• Title/Summary/Keyword: Alkaline pulp

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The Middle Lamella Remainders on the Surface of Various Mechanical Pulp Fibres

  • Li, Kecheng;Tan, Xuequan;Yan, Dongbo
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.51-59
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    • 2006
  • The surface of various mechanical pulp fibres including thermomechanical pulp (TMP), chemithermomechanical pulp (CTMP), and alkaline peroxide mechanical pulp (APMP) fibres, were characterized using SEM, AFM, and XPS. With SEM and AFM, middle lamella material was observed to be non-fibrillar, patch-like, while fibre secondary wall was observed to have a microfibrillar structure. It was found that after the first-stage refiner, lignin-rich middle lamella remainders are present on the fibre surface of all three pulps, although most of the fibre surfaces expose microfibrillar structure. After the final-stage refining, large amounts of granules are present on the TMP fibre surface. In contrast, most middle lamella remainders remain on the surface of CTMP fibres after final stage refining and even after peroxide bleaching. XPS results have confirmed that the non-fibrillar surface material is the lignin-rich middle lamella remainder., and the remainders of middle lamella contribute to the high surface lignin concentration.

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Soda-Anthraquinone Pulping and Alkaline Sulfite-Anthraquinone Pulping of Rice-Straw (볏짚을 이용한 소다-안트라퀴논 펄프 및 알칼리성 아황산염-안트라퀴논 펄프 제조)

  • 강진하;박성철;박성종
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.3
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    • pp.34-42
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    • 1997
  • This study was carried out to investigate the proper cooking conditions of soda-anthraquinone and alkaline sulfite-anthraquinone pulping of rice-straw, and get basic data f9r the use of rice-straw chemical pulp through the test of characteristics and physical properties of pulps made in the various cooking conditions From the experimental results , we can conclude as follows. In the soda-anthraquinone pulping of rice-straw, the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of caustic soda of 20% with the addition of anthraquinone(0.05%). And total yield, Kappa No. and brightness of pulp made in the condition above mentioned were 41.9%, 7.7 and 51.1 respectively. In the alkaline sulfite-anthraquinone pulping of rice-straw, the proper mixing ratio of cooking chemical(caustic soda : sodium sulfite) was 50:50. And the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of cooking chemical of 20% with the addition of anthraquinone(0.05%). At that time, the total yield, Kappa No, and brightness of pulp were 50.1%, 9.1 and 40.2 respectively. As a result, the alkaline sulfite-anthraquinone pulping was superior to the soda-anthraquinone pulping in the aspect of yield, but inferior in the viewpoints of Kappa No. and brightness. For the comparison of qualities of pulps made in the various cooking methods and conditions, the physical properties of four sorts of pulps were tested. As a result, soda-anthraquinone pulps were superior to alkaline sulfite-anthraquinone pulps in the various strengths excluding tear strength and brightness. On the other hand, pulps made in the condition of addition of cooking chemical of 20% were superior to pulps in the dosage of 15% in the aspects of all the strengths and brightness.

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Deinking of Electrostatic Wastepaper with Cellulolytic Enzymes and Surfactant in Neutral pH

  • Eom, Tae-Jin;Yoon, Kyong-Dong;Park, Soung-Bae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.123-128
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    • 2006
  • Enzymatic deinking method can avoids the alkaline environment as usual required in chemical deinking, which consequently cuts chemical costs and reduced the white water pollution. The electrostatic wastepaper was dinked with commercial cellulolytic enzymes and surfactant in neutral pH and the effectiveness of deinking and the physical properties of deinked pulp were evaluated. The disintegrating efficiency of the electrostatic wastepaper in neutral pH was enhanced with enzyme treatments. Although the freeness of deinked pulp with enzymes was higher than that of deinked pulp with chemical deinking agents, the brightness of the enzymatic deinked pulp was slightly lower than that of the chemical deinked pulp. But, by additions of nonionic surfactants, the brightness of deinked pulp was increased with less residual ink particles and mechanical properties of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

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Deinking of Electrostatic Wastepaper with Cellulolytic Enzymes and Surfactant in Neutral pH

  • Eom, Tae-Jin;Kim, Kang-Jae;Yoon, Kyoung-Dong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.5
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    • pp.12-19
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    • 2007
  • Enzymatic deinking method can avoids the alkaline environment as usual required in chemical deinking, which consequently cuts chemical costs and reduced the white water pollution. The electrostatic wastepaper was dinked with commercial cellulolytic enzymes and surfactant in neutral pH and the effectiveness of deinking and the physical properties of deinked pulp were evaluated. The disintegrating efficiency of the electrostatic wastepaper in neutral pH was enhanced with enzyme treatments. Although the freeness of deinked pulp with enzymes was higher than that of deinked pulp with chemical de inking agents, the brightness of the enzymatic deinked pulp was slightly lower than that of the chemical deinked pulp. But, by additions of nonionic surfactants, the brightness of deinked pulp was increased with less residual ink particles and mechanical properties of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

Neutral Deinking of Old Newsprints Contaminated with Flexo Ink

  • Hoon Ryu;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.5
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    • pp.10-16
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    • 2003
  • Presence of small amount of old newspapers printed with waterbased flexographic inks leads to a significant loss of brightness of the deinked pulp by flotation process. Recently there has been an increased interests in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. Effects of the deinking processes on pulp quality and white water characteristics were examined. It was shown that neutral deinking would provide significant improvement in brightness, yield, and freeness as compared with conventional alkaline deinking. There was no increase in brightness when OMG was added in the furnish up to 20 %, and it was attributed to the redeposition of flexo inks on chemical pulp fibers.

NEUTRAL DEINKING OF OLD NEWSPRINTS CONTAMINATED WITH FLEXO INK

  • Hoon Ryu;Lee, Hak-Lae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.343-348
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    • 1999
  • Presence of small amount of old newspapers printed with waterbased flexographic inks leads to a significant loss of brightness of the deinked pulp by flotation process. Recently there has been an increased interests in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. Effects of the deinking processes on pulp quality and white water characteristics were examined. It was shown that neutral deinking would provide significant improvement in brightness, yield, and freeness as compared with conventional alkaline deinking. Three was no increase change in brightness when OMG was added in the furnish up to 20%, and it was attributed to the redeposition of flexo inks on chemical pulp fibers.

Preparation and Characteristics of Alkaline -active Cellulases from Coprinaceae

  • Lee, Jung-Kyung;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.68-76
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    • 1999
  • Coprinus cinereus 2249 producing alkaline-active cellulase was screened from 29 species of Corpinaceae and constitutively produced alkaline carboxymethyl cellulase (CMCase) and filter paper cellulase (Fpase). When cultivated at pH 9.0, 25$^{\circ}C$ and 5 days, copnnus cinereus 2249 produced higher alkaline activity on 0.5% CMC, 2% wheat bran as carbon source and 0.5% peptone, 0.05% yeast extract as nitrongen source compared with other culture conditions. The level of cellulase production was higher in the presence of wheat bran than in the presence of CMC. The optimum temperature and pH for alkaline -active cellulase activity weas 50$^{\circ}C$ and 9, 0, respectively.

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Aging Behavior of Beeswaxed Hanji(II) - Acidic and Alkaline Aging of Beeswaxed Hanji - (밀랍지의 열화 거동 (제2보) - 산 및 알칼리에 의한 밀랍지의 열화 -)

  • Kim, Kang-Jae;Lee, Min-Hyung;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.66-72
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    • 2011
  • The annals of Joseon Dynasty is one of UNESCO's Memory of the World Register. For the safety preservation of the waxed annals of Joseon Dynasty, the acidic and alkaline aging mechanism of beeswax and beeswaxed Hanji has been investigated. The weight loss of beeswaxed Hanji by the acidic aging was higher than those of alkaline beeswax. The acid value and relative intensity of carbonyl groups in beeswax were slowly increased with aging time. The strength of dewaxed Hanji was decreased with aging time. The significant changes of crystallinity of dewaxed Hanji by acidic and alkaline aging were not observed.

Gene Expression of Exposure to Mineral Trioxide Aggregate(MTA) on Dental Pulp Cells (Mineral Trioxide Aggregate(MTA)에 의한 치수세포의 유전자 발현변화)

  • Choi, Yu-Seok;Lee, Nan-Young;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.1
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    • pp.30-38
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    • 2008
  • Dental pulp cells are assumed to possess the capacity to elaborate both bone and dentin matrix under the pathological conditions following tooth injury. The purpose of this study is to examine the effects of mineral trioxide aggregate (MTA) on various gene expression regarding dentinogenesis and cell viability assay in cultured primary human dental pulp cells. The author also examined the effects of this material on cellular alkaline phosphatase activity as a potential indicator of dentinogenesis. For gene expression on MTA, reverse transcriptase polymerase chain reaction was performed using primer sets of glyceraldehyde-3-phosphate dehydrogenase, type I collagen, alkaline phosphatase(ALP), osteonectin, and dentin sialoprotein after 2 and 4 days. Cell viability assay showed that the proportion of MTA-treated pulp cells which had been exposed for 5 days to MTA was higher than that of the control cells. Among the genes investigated in this study, ALP and osteonectin(SPARC) were increased in MTA treated group than in control. These findings suggest that this dental pulp culture system may be useful in the future as a model for studying the mechanisms underlying dentin regeneration after the treatment with MTA. Exposure to MTA material would not induce cytotoxic response in the dental pulp cells. In addition, MTA could influence the behavior of human pulp cells by increasing the ALP activity and SPARC synthesis.

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Mineralization-inducing potentials of calcium silicate-based pulp capping materials in human dental pulp cells

  • Kang, Sohee
    • Journal of Yeungnam Medical Science
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    • v.37 no.3
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    • pp.217-225
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    • 2020
  • Background: This study was performed to provide a long-term bacterial seal through the formation of reparative dentin bridge, calcium silicate-based pulp capping materials have been used at sites of pulpal exposure. The aim of this study was to evaluate the mineralization-inducing potentials of calcium silicate-based pulp capping materials (ProRoot MTA [PR], Biodentine [BD], and TheraCal LC [TC]) in human dental pulp cells (HDPCs). Methods: Specimens of test materials were placed in deionized water for various incubation times to measure the pH variation and the concentration of calcium released. The morphology of HDPCs cultured on the specimens was examined using a confocal laser scanning microscope (CLSM). Alizarin red S staining and alkaline phosphatase assays were used to evaluate mineralization-inducing potentials of the capping materials. Results: BD showed the highest calcium release in all test periods, followed by PR and TC. (p<0.05). All experimental groups showed high alkalinity after 1 day, except at 14 days. BD showed the highest cell viability compared with PR and TC after 1 and 3 days, while TC showed the lowest value (p<0.05). The CLSM analysis showed that cells were well adhered and expressed actin filaments for all pulp capping materials. Mineralization by PR and BD groups was higher than that by TC group based on alizarin red S staining. BD showed significantly higher alkaline phosphatase activity than PR and TC, while TC showed the lowest value (p<0.05). Conclusion: Within the limitations of the in vitro study, BD had higher mineralization-inducing potential than PR and TC.