• Title/Summary/Keyword: Alkali-activated cement

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Influence of Water Glass on Strength of Fly Ash-Cements (플라이 애쉬-시멘트의 강도특성에 대한 물유리의 영향)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Sang-Ho;Rim, Yu-Sup;Kim, Dong-Kuk;Kim, Se-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.661-666
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    • 2006
  • The compressive strength of a paste composed of a low-calcium Class F fly ash and alkaline activator solutions was investigated. These activator solutions, made with sodium hydroxide, water glass and water, have a very high $OH^-$ concentration. The composition of alkaline activator solution and temperature have been shown to notably influence the development of the compressive strength of the fly ash-cements paste. Compressive strength of 50 MPa could be achieved by curing of the fly ash at $60^{\circ}C$ for 48 hrs or $85^{\circ}C$ for 24 hrs. This study presented the optimum mixing ratio of Class F fly ash/sodium hydroxide/water glass as 25:8:2 in weight basis, and activator/fly ash as 0.6/1.0 for high strength paste.

Evaluation on Chloride Binding Capacity of Mineral Mixed Paste Containing an Alkaline Activator (알칼리 활성화제를 사용한 무기질 혼합 페이스트의 염화물이온 고정화 평가)

  • Cho, Gyu-Hwan;Yeo, In-Hwan;Ji, Dong-Hun
    • Journal of the Korea Concrete Institute
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    • v.28 no.2
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    • pp.157-165
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    • 2016
  • It is possible to achieve high strength ranging from 40 MPa to 70 MPa in alkali-activated slag concrete (AASC), and AASC is also known to have a finer pore structure due to its high latent hydraulicity and fineness of slag cement, which makes it difficult for chloride ions to penetrate. Electrophoresis is mostly used to calculate the effective diffusion coefficient of chloride ions, and then to evaluate resistance to salt damage. Few studies have been conducted on the fixation capacity of chloride ions in AASC. For this reason, in this study the chloride fixation within the hardened paste was evaluated according to the type and the amount of alkaline activators. As a result, it was revealed that among the test specimens, the chloride fixation was greatest in the paste containing $Na_2SiO_3$. In addition, it was found that as more activator was added, a higher level of chloride fixation was observed. Through this analysis, it can be concluded that the type and the amount of alkaline activators have a high correlation with the amount of C-S-H produced.

Material Property Evaluation for UFFA Rapid Setting Concrete including Calcium Hydroxide (수산화칼슘을 첨가한 UFFA 초속경 콘크리트의 물성특성 평가)

  • Jeon, Sung-Il;Nam, Jeong-Hee;An, Ji-Hwan;Kwon, Soo-Ahn
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.189-198
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    • 2008
  • Generally, UFF A(Ultra Fine Fly Ash) has merit that advances a greater concrete workability and activates a greater pozzolanic reaction than common fly ash due to its ultra fine particle size. These properties enhance concrete durability by reducing permeability and increasing resistance of alkali silica reaction(ASR) and sulfate attack, etc. Due to these reasons, UFFA can be used in a rapid setting concrete. The purpose of this study is to develop and evaluate the rapid setting concrete with UFF A as a repair material for early-opening-to-traffic. In previous studies, if only UFFA is added to the rapid setting concrete mixture, pozzolanic reaction doesn't happen actively. Therefore, in this study, the chemical and physical tests were performed for rapid setting concrete with UFFA including calcium hydroxide and the activity of pozzolanic reaction was evaluated. Finally, the effectiveness of this mixture on enhancing concrete durability was investigated. As results, adding UFF A decreased the water/cement ratio of concrete, and compensated the reduced portion of the early strength of concrete. Also, rapid setting concrete with UFFA including calcium hydroxide activated a greater pozzolanic reaction than normal-UFF A concrete. As calcium hydroxide increases, electrical indication of concrete's ability to resist chloride ion penetration is promoted significantly.

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