• Title/Summary/Keyword: Alkali sulfate

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A Hardening Properties of Eco-Friendly SCW Grouting Material (친환경 SCW공법용 그라우팅재의 경화특성)

  • Jo, Jung-Kyu;Park, In-Wook;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.2
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    • pp.109-115
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    • 2018
  • Since the current method of SCW cement milk pouring method uses one to one ratio of cement milk with OPC, there are some problems such as drying shrinkage, increased cost, difficulty of controlling mix proportions for various conditions of applied soil, and precipitation of $Cr^{6+}$ due to the excessively used cement. Specifically, in aspect of sustainability issues of cement manufacturing, the consumption of cement should be reduced. Hence, in this research, as a replacement of cement for SCW method, blast furnace slag with sulfate or alkali as a stimulant, and expansive admixture were used. By using blast furnace slag as a hardening composite of SCW, there are many advantages such as free controllable mix proportions, rapid setting time with less mud occurrence, less cost with less energy for mixing, constant strength development, and less precipitation of $Cr^{6+}$. Regarding the alternative composites for SCW, in this research, durability and chloride resistance were evaluated.

Degradation of Cement Mortar with Supplementary Cementitious Materials Submerged in Various Oils (각종 유지류에 침지된 혼화재 치환 시멘트 모르타르의 열화특성)

  • Han, Cheon-Goo;Hwang, Chan-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.137-143
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    • 2017
  • There has been a number of research on concrete durability. specially, as a research on chemical ingression, the research on the degradation against acid, alkali, and sulfate has been conducted. On the other hand, for the research on oils, especially, the influence of various oils on cement mortar with Supplementary Cementitious Materials(SCMs) is not sufficiently studied. hence, in this research, the degradation of cement mortar incorporated fly ash and blast furnace slag is researched when the cement mortar is submerged in various oils. For the result of experiment, as the content of fatty acid in the oils, the degradation of cement mortar with SCMs was occurred more, and the cement mortar with SCMs suffered more degradation than the ordinary portland cement regarding the oil submerging.

Purification of Materials Produced by Amylocolatosis sp. and Anticancer Effect in Oral Cancer Model (Amylocolatosis sp.가 생산하는 항암물질의 정제 및 구강암 모델에 미치는 항암 효과)

  • Kim, Jung;Park, Young-Min;Lim, Do-Seon
    • Journal of dental hygiene science
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    • v.3 no.1
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    • pp.11-14
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    • 2003
  • A methylotrophic Actinomycetes strain, which produce the anti-oral cancer activity compound, was isolated from soil and estimated as Amylocolatosis sp. based on taxonomic studies. A methanol didn't have influence on the production of the anticancer compounds. These compound were isolated by ethylacetate extract, silica gel column chromatography, sephadex LH-20 column and reverse phase HPLC. The compounds were very stable under heat ($121^{\circ}C$), acid(pH 2.0) and alkali(pH 11.0) treatment. The cytotoxic effect of isolated anticancer compounds on various cancer cell lines such as A549, SNU-1, KB, L1210, and Sarcoma 180 was investigated by MTT assay method. And these produced compounds also showed the broad antimicrobial spectrum to test strains such as bacteria and yeast.

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Anti-degradation of Various Mortar Mixtures Depending on Oil Submerging Conditions (모르타르 배합비별 각종 유지류 침지에 따른 열화저항성)

  • Han, Cheon-Goo;Hwang, Chan-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.219-225
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    • 2017
  • The durability factors of concrete has been researched by many researchers. Among the chemical ingression by acid, alkali, or salt, specially the ingression by sulfate has been actively studied and reported. Generally, for the oil type chemical, it is reported to cause the excessive expansion of cement mortar and further to cause the collapse, while there was no enough research on influence of oil type, relationship with microstructure of mortar, and collapse pattern. Therefore, in this research, using the various oils from general market, the degradation properties of the mortar mixtures with various mix designs were evaluated. according to the experiment, Bio diesel damaged worst and the mix design with less cement content showed the worst damage against oils.

Geochemistry of Geothermal Waters in Korea: Environmental Isotope and Hydrochemical Characteristics II. Jungwon and Munkyeong Areas (한반도 지열수의 지화학적 연구: 환경동위원소 및 수문화학적 특성 II. 중원 및 문경 지역)

  • Yun, Seong-Taek;Koh, Yong-Kwon;Choi, Hyen-Su;Youm, Seung-Jun;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.31 no.3
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    • pp.201-213
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    • 1998
  • From the Jungwon and Munkyeong areas which are among the famous producers of the carbonate-type groundwaters in Korea, various kinds of natural waters (deep groundwater, shallow groundwater and surface water) were collected between 1996 and 1997 and were studied for hydrogeochemical and environmental isotope (${\delta}^{34}S_{so4}$, ${\delta}^{18}O$, ${\delta}D$)systematics. Two types of deep groundwaters (carbonate type and alkali type) occur together in the two areas, and each shows distinct hydrogeochemical and environmental isotope characteristics. The carbonate type waters show the hydrochemical feature of the 'calcium(-sodium)-bicarbonate(-sulfate) type', whereas the alkali type water of the 'sodium-bicarbonate type'. The former type waters are characterized by lower pH, higher Eh, and higher amounts of dissolved ions (especialJy, $Ca^{2+}$, $Na^{+}$, $Mg^{2+}$, $HCO_3{^-}$ and $SO_4{^{2-}}$). Two types of deep groundwaters are all saturated or supersaturated with respect to calcite. Two types of deep groundwaters were both derived from pre-thermonuclear (about more than 40 years old) meteoric waters (with lighter 0 and H isotope data than younger waters, i.e., shallow cold groundwaters and surface waters) which evolved through prolonged water-rock interaction. Based on the geologic setting, water chemistry, and environmental isotope data, however, each of these two different types of deep groundwaters represents distinct hydrologic and hydrogeochemical evolution at depths. The carbonate type groundwaters were formed through mixing with acidic waters that were derived from dissolution of pyrites in hydrothermal vein ores (for the Jungwon area water) or in anthracite coal beds (for the Munkyeong area water). If the deeply percolating meteoric waters did not meet pyrites during the circulation, only the alkali type groundwaters would form. This hydrologic and hydrogeochemical model may be successfully applied to the other carbonate type groundwaters in Korea.

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Hydrogeochemistry and Contamination of Meteoric Water at the Narim Mine Creek, Korea (나림광산 수계에 분포하는 순환수의 수문지구화학 및 오염)

  • 이찬희
    • Economic and Environmental Geology
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    • v.32 no.4
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    • pp.385-398
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    • 1999
  • The Narim gold mine is located approimately 200km southeast of Seoul within the Muju mineralized district of the Sobaegsan gneiss complex, Korea. Environmental geochemistry were undertaken for various kinds of water (surface, ground and mine water) collected of April, September and November in 1998 from the narim mine creek. Hydrogeochemical compositions of water samples are characterized by the relatively significant enrichment of Na+K, alkali ions, $HCO_{3}$, $NO_{3}$, Cl and F in groundwater, wheras the mine and surface waters are relatively enriched in Ca+Mg, hea표 metals and $SO_{4}$. Therefore, the groundwaters belong to the (Na+Ca)-( $HCO_{3}+SO_{4}$) type, respectively. The pH and EC values of the non-mining creek surfers are relatively lower compared with those of the surface water of the mine and ore dump area. The d values ($\delta$D-8$\delta^{18}$O) of all kinds of water from the Narim mine creek are 5.8 to 13.1 The range of $\delta$D and $\delta^{18}$O values (relative to SMOW) are shown in distinct two groups as follows: for the April waters of -64.8 to -67.8$\textperthousand$ and -9.6 to -10.0$\textperthousand$(d value=10.1 to 13.1), and for the November waters of -65.9 to -70.2$\textperthousand$ and -9.3 to -9.6$\textperthousand$ (d value=5.8 to 7.9), respectively. This range variation indicates that two group water were composed of distinct waters with seasonal difference. Geochemical modeling showed that mostly toxic metals (As, Fe, Mn, Ni, Pb, Zn) may exist largery in the from of metal $(M2^+)$ and metal-sulfate $(MSO_4\;^{2-$\mid$),\; and \;SO_4^{2-$\mid$}$ concentration influenced the speciation of heavy metals in the meteoric water. These metals in the groundwater could be formed of $CO_3 \;and \;(OH)_3$ complex ions. Using computer program, saturation index of albite, calcite, dolomite in meteoric water show undersaturated and progreddively evolved toward the saturation state, however, ground and mine water are nearly saturated. The gibbsited water-mineral reaction and stabilities suggest that the weathering of silicate minerals may be stable kaolinite, illite and Nasmectite. The clay minerals will be transformed to more stable kaolinite owing to the contiunous reaction.

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Studies on Zinc deficiency in paddy soil -I. Zinc deficiency of the rice plant in Korea and Philippine soils (답토양(畓土壤)에서의 아연결핍(亞鉛缺乏)에 관(關)한 연구(硏究) -I. 수도(水稻)에 있어서 아연결핍(亞鉛缺乏)에 관(關)한 한국(韓國)과 비율빈 답토양(畓土壤)에 대(對)한 비교연구)

  • Ahn, Jong Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.5 no.1
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    • pp.41-47
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    • 1972
  • An experiment was conducted to study the zinc deficiency of rice plant grown on Boeun soil of Korea and on Batangas soil of the philippines. The results obtained are summarized as follows: 1. Batangas soil was deficient in zinc because of the high pH, high organic matter and high calcium. Zinc content of the rice plant grown on Batangas soil was l6ppm. On the other hand, Boeun soil had low organic matter. Zinc content of the rice plant grown on Boeun soil was 33ppm. 2. The top leaf had higher zinc content than any other leaves. Zinc deficiency apparently occured when the zinc content of the rice plant was below 18ppm. 3. The physiologically acid fertilizer such as ammonium sulfate was more advantageous in improving zinc up take than the urea. 4. The zine deficiency was promoted when the Mn/Zn ratio is high, and zinc and manganess interact antagonistically in the growth of rice plant. 5. The zinc deficiency could be overcome by applying zinc chloride and fritted Trace elements to the Batangas soil, and the yield was significantly increased than conrtol.

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Properties of Non-Sintered Cement Mortar using Alkali and Sulfate Mixed Stimulants Accroding to Curing Method (양생방법에 따른 알칼리 및 황산염 복합자극제를 사용한 비소성 시멘트 모르타르의 특성)

  • Park, Sung-Joon;Kim, Ji-Hoon;Hyung, Won-Gil
    • Journal of the Korea Concrete Institute
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    • v.27 no.3
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    • pp.237-244
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    • 2015
  • Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

Material Property Evaluation for UFFA Rapid Setting Concrete including Calcium Hydroxide (수산화칼슘을 첨가한 UFFA 초속경 콘크리트의 물성특성 평가)

  • Jeon, Sung-Il;Nam, Jeong-Hee;An, Ji-Hwan;Kwon, Soo-Ahn
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.189-198
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    • 2008
  • Generally, UFF A(Ultra Fine Fly Ash) has merit that advances a greater concrete workability and activates a greater pozzolanic reaction than common fly ash due to its ultra fine particle size. These properties enhance concrete durability by reducing permeability and increasing resistance of alkali silica reaction(ASR) and sulfate attack, etc. Due to these reasons, UFFA can be used in a rapid setting concrete. The purpose of this study is to develop and evaluate the rapid setting concrete with UFF A as a repair material for early-opening-to-traffic. In previous studies, if only UFFA is added to the rapid setting concrete mixture, pozzolanic reaction doesn't happen actively. Therefore, in this study, the chemical and physical tests were performed for rapid setting concrete with UFFA including calcium hydroxide and the activity of pozzolanic reaction was evaluated. Finally, the effectiveness of this mixture on enhancing concrete durability was investigated. As results, adding UFF A decreased the water/cement ratio of concrete, and compensated the reduced portion of the early strength of concrete. Also, rapid setting concrete with UFFA including calcium hydroxide activated a greater pozzolanic reaction than normal-UFF A concrete. As calcium hydroxide increases, electrical indication of concrete's ability to resist chloride ion penetration is promoted significantly.

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The Effect of Lime and Wollastonite on an Acid Sulfate Soil (특이산성토에 대한 석회 및 규회석의 효과)

  • Park, Nae Joung;Park, Young Sun;Lee, Kyu Ha;Kim, Yung Sup
    • Korean Journal of Soil Science and Fertilizer
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    • v.5 no.1
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    • pp.25-32
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    • 1972
  • The effects of limestone and wollastonite on an acid sulfate soil were studied. In addition, the effect of wollastonite was analyzed in terms of those due to calcium and to silica in the paddy field and in the laboratory with equivalent amounts of lime and wollastonite on a calcium basis. 1. Lime and wollastonite as liming materials were equally effective in neutralizing the soil acidity. 2. Lime, however was more reactive, raising the pH up to neutralization point in three days under waterlogged conditions at $25^{\circ}C$, in the lab study, and introduced alkali damage to transplanted rice seedlings showing marked restrictions of tillering in the field even though lime was applied two weeks before transplanting. On the other hand, wollastonite reacted very slowly, taking one week to two weeks to reach neutralization even when thoroughly mixed, and did not restrict the tillering. 3. Both lime and wollastonite effectively reduced the toxic aluminium in soil as well as in the soil solution but not always in the case of ferrous iron. However the reduction effect of the toxic substances in the experimental field was not so great as expected, because typical toxic symptoms were mild only. 4. Lime considerably increased the availability of silica in soil resulting in an increase of silica content in straw. Wollastonite released extra available silica itself resulting in a greater uptake of silica. 5. Increase of silica uptake by these materials was effective in reducing rate of infection of neck blast and resulted in higher rate of ripening, and in turn increased the paddy yield. 6. Application of either one significantly diminished the effect of the other. 7. Wollastonite markedly increased tillering in the early growing stage, but decreased the rate of effective tillers finally, resulting in about the same number of ears per hill at harvesting. 8. These liming materials appear to increase the number of grains per panicle slightly.

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