• Title/Summary/Keyword: Alloy steels

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Effect of Cobalt Contents on the Biocompatibility and Corrosion Properties of Fe-31Cr-27Ni-1.6Mo-1.5W-0.26N Alloy (Fe-31Cr-27Ni-1.6Mo-1.5W-0.26N계 초내식성 스테인리스강의 생체적합성 및 부식특성에 미치는 Co함량의 영향)

  • Jang, Soon Geun;Yoo, Young Ran;Nam, Hee Soo;Shim, Gyu Tae;Kim, Jung Gu;Kim, Young Sik
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.209-216
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    • 2008
  • Super austenitic stainless steels shows the high PRE (Pitting Resistance Equivalent) number and the good corrosion resistance. This work controlled the Co contents in Fe-31Cr-1.7Mo-27Ni-0.25N alloys to elucidate the effect of cobalt contents on the biocompatibility and corrosion resistance. Increasing Co contents, the hardness of the annealed alloys tends to be reduced. In aged alloys, cobalt decreased the increments of hardness by aging treatment. Cobalt decreased the critical pitting temperature (CPT) in 6% $FeCl_3$ + 1% HCl solution, but improved the anodic polarization behavior in Hanks' balanced salt solution and artificial saliva solution. Repassivation rate in artificial body solutions was improved by increasing cobalt contents, but didn't show the linear relationship to PRE number of the alloys. The experimental alloys showed the non-cytotoxicity because of its high corrosion resistance.

Study on the Austenite Formation and Mechanical Properties of AGI (Austempered Gray Cast Iron) According to Aluminum Content (알루미늄 함량에 따른 AGI (Austempered Gray Cast Iron)의 오스테나이트 형성 및 기계적 특성에 관한 연구)

  • Kim, Dong-Hyuk
    • Journal of Korea Foundry Society
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    • v.41 no.6
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    • pp.543-549
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    • 2021
  • Aluminum cast iron has excellent oxidation resistance and good resistance to sulfide and corrosion. Compared to Ti and Ni alloys, it is expected to be a substitute material for structural materials and stainless steels because it is relatively inexpensive to use Fe, which is a non-strategic element. This results in a weight reduction effect of about 30% as compared to the use of stainless steel. With regard to aluminum as an alloying material, it is an element that has been widely used for the alloying of cast iron in recent years. Practical use has been delayed owing to the resulting lack of ductility at room temperature and the sharp decrease in the strength above 600℃ of this alloy, however. The cause of the weak room temperature ductility is known to be environmental embrittlement by hydrogen, and the addition of various alloying elements has been attempted in order to mitigate these shortcomings. Although alloying elements such as vanadium, chromium, and manganese are mainly used to increase the hardness and wear resistance of gray cast iron, the price of finished products containing these elements and the problems associated with alloys with this material impose many limitations.

Evaluation of Wear Performance of Corroded Materials in an 800℃ Molten Salt Environment (800℃ 용융염 환경에서 부식된 재료의 마모 성능 평가)

  • Yong Seok Choi;Kyeongryeol Park;Seongmin Kang;Unseong Kim;Kyungeun Jeong;Ji Ha Lee;Tae Woong Ha;Kyungjun Lee
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.97-102
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    • 2024
  • The next-generation Molten Salt Reactor is known for its high safety because it uses nuclear fuel dissolved in high-temperature molten salt, unlike traditional solid atomic fuel methods. However, the high-temperature molten salt causes severe corrosion in internal structural materials, threatening the reactor's safety. Therefore, it is crucial to investigate the high-temperature corrosion resistance and wear performance of materials used in reactors to ensure safety. In this study, the high-temperature corrosion resistances and wear performances of corrosion samples in a NaCl-MgCl2-KCl (20-40-40 [wt%]) molten salt are investigated to evaluate the applicability of economically viable stainless steels, 316SS and 304SS. Hastelloy C276 and a new alloy containing a small amount of Nb are used as reference samples for comparative analysis. The mass loss, mass loss rate per unit volume, and surface roughness of each sample are measured to understand the corrosion mechanisms. Scanning electron microscopy and energy-dispersive spectroscopy analyses are employed to analyze the corrosion mechanisms. Wear tests on the corroded samples are also conducted to assess the extent of corrosion. Based on the experimental results, we predict the lifespans of the materials and evaluate their suitability as candidate materials for molten salt reactors. The data obtained from the experiments provide a valuable database for structural materials that can enhance the stability of molten salt reactors and recommend high-temperature corrosion-resistant materials suitable for next-generation reactors.

Magnetic Shielding with Thin Magnetic Materials near Power Cables (박판 자성 재료를 이용한 전력 케이블 인근의 자기장 차폐)

  • Kim, Sang-Beom;Soh, Joon-Young;Shin, Koo-Yong;Jeong, Jin-Hye;Myung, Sung-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.7
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    • pp.639-647
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    • 2009
  • In this work, wrapping conductors with thin magnetic materials is proposed as a magnetic shielding method. The 0.1 mm thick metal sheets of mu-metal, grain-oriented electrical steel, and non-oriented electrical steel were produced from commercial alloy sheets through cold rolling and followed high temperature annealing. In case of 3-phase electric currents, mu-metal was the best in shielding performance at a B-field magnitude of about 100 ${\mu}T$, whereas silicon steels were better than mu-metal at a B-magnitude over 500 ${\mu}T$. In addition, wrapping with silicon steel(inner) together with mu-metal(outer) resulted in a shielding factor less than 0.1 even at 500 ${\mu}T$. These results are due to changes in hierarchy of magnetic permeabilities of the materials with increasing magnetic field strength. In case of single-phase electric current, B-magnitude outside the magnetic shell was rather increased compared to the unshielded case. This result is explained by vector composition of B-fields near magnetic shielding materials.

Collapse Analysis of Ultimate Strength Considering the Heat Affected Zone of an Aluminum Stiffened Plate in a Catamaran (카타마란 알루미늄 보강판의 열영향부 효과를 고려한 최종강도 붕괴 해석)

  • Kim, Sung-Jun;Seo, Kwang-Cheol;Park, Joo-Shin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.5
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    • pp.542-550
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    • 2020
  • The use of high-strength aluminum alloys for ships and of shore structures has many benefits compared to carbon steels. Recently, high-strength aluminum alloys have been widely used in onshore and of shore industries, and they are widely used for the side shell structures of special-purpose ships. Their use in box girders of bridge structures and in the topside of fixed platforms is also becoming more widespread. Use of aluminum material can reduce fuel consumption by reducing the weight of the composite material through a weight composition ratio of 1/3 compared to carbon steel. The characteristics of the stress strain relationship of an aluminum structure are quite different from those of a steel structure, because of the influence of the welding[process heat affected zone (HAZ). The HAZ of aluminum is much wider than that of steel owing to its higher heat conductivity. In this study, by considering the HAZ generated by metal insert gas (MIG) welding, the buckling and final strength characteristics of an aluminum reinforcing plate against longitudinal compression loads were analyzed. MIG welding reduces both the buckling and ultimate strength, and the energy dissipation rate after initial yielding is high in the range of the HAZ being 15 mm, and then the difference is small when HAZ being 25 mm or more. Therefore, it is important to review and analyze the influence of the HAZ to estimate the structural behavior of the stiffened plate to which the aluminum alloy material is applied.

Impact Properties and Fractography of Structural Materials for LNG Tank at Cryogenic Temperatures (LNG 저장탱크용 재료의 극저온 충격특성과 파면해석)

  • Shin Hyung-Seop;Lee Hae-Moo;Shin Ju-Yeong;Park Jong-Seo
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.99-106
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    • 1998
  • In order to investigate the impact properties of structural materials for LNG tank, instrumented Charpy impact tests were carried out at cryogenic temperatures. $9\%$ Ni steel showed a superior fracture resistance because of less degradation in toughness until 77 K. From the load-deflection curve obtained by an instrumented methods it was found that with the decrease of temperature from 173 K to 77 K, the peak load in the curve increased, but the total absorbed energy decreased. In addition, the energy absorbed during the crack growth was larger than one absorbed in the process of crack initiation. In SUS304L material, the energy absorbed in the process of the crack initiation was relatively large, but the energy absorbed in the process of crack growth was small, the behavior of absorbed energy was well agreed with the observations of the fracture surface which showed a relatively smooth fracture surface. The absorbed Charpy impact energy in the case of A5083 alloy was lower as compared with other steels, and some cracks were observed along the crack propagation direction at the fracture surface of 77 K.

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Verification of the Viability of Equipotential Switching Direct Current Potential Drop Method for Piping Wall Loss Monitoring with Signal Sensitivity Analysis (등전위 교번식 직류전위차법의 신호 정밀도 검증을 통한 배관 감육 진단 기술에의 적용성 검증)

  • Ryu, Kyung-Ha;Hwang, Il-Soon;Kim, Ji-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.2
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    • pp.191-198
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    • 2008
  • Flow accelerated corrosion (FAC) phenomenon of low alloy carbon steels in nuclear power plant has been known as one of major degradation mechanisms. It has a potential to cause nuclear pipe rupture accident which may directly impact on the plant reliability and safety. Recently, the equipotential switching direct current potential drop (ES-DCPD) method has been developed, by the present authors, as a method to monitor wall loss in a piping. This method can rapidly monitor the thinning of piping, utilizing either the wide range monitoring (WiRM) or the narrow range monitoring (NaRM) technique. WiRM is a method to monitor wide range of straight piping, whereas NaRM focuses significantly on a narrow range such as an elbow. WiRM and NaRM can improve the reliability of the current FAC screening method that is based on computer modeling on fluid flow conditions. In this paper, the measurements by ES-DCPD are performed with signal sensitivity analyses in the laboratory environment for extended period and showed the viability of ES-DCPD for real plant applications.

Application of Gamma Ray Densitometry in Powder Metallurgy

  • Schileper, Georg
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.07a
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    • pp.25-37
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    • 2002
  • The most important industrial application of gamma radiation in characterizing green compacts is the determination of the density. Examples are given where this method is applied in manufacturing technical components in powder metallurgy. The requirements imposed by modern quality management systems and operation by the workforce in industrial production are described. The accuracy of measurement achieved with this method is demonstrated and a comparison is given with other test methods to measure the density. The advantages and limitations of gamma ray densitometry are outlined. The gamma ray densitometer measures the attenuation of gamma radiation penetrating the test parts (Fig. 1). As the capability of compacts to absorb this type of radiation depends on their density, the attenuation of gamma radiation can serve as a measure of the density. The volume of the part being tested is defined by the size of the aperture screeniing out the radiation. It is a channel with the cross section of the aperture whose length is the height of the test part. The intensity of the radiation identified by the detector is the quantity used to determine the material density. Gamma ray densitometry can equally be performed on green compacts as well as on sintered components. Neither special preparation of test parts nor skilled personnel is required to perform the measurement; neither liquids nor other harmful substances are involved. When parts are exhibiting local density variations, which is normally the case in powder compaction, sectional densities can be determined in different parts of the sample without cutting it into pieces. The test is non-destructive, i.e. the parts can still be used after the measurement and do not have to be scrapped. The measurement is controlled by a special PC based software. All results are available for further processing by in-house quality documentation and supervision of measurements. Tool setting for multi-level components can be much improved by using this test method. When a densitometer is installed on the press shop floor, it can be operated by the tool setter himself. Then he can return to the press and immediately implement the corrections. Transfer of sample parts to the lab for density testing can be eliminated and results for the correction of tool settings are more readily available. This helps to reduce the time required for tool setting and clearly improves the productivity of powder presses. The range of materials where this method can be successfully applied covers almost the entire periodic system of the elements. It reaches from the light elements such as graphite via light metals (AI, Mg, Li, Ti) and their alloys, ceramics ($AI_20_3$, SiC, Si_3N_4, $Zr0_2$, ...), magnetic materials (hard and soft ferrites, AlNiCo, Nd-Fe-B, ...), metals including iron and alloy steels, Cu, Ni and Co based alloys to refractory and heavy metals (W, Mo, ...) as well as hardmetals. The gamma radiation required for the measurement is generated by radioactive sources which are produced by nuclear technology. These nuclear materials are safely encapsulated in stainless steel capsules so that no radioactive material can escape from the protective shielding container. The gamma ray densitometer is subject to the strict regulations for the use of radioactive materials. The radiation shield is so effective that there is no elevation of the natural radiation level outside the instrument. Personal dosimetry by the operating personnel is not required. Even in case of malfunction, loss of power and incorrect operation, the escape of gamma radiation from the instrument is positively prevented.

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Microstructures and Hardness of Al-Si Coated 11%Cr Ferritic Stainless Steel, 409L GTA Welds (Al-Si 용융도금된 11%Cr 페라이트 스테인리스강, STS409L GTA 용접부의 미세조직과 경도)

  • Park, Tae-Jun;Kong, Jong-Pan;Na, Hye-Sung;Kang, Chung-Yun;Uhm, Sang-Ho;Kim, Jeong-Kil;Woo, In-Su;Lee, Jong-Sub
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.92-98
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    • 2010
  • Ferritic stainless steels, which have relatively small thermal expansion coefficient and excellent corrosion resistance, are increasingly being used in vehicle manufacturing, in order to increase the lifetime of exhaust manifold parts. But, there are limits on use because of the problem related to cosmetic resistance, corrosions of condensation and high temperature salt etc. So, Aluminum-coated stainless steel instead of ferritic stainless steel are utilized in these parts due to the improved properties. In this investigation, Al-8wt% Si alloy coated 409L ferritic stainless steel was used as the base metal during Gas Tungsten Arc(GTA) welding. The effects of coated layer on the microstructure and hardness were investigated. Full penetration was obtained, when the welding current was higher than 90A and the welding speed was lower than 0.52m/min. Grain size was the largest in fusion zone and decreased from near HAZ to base metal. As welding speed increased, grain size of fusion zone decreased, and there was no big change in HAZ. Hardness had a peak value in the fusion zone and decreased from the bond line to the base metal. The highest hardness in the fusion zone resulted from the fine re-precipitation of the coarse TiN and Ti(C, N) existed in the base metal during melting and solidification process and the presence of fine $Al_2O_3$ and $SiO_2$ formed by the migration of the elements, Al and Si, from the melted coating layer into the fusion zone.

A COMPARATIVE STUDY ON THE PHYSICAL PROPERTIES OF ORTHODONTIC PLIERS ACCORDING TO TYPES OF STERILIZATION (멸균 방법에 따른 교정용 플라이어의 물성 변화에 대한 비교 연구)

  • Cho, Il-Je;Son, Woo-Sung
    • The korean journal of orthodontics
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    • v.28 no.2 s.67
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    • pp.329-341
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    • 1998
  • Sterilization has received much attention in orthodontic practices over the past several years. The present study was undertaken to investigate the effects of sterilization on the physical properties of orthodontic pliers-AEZ, Unitek, and Dentronix ligature cutters. This study was designed to examine the tips of ligature cutters before and after 200 and 400 sterilization cycles using the Bowmar RHT-1000, the Dentronix DDS-5000, and the Eschmann SES-2000. The tip surface and the fracture surface were observed with a scanning electron microscope. The microstructure was observed with an optical microscope. The hardness test was carried out with the mic개-Vickers hardness tester and the Rockwell C Scale hardness tester. The chemical composition was analyzed by energy dispersive X-ray spectrometer. The results of this study were as follows : 1. The number and the size of corrosion products on the tip surface and the proportion of cleavage planes in fractured specimen increased, but the hardness of the tip decreased in proportion to sterilization cycles. From these observations, it was considered that mechanical properities decreased in proportion to sterilization cycles. 2. The number and the size of chromium carbides increased in proportion to sterilization cycles. Coarse microstructure decreased mechanical properities. 3. The AEZ and Unitek ligature cutters were Fe-Cr stainless steels, but the Dentronix ligature cutter was Co-Cr alloy. There were many differences among manufactures, but the chemical composition was .not changed after sterilization cycles. 4. The tip edge of ligature cutter used in a clinic revealed microcracks with the SEM observation. Clinical experience confirmed that ligature cutters were gradually degraded by sterilization.

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