• The Korean Journal of Ecology
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• 제21권5_1호
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• pp.457.1-463
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• 1998

the research has been made for alkali and metal element concentrations in top soils and plants from the abandoned coal mine, Keumsan, Chungnam Province. Samples of the top soil and plant (Miscanthus sinensis and Pinus rigida) were collected from the mine area in which was divided into t재 regions the polluted region influenced by the coal mining and the non-polluted region. pH of the top soils was 3.16-4.33 in the polluted region. Ca, Sr and P concentrations were high in the polluted soils, and Al and Ba concentrations were high in the non-polluted soils. No differences were found in K, Na and Ti concentrations. M. sinensis was higher in the element concentrations than P. rigida. In the average concentration of the alkali and metal element, M. sinensis showed high Cs and Na in the polluted region, and high Ba, Ca, K, Sr and concentrations in the non-polluted region. P. rigida had high Cs, Na and Rb concentrations in the polluted region. M. sinensis and P. rigida were higher in the root than above-ground part in the most element, but Ca and K. Ca, K and Na concentrations within both plants had higher than those of soils.

• 한국세라믹학회지
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• 제13권4호
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• pp.15-19
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• 1976

Mutual interferences of alkali and alkali-earth metals in atomic absorption were examined. For determination of Na or K interfering elements increase the absorbancy, and for Ca or Mg decrease. Since influences of coexisting elements become nearly constant by addition of large amount of same coexisting element, could be use mixed standard solution for alkali or alkali-earth metal determination in the presence of other alkali and alkali-earth metals. The metals can be readily incorporated into scheme of rapid silicate analysis. Precision and accuracy are good.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집B
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• pp.956-961
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• 2000

This paper describes the design of a small size Alkali Metal Thermal to Electric Converter (AMTEC) which employs a capillary structure for recirculating sodium working fluid. The cycle is based on the simple and small capillary type ${\beta}"$ -alumina and wick tube element. The proposed cell consists of the 37 conversion elements with capillary tube of $50{\mu}m$ in diameter and the sealed cylindrical vessel of 22mm in outer diameter. Results on the cycle analysis of sodium flow and heat transfer in the cell showed that the expected power output was 4.65W and the conversion efficiency was 19% for the source temperature of 900K.

• 한국동물학회:학술대회논문집
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• 한국동물학회 1997년도 한국생물과학협회 학술발표대회
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• pp.156.2-156
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• 1997

No Abstract, See Full Text

• 한국전기전자재료학회논문지
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• 제27권1호
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• pp.50-55
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• 2014

It was firstly found in 1st group element. Recently, it has been reported on the improvement of efficiency of the OLEDs by introducing thin layer of some carbonate materials of alkali metal. In order to improve the efficiency of OLEDs which is one of the next generation displays, we have studied the electrical characteristics of the device depending on the thickness ratio of the hole-injection layer to the electron-injection layer. Teflon-AF was used as the hole-injection material, and alkali-metal carbonates of $Li_2CO_3$ were used as the electron-injection materials. To obtain a proper thickness ratio, we manufactured. Four types of devices with the thickness ratio of HIL to EIL were made to be 1 : 4, 2 : 3, 3 : 2, and 4 : 1. The results of electrical and optical properties showed that the device with the thickness ratio of 4 : 1 is the most excellent result. In addition, to prepare a four-layer device by inserting the ${\alpha}$-NPD is a hole transporting material was compared with three-layer element. As a result, the maximum luminance, the maximum luminous efficiency, maximum external quantum efficiency of about 124 [%], 164 [%], 106 [%] improve was confirmed.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2867-2872
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• 2010

Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

• 암석학회지
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• 제5권1호
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• pp.66-83
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• 1996

이 연구는 알칼리 화산도로 특정지워진 제주도의 동부 성읍리, 서부 한림읍 이사돌 그리고 한경면고산리 지구내 해안에 분포하는 수매의 솔리아이트에 대한 암석기재, 광물화학, 주성분 및 미량성분 원소의 화학자료를 보고한다. 이들은 주로 반상조직인 알칼리암류에 비해 세립질이며, 주상 혹은 침상의 사장석 ($An_{61-46}$)과 사방휘석(브론자이트) 및 감람석($Fo_{78-67}$)이 입자간 조직을이룬다. 특징적으로 사방휘석이 반자형의 반정 혹은 미반정으로 산출되고, 두 유형의 단사휘석(피저나이트와 보통 휘석)은 석기 광물로만 산출한다. 이들 솔리아이트는 노옴 석영을 가지며, 주성분 원소의 변화 범위는 좁다(SiO2=51.0-52.5 wt%; Mg#=54-60). 주성분 원소와 전이금속 원소의 변화경향이 알칼리암ㄹ와 두드러진 것은 동일 마그마의 분화로 솔리아이트와 알칼리암의 관계를 설명할 수 없다는 것을 시사한다. 한편, $K_2O$, Rb, Ba, Nb, La들 간의 비는 솔리아이트와 알칼리암이 유사한 반면, P, Y, Yb 등 석류석과 친화적인 원소와 이 원소들 간의 비는 솔리아이트가 알칼리암보다 크다. 이러한 미량원소 특징은 제주도의 솔리아이트와 알칼리 현무암류는 동질 기원이나 부분용융정도가 다른 모마그마로부터 유래되었음을 시사한다.

• 한국응용과학기술학회지
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• 제31권3호
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• pp.394-401
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• 2014

In order to minimize a building energy consumption with ventilation, a development of smart ventilation system is very important. In this study, a dry adsorbent that is main element of smart ventilation system was developed for removing indoor $CO_2$, and evaluate the adsorption performance. Specific surface area, pore characteristic and crystal structure of the modified sorbent was measured to analyze physical properties. From this analysis, it was found that the developed absorbent has a low specific surface area, due to mesopores of substrate was filled with metal contained raw material. Additionally, through analysis of the adsorption properties, the developed adsorbent was shown a adsorption form of mesopore (type IV), which means adsorption amount was rapidly increased at the part of high-pressure. Order to applying for the field, chamber test was performed. Continuous column tests (2,500 ppm) and batch chamber tests ($4m^3$, 5,000 ppm) showed $CO_2$ removal efficiency of 95% and 88% within 1 hour, respectively.

• 자원리싸이클링
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• 제6권3호
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• pp.3-8
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• 1997

I사의 전기로 제강 슬래그(이하 슬래그)는 상당량의 금속철(metal Fe)과 wustite(FeO), magnetite(Fe$_3$O$_4$), gehlenite(${CaAl}_{2}{SiO}_{7}$) 및 monticellite(CaMgSiO$_4$)등으로 구성된다. 슬래그에 함유된 금속철(Fe 품위: 95%이상)을 회수하기 위해서는 금속철을 단ㄱ체로 분리시키는 것이 바람직하며, 매립으로 활용할 수밖에 없는 슬래그를 단계적으로 파쇄하면 대부분의 금속철은 구상의 단체로 분리된다. 구상의 단체인 금속철의 크기에 따라 흡인되는 자장의 세기를 측정하면 금속철이 흡인되는 최소 자장의 세기는 약 100G로 거의 일정하다. 다단계로 파쇄한 슬래그를 100G의 자장에서 회수한 산물은 95%이상의 철분이 함유된 금속철이었으나, 자장의 세기를 증가시키면 철의 산화물 및 알칼리 토금속류의 화합물등도 함께 회수되므로 품위가 저하된다. 따라서 매립되는 슬래그를 다단계로 파쇠하고, 각 입도에서 100G로 자선하면 파쇄된 슬래그에 함유된 대부분의 금속철을 회수할 수 있다. I사에서 매립하는 35만톤의 슬래그를 다단계로 파쇄하는 경우에, 30~4.7mm의 입도에서는 매립되는 전체 슬래그중의 약 0.73%인 2천 5백톤 정도의 금속철이 100G의 자장에서 회수될 수 있고, 4.7~0.3mm서도 약 1.2%인 4천 2백톤 정도가 회수될 수 있다. 그러므로 자력선별로 회수할 수 있는 금속철은 매립되는 슬래그중의 약 1.9%인 6천 7백톤 정도가 된다.

• 한국재료학회지
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• 제19권7호
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• pp.386-390
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• 2009

Niobium(Nb) and Tantalum(Ta) are rarely found apart in nature and never in the free state. The element niobium amounts to 3% of the crustal abundance. On the whole, the niobium capacitor showed somewhat more unstable characteristics than the commercial tantalum capacitors, but is nonetheless considered applicable as a future substitute for tantalum capacitors. In this study, niobium powder was made from potassium heptafluoroniobite($K_2NbF_7$) by using sodium(Na) as a reductant and KCl and KF as diluents based on the hunter sodiothermic reduction method.,In order to obtain a high surface area niobium powder via the sodiothermic reduction method, a certain amount of diluent, such as alkali metal halides selected from NaCl, KCl, KF and NaF, was added in the raw materials to be reduced. However, if a higher surface area of powder is required, more diluents need to be used in the said method in order to produce niobium powder. But when more diluents are used, the niobium powder will be contaminated with more impurities and the yield will also decreased.