg_{17}Al_{12})$ and $Al_2Ca$ phases. The 0.5%Sn addition resulted in the formation of rod-shaped CaMgSn particles with the extinction of $Al_2Ca$. The Sn-containing alloy exhibited better creep resistance below $175^{\circ}C$, but the tendency was reversed above $200^{\circ}C$. The reason was discussed in relation to the change in thermal stability of ${\beta}$ phase in response to the Sn addition.

The prediction of vapor-liquid equilibrium data for 2-methyl-2-propanol-2-butanone system at low pressure (저압하에서 2-methyl-2-propanol-2-butanone계의 기액평형치의 추산)

  • Shim, Hong-Seub;Rhew, Jong-Ha
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.1
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    • pp.97-105
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    • 2004
  • The Vapor-liquid equilibrium data for the binary system of 2-methyl-2-propanol-2-butanone are measured at subatmospheric pressure of 100, 200, 300, 400, 500, 600, 700 and 760 torr. This study shows that the relations between logarithmic values of relative valatility(log ${\alpha}$)and liquid phase composition(${\chi}$) in the above binary systems are expressed as a linear function. When the linear relationships of between logarithmic values of relative volatilities and liquid phase compositions in the binary systems of various pressure intersect at a point, this empirical equation can be applied to the systems of this kind. From these relations the vapor-liquid equilibrium data are estimated and compared with the measured values to be in a good agreement with in accuracy ${\pm}0.0021$ for the various pressure.

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High Temperature Oxidation Behavior and Surface Defect in Fe-25Mn-1.5Al-0.5C Steel (Fe-25Mn-1.5Al-0.5C강의 고온 산화 거동과 표면 결함)

  • Park, Shin Hwa;Hong, Soon Taik;Kim, Tai Wung;Chung, In-Sang
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.158-162
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    • 2000
  • The high temperature oxidation behavior and the surface defect in Fe-25Mn-1.5A1-0.5C steel was investigated by XRD (X-ray Diffractin) and electron microscopy. The intra- and inter-granular oxides were formed by the selective oxidation of manganese and aluminum, which were identified to MnAl2O4 phase. Aluminum nitride (AlN) was formed in front of these oxides. The ${\gamma}$-matrix was transformed to ${\alpha}$- and ${\varepsilon}$- phases by the selective oxidation of manganese. The surface defect, micro-scab was induced by the difference of the high temperature ductility between the matrix and the inter-granular oxide.

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Phase Transformation Behavior on Aging Treatment in CuAINi Shape Memory Alloy (CuAINi 형상기억합금의 시효처리에 따른 상변태 거동)

  • Yang, G.S.;Kang, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.213-222
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    • 1993
  • This research was performed to investigate the transformation behavior and shape memory effect of Cu-13.5Al-4.5Ni(wt%) alloy with various aging temperature and time. The results obtained in this study are as follows: Transformation temperature was very increased when aging temperature is at $250^{\circ}C$. The variation of transformation temperature in first reverse transformation cycle and second was very significant, but there was little difference in case of 2nd and 3rd. Transformation temperature at various aging temperature was increased with increasing of aging temperature and time. Microvickers hardness was increased with increasing of aging temperature and time. It was found that ${\alpha}$ and ${\gamma}_2$ phase were created by aging of long time at high temperature.

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A Simple Current Controller for Three-Phase PWM Inverters Using Three-Level Comparators (3레벨 비교기를 이용한 간단한 전류제어기)

  • Moon, Hyoung-Soo;Han, Woo-Yang;Lee, Chang-Goo;Sin, Dong-Yong
    • Proceedings of the KIEE Conference
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    • 2001.04a
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    • pp.274-276
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    • 2001
  • A simple current controller for three-phase PWM power inverters using 3-level comparator is presented. All voltage vectors are accurately selected in order to minimize the current error using two three-level comparators and ${\alpha}-{\beta}$ current reference frame. The proposed algorithm have fast response and low current errors. This current controller is improved synchronization problem and increased the voltage utilization value. Usefulness of propose method are verified on the simulation result using Matlab/Simulink.

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The Sliding Wear behavior of Fe-Cr-C-Si Alloy in Pressurized Water (Fe-Cr-C-Si 계 경면처리 합금의 고압ㆍ수중 마모거동)

  • Lee, Kwon-yeong;Lee, Min-Woo;Oh, Young-Min;;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.224-227
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    • 2003
  • The sliding wear behavior of a Fe-base hardfacing alloy was investigated in the temperature range of $25∼250^{\circ}C$ under a contact stress of 15 ksi (103 MPa). The wear loss of this Alloy in pressurized water was less than that of NOREM 02. And galling did not occurred at this alloy in all temperature ranges. It was considered that the wear resistance of this Alloy was attributed to the strain-induced phase transformation from austenite to $\alpha$'martensite during sliding wear.

Synthesis of NiO-doped Al2O3 Powder by Spray Pyrolysis (분무열분해법에 의한 NiO 첨가 Al2O3 분체의 합성)

  • 박정현;조경식;김한태
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.593-602
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    • 1991
  • Al2O3 and NiO-doped Al2O3 powders were prepared from the ethanol solution of Al (NO3)3$.$9H2O and Ni(NO3)2$.$6H2O by spray pylolysis method using two-fluid nozzle. As a result of spraying test with 0.3 mol/{{{{ iota }} concentration starting solution, mean droplet sizes varied with 8.99∼9.69$\mu\textrm{m}$ and those standard deviation were 4.57∼5.12. As-prepared powders which were synthesized at 1000$^{\circ}C$ have spherical shape, sizes of 0.1∼3.0$\mu\textrm{m}$ and specific surface area of 22.34∼24.20㎡/g. Most powders consisted of {{{{ gamma }}-Al2O3 phase and transforned into ${\alpha}$-A;2O3 phase by calcination at 1100$^{\circ}C$ for 1 hr. NiO-doped Al2O3 sintered bodies had better sinterability than those of pure Al2O3 and 0.3 wt% NiO-doped Al2O3 had near theoretical density and dense microstructure.

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The Notch Effects on the Fatigue fracture Behaviour of Ferrite-Martensite Dual Phase Steel (페라이트-마르텐사이트 이상조직강의 피로파괴거동에 미치는 노치효과)

  • 도영민
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.46-53
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    • 2003
  • For the tensile tests of the F.E.M., microvoids are created by the boundary separation process at the martensite boundary or neighborhood and at inclusions within the fracture. to grow to the ductile dimple fracture. For the case of the M.E.F., microvoids created at the discontinuities of the martensite phase which exists at the grain boundary of the primary ferrite are grown to coalescence with the cleavage cracks induced at the interior of the ferrite, which as a result show the discontinuous brittle fracture behavior. In spite of their similar tensile strengths, the fatigue limit and the notch sensitivity of the M. E.F. is superior to those of the F.E.M., The M.E.F. is much more insensitive to notch than F.E.M. from the stress concentration factor($\alpha$).

Surface Characteristics of Anodized Ti-30Nb-xTa Alloys with Ta Content

  • Kim, Eun-Sil;Ko, Yeong-Mu;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.254-254
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    • 2012
  • The purposed of this work was to determine surface charateristics of anodized Ti-30Nb-xTa alloys with Ta content. Samples were prepared by arc melting, followed by followed by homogenization for 12 hr at $1000^{\circ}C$ in argon atmosphere. The electrolyte for anodization treatment was prepared by mixing 465ml $H_2O$ with 35M $H_3PO_4$ and anodized at 180V to 220V. The microstructures of the alloys were examined by X-ray diffractometer (XRD) and optical microscopy (OM). Surface characteristics of anodized Ti-30Nb-xTa alloys was investigated by potentiodynamic test and potentiostatic in 0.9% Nacl solution at $36.5{\pm}1^{\circ}C$. It was observed that the changed ${\alpha}$ phase to ${\beta}$ phase with Ta content.

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