• 펄프종이기술
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• 제33권2호
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• pp.17-23
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• 2001

AKD sizing behavior of handsheets, which were prepared from the different pulps with various AKD fixing agents, was studied in this investigation. AKD sizing performance could be improved by removal of fines in the stock, minimizing damage of fiber, using a suitable fixing agent and heat treatment. Fillers with low surface energy, like calcium carbonate and talc, showed quite positive effect in AKD sizing. When PAM was added to the DIP stock as fixing agent, it showed lower sizing degree than polyamine did. But in case of NBKP system, PAM was more effective than polymine.

• 펄프종이기술
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• 제33권1호
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• pp.8-15
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• 2001

Presence of small amount of old newsprints printed with waterbased flexographic inks leads to a significant loss brightness of the deinked pulp by flotation process. Recently there has been an increased interest in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. It was shown that neutral deinking provides significant improvements in brightness, yield and freeness as compared with alkaline deinking. Flotation efficiency was different depending upon the type of surfactants used in neutral deinking. The result of this study showed that alcohol type surfactant is superior to fatty acid type surfactant in neutral deinking efficiency.

• 펄프종이기술
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• 제34권2호
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• pp.67-72
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• 2002

The two stage laccase-assisted delignification process led to significant lignin removal in the non-pressurized treatments. It is clearly shown that an alkaline extraction prior to the second laccase treatment significantly increased the overall delignification by ∼15%. This is in line with the contention that the residual lignin has undergone structural changes during the alkaline extraction, and the resulting modified structures are susceptible to the laccase oxidation. In phenolic hydroxyl group, the pre- methylated sample was very responsive to the delignification process. The phenolic hydroxyl groups could be increased during side chain cleavage catalyzed by laccase. This finding demonstrates that the delignification oi etherified structures is an important reaction in the delignificaton by laccase.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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• pp.291-295
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• 1999

Coprinus cinereus 2249 that is a kind of basidiomycetes constitutively produced alkaline carboxymethyl cellulase (CMCase), filter paper cellulase (FPase) and xylanase. Crude enzymes prepared with optimal conditions showed higher FPase activity than CMCase activity. The FPase was most active at pH 9 at 50$^{\circ}C$. When applied on deinking of the old newsprint (ONP), it increases the freeness and brightness due to effect of hydrolysis at 0.1% enzyme concentration. Also, The physical properties of deinked pulp were improved.

• 펄프종이기술
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• 제35권3호
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• pp.66-73
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• 2003

Alkaline cellulolytic enzymes are prepared from Coprinus cinereus 2249. Recovery method of enzyme protein from cultured medium and effect factors on enzyme activity of protein were investigated. The results could summarized as follows, \circled1 Amount of enzyme protein from cultured medium was highest in incubation with shaking and addition of skim milk. \circled2 Protein from cultured medium was alkaline enzymatic protein which shows the highest activity at pH 9.0. \circled3 The most effective recovery method of enzyme protein was the precipitation of protein by addition of cultured medium of protein in ethanol. \circled4 The enzyme activity was enhanced by tween-80 and decreased with $Al_2(SO_4)_3$, $H_2O_2$et al, and was little changed with metal ions except $Hg^{++}$.

• 펄프종이기술
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• 제33권4호
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• pp.49-54
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• 2001

This study was carried out to acquire basic data for the bleaching of bamboo chemical pulp. Bamboo chemical pulps (alkaline sulfite (AS)-anthraquinone (AQ) pulp, Kraft pulp) were bleached with two kinds of multistage bleaching methods (CEDED, PDED) using the various kinds of bleaching agents. And, physical properties of bleached pulps were investigated. The conclusions obtained from the results were as follows; The yield of AS-AQ pulp bleached with four-stages bleaching method using the hydrogen peroxide and chlorine dioxide as a bleaching agents was higher than the other bleached pulps. The brightness of kraft pulp bleached with five-stages bleaching method using the chlorine and chlorine dioxide as a bleaching agents was higher than the other bleached pulps. The physical properties of kraft pulp bleached with four-stages bleaching method using the hydrogen peroxide and chlorine dioxide as a bleaching agents was higher than the other bleached pulps.

• 펄프종이기술
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• 제33권5호
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• pp.25-29
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• 2001

Dimethyldioxirane (DMD), which is a source of active oxygen, is effective agent that can be used in chemical pulp bleaching. In this study, delignification of kraft bagasse pulp has been carried out by using DMD. The effect of the applied charge of DMD (as active oxygen) and pH of the delignification medium were studied. The optimum conditions of the applied DMD charge and pH of the delignification reaction were achieved at pH range from 8~9, 2% of DMD (as active oxygen) and the rest of delignification reaction conditions were $25^{\circ}C$, 60 min, and 12% pulp consistency. The development of brightness per unit kappa number removal (ΔBrightness/ Δ Kappa number) has highest value at the optimum condition. The study showed that the reactivity of kraft bagasse pulp be enhanced to wards alkaline hydrogen peroxide bleaching by pulp treatment with DMD.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 추계학술발표논문집
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• pp.1-8
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• 2006

• 펄프종이기술
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• 제48권1호
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• pp.100-110
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• 2016

Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

• 펄프종이기술
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• 제32권2호
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• pp.45-50
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• 2000

This study was to get the optimum conditions on bleaching by mixing of various colored ledgers with white ledger by 50：50 ratio. This bleaching was carried out by two steps, reductive-oxidative process was shown a better brightness compared to oxidative-reductive one. Especially, in reductive bleaching using sodium hydrosulfite, the aging temperature should keep above 6$0^{\circ}C$ irrespective of aging time, alkaline condition was more effective than acid one. Final brightness after bleaching and feinting was obtained over 78% to be used by the raw pulp of tissue.