• Bulletin of the Korean Chemical Society
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• v.17 no.9
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• pp.840-845
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• 1996

Rate constants have been measured spectrophotometrically for the reactions of p-and m-nitrophenyl 2-thiophenecarboxylate (5a and 5b, respectively) with alkali metal ethoxides (EtO-M+) in absolute ethanol at 25.0±0.1 ℃. The reactivity of EtO-M+ exhibits dependence on the size of alkali metal ions, i.e. the reactivity of EtO-M+ toward 5a decreases in the order EtO-K+ ≥ EtO-Na+ > EtO-Li+ > EtO-, while the one toward 5b does in the order EtO-Na+ ≥ EtO-K+ > EtO-Li+ > EtO-. This result indicates that ion paired EtO-M+ is more reactive than dissociated EtO-, and alkali metal ions form complexes with the substrate more strongly at the transition state than at the ground state. The catalytic effect shown by alkali metal ions appears to be less significant in the reaction of 5 than in the corresponding reaction of 4, indicating that complexation of alkali metal ions with 5 is not as strong as the one with 4.

• Applied Biological Chemistry
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• v.27 no.3
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• pp.214-216
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• 1984

Alkali gelatinization of rice, corn, arrow root and ginger root starches at various sodium hydroxide concentrations was investigated. Critical concentrations of alkali for starch gelatinization ranged from 2.33 to 3.17 meq NaOH per gram of starch. Ginger root starch was most resistant to alkali gelatinization and arrow root starch was least stable to alkali.

• Cement Symposium
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• no.1
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• pp.69-91
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• 1973

To obtain a more accurate results in alkali analysis of cement and its raw materials we must solve some difficult problems. The most important problem is not only dissoloing the sample with keep up alkali content but compensating interference effects. Her

• Cement
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• s.49
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• pp.38-41
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• 1972

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.4
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• pp.69-75
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• 2014

Effects of alkali swelling of HwBKP (hardwood bleached kraft pulp) at a low concentration below 2 percent (based on the oven-dried weight of pulp) on handsheet properties were investigated. Swelling treatment of HwBKP was performed at various low NaOH concentrations with/without beating. Then, the changes in handsheet properties were evaluated in terms of bulk, optical and strength properties. It was found that bulk was slightly increased when the alkali concentration was increased. When the pulp was only swollen without beating, paper optical and strength properties was slightly decreased or not changed with alkali concentration. When the pulp was alkali-swollen after beating, paper strength and opacity showed almost no changes while brightness was increased. When the pulp was beaten after NaOH swelling, alkali concentration showed almost no effect on brightness and opacity of paper. Paper strength was slightly decreased with alkali concentration, suggesting that alkali pretreatment before refining could adversely affect refining efficiency.

• Magazine of the Korea Concrete Institute
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• v.6 no.2
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• pp.108-117
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• 1994

This study was performed to investigate the Alkali-Silica Reaction(ASR) of crushed stones using chemical analysis, polarization microscope, XRD, chemical method(KS F 2545, ASTM C 289), mortar-bar method( KS F 2546, ASTM C 227) and Scanning Electron Microscope (SEM ) and Energy Dispersive X-ray Analysis(EDXA) of reaction products by ASK in the mortar bars and to investigate the influence on alkali content and kind of added alkali to the ASR. Test results show that one kind of domestic crushed stone is estimated as deleterious by ASTM chemical method and mortar bar method, and reaction product is proved as alkali silicate gel by EDXA.

• Textile Coloration and Finishing
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• v.11 no.5
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• pp.22-29
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• 1999

The increase in color depth of polyester fiber dyed with black disperse dyes was investigated with respect to the kinds of resins and alkali treatment. The color depth of the dyed polyester fiber increased continuously according to the concentration of resins coated onto the fabrics. The alkali treatment to polyester fiber before dyeing also enhanced the color depth. It was thought that the polyester fiber was hydrolyzed by alkali resulting micropores on the sample. And the following treatment with a resin, Jet Black T-101, to the polyester fiber increased the color depth much higher. The successive process of alkali treatment, dyeing and Jet Black T-101 treatment could give the best color depth to polyester fiber. Although the alkali treatment reduced the tensile strength of polyester fiber, the color depth of polyester fiber enhanced sufficiently within the range of practically acceptable weight loss and strength. To analyze the micropore on the polyester fiber formed by alkali treatment, nitrogen porosimeter was used. As the weight loss of polyester fiber treated with alkali increased, the BET(Brunauer-Emmett-Teller) surface area, total pore volume, and average pore size of the sample increased.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.1015-1018
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• 2004

We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.65-72
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• 2014

In this study, effects of alkali swelling at low concentration below 2 percent on properties of hardwood bleached kraft pulp (HwBKP) were elucidated. Swelling treatment of HwBKP was performed at various NaOH concentrations with/without beating. Then, the swelling characteristics of pulp fiber was evaluated by measuring the solvent retention values such as water retention value (WRV) and isopropyl alcohol retention value (LRV). It was found that fiber characteristics were influenced by NaOH swelling even at low alkali concentration and beating treatment as well. The values of WRV and LRV were decreased when the alkali concentration was increased. It is the result from the decreased acidic groups of pulp which were formed during beating. The acidic groups could be neutralized and then removed by alkali. The difference between WRV and LRV was decreased with increasing alkali concentration while the difference was increased when the alkali swollen pulp was beaten. In addition, the crystalline structure of HwBKP was almost not changed while the crystallinity was influenced by swelling treatment at a low alkali concentration.

• Korean Journal of Food Science and Technology
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• v.39 no.6
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• pp.637-643
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• 2007

In this report, we discussed the physiochemical characteristics of corn starch during the alkali gelatinization process. Here, solubility and the amounts of eluted polysaccharides and amyloses increased in proportion to the amount of alkali added. The X-ray diffraction patterns and DSC thermogram showed that in the early stage of alkali gelatinization, crystallinity of the starch granules was disrupted as compared with heat gelatinization. This resulted in the eluted amylose content, while granule sizes were hardly changed in the alkali treated corn starch. The endotherm peak in the DSC thermogram shifted toward a higher temperature region as the degree of gelatinization increased, suggesting that the retained starch granules were more compactly crystallized during alkali gelatinization than during the heat process. Thus, we concluded that during the alkali gelatinization of corn starch, the disruption of weak particles would occur first, before swelling of the granules.