• Title/Summary/Keyword: Alloy addition

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The Study of Heat Resistant Aluminum Alloy with CrW Homogeneous Solid Solution (CrW 전율고용체 첨가 내열 알루미늄 합금에 관한 연구)

  • Kim, Jin-Pyeong;Sung, Si-Young;Han, Beom-Suck;Kim, Sang-Ho
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.122-126
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    • 2013
  • Recently, heat-resistant aluminum alloy has been re-focused as a downsizing materials for the internal combustion engines. Heat-resistant Al alloy development and many researches are still ongoing for the purpose of improving thermal stability, high-temperature mechanical strength and fatigue properties. The conventional principle of heat-resistant Al alloy is the precipitation of intermetallic compounds by adding a variety of elements is generally used to improve the mechanical properties of Al alloys. Heat resistant aluminum alloys have been produced by CrW homogeneous solid solution to overcome the limit of conventional heat resistant aluminum alloy. From EPMA, it is found that CrW homogeneous soild solution phases with the size of $50-100{\mu}m$ have been dispersed uniformly, and there is no reaction between aluminum and CrW alloy. In addition, after maintaining at high temperature of 573 K, there is no growth of hardening phase, nor desolved, but CrW still exists as a homogeneous solid solution.

Effect of Sn Addition on Corrosion Behavior of Zr-1.0 Nb-xSn Alloy System (Zr-1.0Nb-xSn 합금의 부식거동에 대한 Sn첨가의 영향)

  • Lee, Myeong-Ho;Choe, Byeong-Gwon;Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.369-374
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    • 2002
  • To investigate the corrosion behavior of Zr-1.0Nb-xSn (x=1.0, 1.5, 2.0 and 2.5wt. %)alloy system, the corrosion tests of Zr-1.0Nb-xSn alloys were carried out in steam at $400^{\circ}C$ for 125 days and in 70ppm LiOH solution at $360^{\circ}C$ for 180 days. The matrix microstructures of the test specimens were analyzed using TEM and the oxide structures on the test specimens were analyzed using XRD. It was found from the analyses that the more Sn content the alloy had, the faster it was corroded and with the increase of Sn content in the alloy the fraction of $t-ZrO_2$ to $m-ZrO_2$ was decreased. It was also found that the alloys having more Sn showed more dislocation density than those having less.

Effect of Surface Treatment on Bioactivity of Ti-Ni Shape Memory Alloys (Ti-Ni형상기억합금의 생체활성에 미치는 표면처리의 영향)

  • Choi, Mi-Seon;Nam, Tae-Hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.12
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    • pp.881-886
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    • 2009
  • Research into the replacement of injured systems and tissue in the human body is advancing rapidly. Recently, Ti-Ni shape memory alloys have shown excellent biofunctionality related to their shape memory effect and superelasticity. In this study, the effect of an acid or an alkali treatment on the bioactivity in 49Ti-Ni and 51.5Ti-48.5Ni alloys is investigated in an effort to utilize Ti-Ni alloy as a biomaterial. In addition, the biocompatibility in a SBF solution is assessed through in vitro testing. A porous surface was formed on the surface of both alloys after a chemical treatment. According to the in vitro test, apatite formed on the surfaces of both alloys. The forming rate of apatite in the Ti-rich alloy was faster that in the Ni-rich alloy. The formation of apatite provided proof of the bioactivity of the Ti-Ni alloy. A small quantity of Ni was eluted at the initial stage, whereas Ni was not found for 12 days in the Ti-rich alloy and for 8 days in the Ni-rich alloy. In the case of the treated 51.5Ti-Ni alloy, the shape memory property was worsened but the biocompatibility was improved.

Fragmentation of Particles in Hydriding and Dehydriding (Hydriding과 Dehydriding에서 입자 미세화)

  • Nam, In-Tak
    • Journal of Industrial Technology
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    • v.3
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    • pp.47-51
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    • 1983
  • The fragmentation of Mg and Mg-25(w/o) Al alloy particles in hydriding-dehydriding was studied. The formation of hydride was made in autoclave, and formed hydrides were $MgH_2$ in both pure Mg and Mg-25(w/o) Al alloy particles. Pure Mg was more fractured than Mg-25(w/o) Al alloy in hydriding. The addition of Al exhibited fragmentation in hydriding, but displayed the same fragmentation as Mg in dehydriding.

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Damping Capacity of Mg-Al Casting Alloy Refined by Aluminum Carbide Particles (알루미늄 카바이드 입자로 미세화된 Mg-Al 주조합금의 진동감쇠능)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.6
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    • pp.293-298
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    • 2007
  • Influences of aluminum carbide ($Al_4C_3$) addition on microstructure and damping capacity of Mg-3%Al casting alloy have been investigated based on experimental results of optical micrography, scanning electron microscopy with energy-dispersive spectrometry analysis and damping capacity measurement at RT. The addition of $Al_4C_3$ particles results in an efficient grain refinement. The damping capacity shows an increasing tendency with an increase in $Al_4C_3$ content. The damping value associated with $Al_4C_3$ particles is linearly dependent on the volume fraction of $Al_4C_3$ particles to the 2/3 power, $f_{2/3}$, which corresponds to the total surface area of the particles.

The Effect of Ca Addition on Electrochemical Properties of Mg-alloy by Casting (주조법에 의해 제조된 마그네슘 합금에서 칼슘 첨가가 전기화학적 특성에 미치는 영향)

  • Kim, Hye-Sung
    • The Journal of the Korea Contents Association
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    • v.2 no.1
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    • pp.120-124
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    • 2002
  • It is the purpose of the present to report result of a preliminary electrochemical characterization of the as-cast Mg-Ca alloys. Electrochemical data will be correlated with chemical composition of impurities, and the microstructural change before and after Ca is added. This paper shows that small addition of Ca imparts beneficial effect in electrochemical properties of Mg alloy, primarily, through microstructural modifications.

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Advanced Powder Processing Techniques of Ti Alloy Powders for Medical and Aerospace Applications

  • Miura, Hideshi
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.323-331
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    • 2013
  • In this paper, two kinds of advanced powder processing techniques Metal Injection Molding (MIM) and Direct Laser Forming (DLF) are introduced to fabricate complex shaped Ti alloy parts which are widely used for medical and aerospace applications. The MIM process is used to strengthen Ti-6Al-4V alloy compacts by addition of fine Mo, Fe or Cr powders. Enhanced tensile strength of 1030 MPa with 15.1% elongation was obtained by an addition of 4 mass%Cr because of the microstructural modification and also the solution strengthening in beta phase. However, their fatigue strength was lower compared to wrought materials, but was improved by HIP. Subsequently, the effect of feeding layer height (FLH) on the characteristics of the DLF compacts was investigated. In the case of 100 ${\mu}m$ FLH, surface roughness was improved and nearly full density (99.8%) was obtained. Also, tensile strength of 1080 MPa was obtained, which is higher than the ASTM value.

Characteristics of Microstructure of Hardfacing Layer of Stellite 6 with Mo Addition (몰리브덴을 첨가하여 PTAW법으로 육성된 Stellite 6합금의 미세조직 특성평가)

  • 신종철;김재수;이덕열;양재웅;윤진국;노대호;이종권
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.241-248
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    • 2002
  • Hardfacing layers of Stellite 6 alloy with different molybdenum content are deposited on AISI 1045 carbon steel using plasma transferred arc welding (PTAW). The properties of the hardfacing layer are investigated in order to clarify the effect of molybdenum addition to the cobalt-base alloy. With an increase in molybdenum contents, the size of Cr-rich carbides in the interdendritic region is abruptly refined, but volume fraction of the carbide slightly increases. Also, with an increase of Mo, $M_{6}$ C type carbides are formed instead of Cr-rich $M_{7}$ $C_{3}$ type carbided, and this microstructural change enhanced the mechanical properties of Stellite 6 alloy.

The Effects of Mn and Cr Additions on the Microstructure of A356 Alloys Containing Impure Fe (불순 Fe를 함유한 A356 주조합금에서 미세조직 형성에 관한 Mn과 Cr의 효과)

  • Han, Sang-Won
    • Journal of Korea Foundry Society
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    • v.25 no.3
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    • pp.128-133
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    • 2005
  • The effects of Mn and Cr on the crystallization behaviors of Fe-bearing intennetallics in A356 alloy were studied. Coarse and acicular ${\beta}-Al_{5}$FeSi phase in A356-0.20wt.%Fe alloy was modified into small ${\alpha}$-Al(Fe,Mn)Si and ${\alpha}$-Al(Fe,Cr)Si phases in response to Mn and Cr addition, respectively. Increasing of Mn addition amount elevates the crystallizing temperature of ${\alpha}$-Al(Fe,Mn)Si and the Mn/Fe ratio in the ${\alpha}$-Al(Fe,Mn)Si. Cr is more effective to modify ${\beta}-Al_{5}$FeSi in comparison with Mn. ${\alpha}$-Al(Fe,Mn)Si phase had BCC/SC dual structure.

Effect of Ti, B, Zr Elements on Grain Refinement and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy (주조용 Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe 합금의 결정립 미세화와 주조특성에 미치는 Ti, B, Zr 첨가원소의 영향)

  • Kim, Heon-Joo;Park, Su-Min
    • Journal of Korea Foundry Society
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    • v.35 no.5
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    • pp.120-127
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    • 2015
  • The effects of Ti, B and Zr on grain refinement and castability were investigated in Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurement of cooling curve and micro-structure observation were performed to analyze the effects of the addition of minor elements Ti, B and Zr during solidification. The prominence of effect on grain refinement was in increasing order for Ti, Zr and B element. Fine grain size and an increase of the crystallization temperature for ${\alpha}$-Al solution were evident as the amount of addition elements increased in this study. Addition of 0.15wt% Ti was most effective for grain refinement, and the resulting grain size of ${\alpha}$-Al solution for shell mold and steel mold were $72.3{\mu}m$ and $23.5{\mu}m$, respectively. Fluidity and shrinkage tests were perform to evaluate the castability of the alloy. Maximum fluidity length and minimum ratio of micro shrinkage were recorded for 0.15wt% Ti addition due to the effect of the finest grain size.