• 제목/요약/키워드: Alkali activated

검색결과 255건 처리시간 0.034초

잔골재의 투입시점에 따른 알칼리 활성화 슬래그 모르타르의 강도와 건조수축에 대한 기초적 연구 (The Fundamental Study of Strength and Drying Shrinkage on Alkali-activated Slag Cement Mortar with Different Entering Point of Fine Aggregate)

  • 김태완;엄장섭;서기영;박현재
    • 한국구조물진단유지관리공학회 논문집
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    • 제18권2호
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    • pp.117-125
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    • 2014
  • 본 연구는 수산화나트륨(NaOH)으로 활성화된 알칼리 활성화 슬래그 시멘트(alkali-activated slag cement; AASC)의 기초 특성에 관한 실험에 관한 연구이다. 물-결합재 비(W/B)를 0.4와 0.5로 하였다. 그리고 활성화제의 농도를 2M과 4M을 사용하였다. 각 W/B 비에 대해 5가지의 배합을 고려하였다. N0는 KS L 5109의 방법이고 N1~N4는 배합시간, 배합 단계 그리고 잔골재의 투입시점을 다르게 변화시켰다. 시험결과 AASC의 플로우 값, 강도 그리고 건조수축은 잔골재의 투입시점에 영향을 받았다. 플로우 값은 잔골재의 투입시점이 늦춰짐에 따라 감소하는 경향을 나타내었다. 압축강도와 휨강도는 투입시점이 늦어짐에 따라 증가하였다. 더구나 XRD 분석은 이러한 결과들을 뒷받침하고 있었다. 건조수축은 잔골재의 투입시점이 늦어지면 증가하였다. 본 연구에 고려된 실험요인들을 통해 배합을 조절한다면 AASC의 특성을 향상시킬 수 있을 것이다.

알칼리 자극제에 의한 고로수쇄슬래그의 활성화 특성 (Activation Property of Blast furnace Slag by Alkaline Activator)

  • 안지환;조진상;김형석;;한기석;김환
    • 한국세라믹학회지
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    • 제40권10호
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    • pp.1005-1014
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    • 2003
  • 알칼리 자극제의 종류에 따른 고로수쇄슬래그의 수화 및 물리적 특성을 조사하였다 활성화제는 $Na_2$SiO$_3$, $Na_2$CO$_3$, NaOH, $Na_2$SO$_4$를 사용하였고, $Na_2$SiO$_3$, $Na_2$CO$_3$, $Na_2$SO$_4$$Na_2$O, NaOH는 $\frac{1}{2}$$Na_2$O로 환산하여 1, 3, 5, 7 wt%를 첨가한 후 W/S=0.5로 실험을 실시하였다. 또한, 압축강도 실험은 OPC에 대해 각각 30 wt% 첨가하여 실험을 하였다. 활성화제의 종류에 따라 주요 수화생성물은 C-S-H, $C_4$AH$_{13}$, AFt, Al(OH)$_3$ 등이었으며, $Na_2$CO$_3$의 경우가 가장 큰 슬래그의 수화율을 보였다. $Na_2$SO$_4$를 사용하였을 때 압축강도가 가장 크게 나타났다.

Waste Glass as an Activator in Class-C fly Ash/GGBS based Alkali Activated Material

  • Sasui, Sasui;Kim, Gyu Yong;Lee, Sang Kyu;Son, minjae;Hwang, Eui Chul;Nam, Jeong Soo
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.77-78
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    • 2020
  • An alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali-activated material (AAM). The compressive strength and porosity were measured, and (SEM-EDX) were used to study the hydration mechanism and microstructure. Results indicated that the composition of alkali solutions was significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength. Further increase in WGP dissolution led to strength loss, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite also appeared to improve the strength which contributed to develop C-S-H-type hydration.

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Development of geopolymer with pyroclastic flow deposit called Shirasu

  • Katpady, Dhruva Narayana;Takewaka, Koji;Yamaguchi, Toshinobu
    • Advances in materials Research
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    • 제4권3호
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    • pp.179-192
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    • 2015
  • The study presents a preliminary investigation on the applicability of Shirasu (a pyroclastic flow deposit characterized by high percentage of volcanic glass) in geopolymer. Comparative study on compressive strength and internal pore structure has been done between geopolymers with alkali activated Shirasu and fly ash as aluminosilicates. Mortar mix proportions are selected based on variations in ratio of alkaline activators to aluminosilicate and also on silica to alkali hydroxide ratio. From the experimental study, Shirasu geopolymer exhibited fairly good compressive strength. Mix proportion based on silica to alkali hydroxide ratio is observed to have profound effect on strength development.

알칼리 활성법에 의한 Bottom Ash의 경화 특성에 관한 실험적 연구 (The Experimental Study on Hardening Characteristics of Bottom ash by Alkali Activation)

  • 오동욱;김백중;이종구;강경인
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2008년도 추계 학술논문 발표대회
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    • pp.103-106
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    • 2008
  • Because the physical·chemical properties of bottom ash are inferior, most bottom ash is disused. But the use of bottom ash helps in reducing environmental pollution and solving some bottom ash waste problems. So, we have been investigating about the optimum mixture, hardening mechanism, curing condition and environmental safety of a paste composed of a bottom ash and alkali. optimal mixing proportion of bottom ash solid was cement 5%, water 30%, NaOH 10%. After curing during 28days, bottom ash solid can be achieved compressive strength 15.13MPa. As a result, Compressive strength tests of alkali-activated bottom ash have potential as a replacement of coarse aggregate.

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첨착 ACF를 이용한 염기성 악취물질의 제거 (Removal of Alkali Odors using Impregnated ACFs)

  • 김기환;김덕기;최봉각;신창섭
    • 한국안전학회지
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    • 제13권1호
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    • pp.92-97
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    • 1998
  • Malodorous gases give discomfort and harm to laborers and residential neighborhoods and therefore, the removing odor materials emitted from plants and industrial facilities is important subject. The main ingredients of alkali odor are $NH_3$ and $CE_3SH$. The adsorption characteristics of odors were studied using four different activated carbon fibers(ACF) and active carbon(AC). Alkali odor was removed by using ACF impregnated with $H_3PO_4$ and $H_2SO_4$ and treated with $HNO_3$ and NaOH. The experimental result showed that ACF has a higher removal efficiency than AC. The adsorption capacity was increased with the impregnation and surface treatment, and $H_2SO_4$ was the best impregnant for the removal of alkali odor.

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알칼리 활성화 알루미노실리케이트계 경화체의 고온 열화 특성 (Degradation Propeties of Alkali-Activated Alumino-Silicate Composite Body Exposed to High Temperature)

  • 김원기;김홍주;이승헌
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.627-630
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    • 2005
  • This paper examines degradation properties of alkali-activated alumino-silicate composite body by NAS solution exposed to high temperature. Activators include sodium hydroxides and sodium silicate solution. In the result of experiment, flexural and compressive strength of AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than alumina cement base mortar. Particularly, In case of compressive strength, alumina cement base mortar was decreased by about $60\~70\%$. While, AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than that curing by room temperature. The above results showed that AAS base inorganic binder has a good mechanical properties exposed to high temperature($400\~600$).

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황산의 침해를 받은 슬래그 경화체의 특성 (The Acid-Resistance Properties of Hardened Alkali-Activated Slag Composites)

  • 김원기;소정섭;배동인
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.313-317
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    • 2003
  • The study is the results of accelerated tests and the specimens, mortars, are submerged in a 5% sulfuric acid solution. The deterioration of specimens is followed up by investigating the change in weight and compressive strength of the specimens and techniques such as XRD and XRF are used to examine the chemical changes. Sulfuric acid is a very aggressive acid that reacts with the free lime [$Ca(OH)_2$] in the concrete forming gypsum($CaSO_{4}.2H_{2}O$). This reaction is associated with an increase in volume of the concrete, and the corroded surface becomes soft and white. The results showed that the OPC mortar caused an decrease in weight above 18% and strength loss about 57%. On the other hand, AASC(alkali-activated slag composites) did not cause any decrease in weight and in the case of strength caused an decrease below 10%. In addition, this mechanical results was verified to XRD and XRF.

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알칼리활성 슬래그 콘크리트의 슬럼프 및 압축강도에 대한 단위결합재량의 영향 (Effect of Unit Binder Content on the Slump and Compressive Strength of Alkali-Activated Slag Concrete)

  • 조아람;양근혁;송진규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.361-362
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    • 2010
  • 알칼리활성 슬래그 콘크리트의 슬럼프 및 압축강도에 대한 단위결합재량의 영향을 알아보기 위해 6배합의 알칼리활성 슬래그기반 콘크리트가 실험되었다. 주요 변수로는 단위결합재량으로 300, 350, 400 및 550 kg/$m^3$이다. 실험결과 단위결합재량의 증가는 초기 슬럼프를 증가 시켰으며, 압축강도를 증가 시켰다.

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알칼리활성화 슬래그-레드머드 흙포장재의 현장 적용평가 (Field Application Assessment of Alkali-Activated Slag-Red Mud Soil Mixed Pavement)

  • 강혜주;황병일;김재환;강석표
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.107-108
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    • 2017
  • In this search, by evaluating the field applicability of soil mixed pavement of Red mud is mixed into the soil mixed pavement field applicability, and tries to present the basic data about the site application of recycling of red mud and low carbon construction material to. As a result, the conventional soil concrete organization standards (SPS-KSCICO-001: 2003) meets the criteria for parking lot, making use of red mud, natural color as well as the natural loess is expressed.

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