• Title/Summary/Keyword: Alloy Solidification

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Grain Refinement of Mg-5wt%Zn Alloy by Rapid Solidification Process (급냉응고에 의한 Mg-5wt%Zn 합금의 결정립 미세화)

  • Kim, Yeon-Wook;Lee, Eun-Jong;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.302-308
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    • 1997
  • In spite of the fact that magnesium has low density and good machinability, its applications are restricted as a structural engineering material because of the poor strength, ductility, and corrosion resistance of the conventional ingot metallurgy alloys. Such properties can be improved by microstructural refinement via rapid solidification processing. In this study, Mg-5wt%Zn alloys have been produced as continuous strips by the melt overflow technique. In order to evaluate the influence of the cooling rate on the grain refinement and mechanical properties, seven different thickness strips were produced by means of controlling the speed of the cooling wheel. Then the microstructual observations were undertaken with the objective of evaluating the grain refinement as function of the cooling rate. The tremendous increase in hardness of Mg-Zn alloy was mainly due to the refinement of the grain structure by the effect of rapid solidification. The formation of intermetallic phases on the grain boundaries may have a positive effect on the corroion resistance. Therefore, despite competition from many other developments, the rapid solidification process emerges as a valuable method to develop superior and commercially acceptable magnesium alloys.

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The structure and mechanical properties of unidirectionally solidified Al-Fe-Ni, Al-Fe-B alloy (일방향 응고시킨 Al-Fe-Ni, Al-Fe-B 합금의 기계적 성질 및 조직)

  • 김여원;신문교
    • Journal of Advanced Marine Engineering and Technology
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    • v.10 no.4
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    • pp.57-66
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    • 1986
  • The microstructure and mechanical properties of unidirectionally solidified Al-Fe-Ni and Al-Fe-B alloys have been studied in varying the some conditions. To investigate the change of microstructure and mechanical properties was carried out by the varying the composition and solidification rate from 1.2 to 80 mm/min at temperature gradient 60 .deg. C/cm. The results obtained are as follow; 1. In proportion to the increase of the solidification rate, the type of crystallized phase of these composite alloys was changed by added element. a) The crystallized phase of composite alloy in added nikel was changed from the rod-type fiber to platetype fiber. b) The crystallized phase of composite alloy in added boron was changed from the plate-type fiber to rod-type fiber. 2. The strength was rapidly increased with the changing process of crystallized fiber from the plate-type fiber to the rod-type.

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The Effect of the Sn Amounts on the Microstructure of Rapidly Solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 미세조직에 미치는 Sn 함량 변화의 영향)

  • Cho, Dae-Hyoung;Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.26 no.2
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    • pp.92-97
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    • 2006
  • Contact material is widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. To solve the disadvantages of that, Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to optimize Sn amount that affects the formation of the oxide layer on the surface, we worked for the microstructures and properties of Ag-Sn material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. We have shown that the optimized Sn amount for high hardness is 7.09 wt%Sn. Surface oxide layer forms when Sn amount is over 9.45 wt%. The size of Sn oxide is 20 nm.

Wear properties of Al-Pb alloys produced by a forced stirring method (강제교반법으로 제조된 Al-Pb계 베어링 합금의 마모특성)

  • 임화영;허무영;임대순
    • Tribology and Lubricants
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    • v.8 no.1
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    • pp.70-77
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    • 1992
  • Al-Pb-Si bearing alloys were produced by a forced stirring method and a rapid solidification process to study wear properties of bearing alloys. A homogeneous distribution of Pb particles in Al matrix could be obtained by means of the forced stirring and the rapid cooling during the casting. The wear properties of bearing alloys were tested by a pin-on-disc wear tester. The change in microstructure according to the alloy manufacturing variables was observed by the backscattered electron images. Al-Pb and Al-Si binary alloys showed a transition from mild to severe wear. The transition was not found in Al-Pb-Si ternary alloys. It could be concluded that the lubricatioin effect of Pb and the strengthening effect of Si in the ternary alloys enhanced the bearing properties. A Al-25%Pb-13%Si alloy showed the lowest coefficient of friction in this experiment. It indicated that the optimum concentration of alloy was 25% Pb and 13% Si when the forced stirring of melt and water-cooled-copper-mold solidification were adopted.

A Study on Alloy Design for Improving Pitting Resistance of Austenitic Stainless Steel Weld under Ocean Water Atmosphere (오스테나이트계 스테인리스강 용접부의 공식저항성을 위한 합금설계에 관한 연구)

  • 변경일;정호신;성상철
    • Journal of Welding and Joining
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    • v.17 no.5
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    • pp.89-96
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    • 1999
  • The base metal and weld metal of alloy designed austenitic stainless steels were electrochemically tested in artificial sea water. Pitting resistance of 14 different stainless steels was evaluated by measuring pitting potential. The effect of alloy element to pitting potential was evaluated by changing chromium, nickel, sulfur content. The site of pitting initiation was observed by optical microscope. As a result of electrochemical test, pitting resistance of weld metal was higher than base metal, and rapidly cooled weld metal has higher pitting potential than slowly cooled weld metal. In case of primary δ-ferrite solidification, pitting potential was increased, but residual δ-ferrite was detrimental to pitting resistance. Chromium was more effective to pitting resistance than nickel, and sulfur was very detrimental element to pitting resistance.

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Measurement of Heat Transfer Coefficient of Magnesium Alloy and Temperature Change of Roll using Heat Transfer Solidification Analysis Method (전열응고해석법을 이용한 마그네슘합금의 열전달계수 및 롤의 온도변화 측정)

  • Han, Chang-Suk;Lee, Chan-Woo
    • Korean Journal of Materials Research
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    • v.32 no.9
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    • pp.391-395
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    • 2022
  • Research is being actively conducted on the continuous thin plate casting method, which is used to manufacture magnesium alloy plate for plastic processing. This study applied a heat transfer solidification analysis method to the melt drag process. The heat transfer coefficient between the molten magnesium alloy metal and the roll in the thin plate manufacturing process using the melt drag method has not been clearly established until now, and the results were used to determine the temperature change. The estimated heat transfer coefficient for a roll speed of 30 m/min was 1.33 × 105 W/m2·K, which was very large compared to the heat transfer coefficient used in the solidification analysis of general aluminum castings. The heat transfer coefficient between the molten metal and the roll estimated in the range of the roll speed of 5 to 90 m/min was 1.42 × 105 to 8.95 × 104 W/m2·K. The cooling rate was calculated using a method based on the results of deriving the temperature change of the molten metal and the roll, using the estimated heat transfer coefficient. The DAS was estimated from the relationship between the cooling rate and DAS, and compared with the experimental value. When the magnesium alloy is manufactured by the melt drag method, the cooling rate of the thin plate is in the range of about 1.4 × 103 to 1.0 × 104 K/s.

A Study on Weld Defect and Their Alternatives during Lap Welding of AZ31B Magnesium Alloy by Pulsed Nd: YAG Laser (Nd:YAG 펄스 레이저를 이용한 AZ31B 마그네슘 합금의 겹치기 용접에서 발생하는 용접결함과 그 대책에 대한 연구)

  • Kim, Jong-Do;Lee, Jung-Han;Kim, Young-Sik
    • Journal of Welding and Joining
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    • v.29 no.3
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    • pp.82-88
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    • 2011
  • With a tendency for the application of thin magnesium alloy plates in portable electronic equipment such as cell phone and notebook PC, there is a requirement to develop a welding technology for the lap welding of these thin magnesium alloy. This paper presents the single pulsed laser welding of AZ31B magnesium alloy. The effects of fiber types and parameters such as peak power and pulse width on laser weldability were investigated. The results show that weld defects, especially solidification crack, were always generated in the weld. These defects couldn't be controlled by the simple square pulse, but could be improved through the application of variable pulse. It is because that variable pulse has effect of solidification delay by dropping peak power gradually.

A Study on the Cracking Behavior in the Welds of Ni-Cr-Fe and Ni-Fe-Cr-Mo Alloys Part I : Solidification Cracking in the Fusion Zone (Ni-Cr-Fe 및 Ni-Fe-Cr-Mo계 합금의 용접부 균열특성에 관한 연구 Part I : 용착금속의 응고균열)

  • 김희봉;이창희
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.78-89
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    • 1997
  • This study has evaluated the weld metal solidification cracking behavior of several Ni base superalloys (Incoloy 825, Inconel 718 and Inconel 600). Austenitic stainless steels(304, 310S) were also included for comparison. In addition, a possible mechanism of solidification cracking in the fusion zone was suggested based on the extensive microstructural examinations with SEM, EDAX, TEM, SADP and AEM. The solidification cracking resistance of Ni base superalloys was found to be far inferior to that of austenitic stainless steels. The solidification cracking of Incoloy 825 and Inconel 718 was believel to be closely related with the Laves-austenite (Ti rich in 825 and Nb rich in 718) and MC-austenite eutectic phases formed along the grain boundaries during solidification. Cracking in Inconel 600 was always found along the grain boundaries which were enriched with Ti and P. Further, solidifidcation cracking resistance was dependent not only upon the type of love melting phases but also on the amount of the phases along the solidification grain boundaries.

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Austenite Precipitation Behaviors with Solidification Rate and N Solubility in Cast Duplex Stainless Alloys (주조용 이상스테인리스강에서 응고속도 및 질소고용도에 따른 오스테나이트 석출 거동)

  • Lee, Jong-Yeop;Lee, Je-Hyun;Kim, Sang-Sik;Choi, Byung-Hak;Kim, Sung-Jun;Son, Hee-Young
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.654-659
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    • 2007
  • Austenite precipitation behavior was studied with solidification rates and alloying contents, N and Cr, in duplex stainless steels by directional solidification. Directional solidification experiments were carried out with solidification rates, $1{\sim}100mm/s$, and N and Cr contents, $0{\sim}0.27wt.%,\;25{\sim}28wt.%$ respectively, in a duplex stainless steel, CD4MCU. As the solidification rate increases, the dendrite spacing reduced and the austenite phase in the ferrite matrix became finer. The volume fraction of austenite phase increased and its shape went to be round with increasing nitrogen contents in duplex stainless alloys. The Cr alloying element, even though it is a ferrite former, showed to enhance the nitrogen solubility in the alloy and caused the austenite round and finer. Also, Cr was supposed to decrease the austenite volume fraction, but it increased the austenite slightly due to increasing nitrogen solubility during solidification.

Solidification Phenomena of Al-4.5wt.% Cu Alloy under Moderate Pressures (고압하에서의 Al-4.5wt.%Cu합금의 응고현상)

  • Cho, In-Sung;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.15 no.2
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    • pp.156-163
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    • 1995
  • Solidification of aluminum alloys under moderate pressures has been investigated. Interfacial heat transfer coefficient at the casting/mold interface varies with time after pouring the molten metal into the die cavity, and therefore plays an important role in determining solidification sequence. The heat transfer coefficients were evaluated by using an inverse problem method, based on the measured temperature distribution. The calculated heat transfer coefficients were used for solidification simulation in the squeeze casting process. The effects of applied pressure and positions of insulation in the mold have also been investigated on solidification microstructures and on the formation of macrosegregation of Al-4.5wt.%Cu alloys.

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