• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.109-112
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• 1996

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for all-stolid-state lithium battery. We investigated conductivity, electrochemical properites and impedence spectroscopy of poly(ethylene oxide)[PEO]/poly(vinylidene fluoride)[PVOF] blend electrolytes and charge/discharge cycling of LiCoO$_2$/SPE/Li cell. By adding PVDF and plasticizer to PEO-LICIO$_4$electrolyte, its condustivity was higher than that of PEO-LiCIO$_4$electrolyte. Also PEO$_4$PVDF$_4$LiClO$_4$PC$_{5}$EC$_{5}$ remains stable up to 4.4V vs Li/Li. The discharge capacity of the LiCoO$_2$composite cathode was 92mAh/g based on LiCoO$_2$.EX>.