• Title/Summary/Keyword: Alkali

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Component Analysis and Antioxidant Activity of Plantago asiatica L. (질경이의 영양성분 분석과 항산화 활성)

  • Park, Sung-Jin;Sihn, Eon-Hwan;Kim, Cheun-An
    • Food Science and Preservation
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    • v.18 no.2
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    • pp.212-218
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    • 2011
  • The purpose of this study is to determine the possibility of using Plantago asiatica as natural health food source. To accomplish this purpose. the contents of proximate and anti oxidative nutrients of P. asiatica were measured. The contents of carbohydrate. crude protein. crude fat and crude ash are 63.71%, 18.75%, 1.67% and 6.48%, respectively And the calories and total dietary fiber of P. asiatica was 466.71 Kcal. Total dietary fiber was 22.68%, respectively. The contents of essential and non-essential amino acids were 4.815.22 mg and 6.591.04 mg, respectively. The K was the largest mineral followed by P, Ca, Mg, and Na, which means P. asiatica is alkali material. The EDA of P. asiatica was 59.32~70.30%, and the activity was dependent on the sample concentration. Total phenolic content of P. asiatica was $79.65{\mu}g/g$, and total flavonoids content was $4.43{\mu}g/g$. The P. asiatica extract showed the highest reducing power (3.5) at a concentration of 25 mg/mL. Based on the above results, we deemed that the P. asiatica might have potential antioxidant activities. The general nutrients and other antioxidant bioactive materials in P. asiatica were also potential materials for good health food.

Characteristics of Volatile Fatty Acids Release During the Hydrolysis of Rice Straw (볏짚의 가수분해과정중 유기산 생성 특성)

  • Hong, Seung-Gil;Shin, JoungDu;Heo, Jeong-Wook;Park, Woo-Kyun;Shin, Hyun-Seon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.2
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    • pp.36-43
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    • 2012
  • Objective of this study was to investigate the effects of pre-treatment of rice straw by sizes(3cm, milled), temperatures($35^{\circ}C\;and\;55^{\circ}C$), with/without NaOH treatment, and RPM on the characteristics of volatile fatty acids production. The concentration of total volatile fatty acids (TVFAs) was increased with the hydrolyzed time. Concentration of VFAs in milled rice straw was higher than that in 3 cm cut. With the alkali treatment, the concentration of TVFAs were sharply increased, which showed 3 times higher than non-treatment. Concentration of VFAs was high at 150 rpm at $35^{\circ}C$, and at 80rpm and 200 rpm at $55^{\circ}C$. Among them acetic acid was dominant, which showed the similar increase with TVFAs. It was also observed that in the case of fibrous material, the contents of cellulose and hemi-cellulose were reduced a little, but no change in lignin.

A Study on the Reduction of Harmful Compound in Cigarette Smoke [Part II] -Influence of solvont extraction- (담배 연기중(煙氣中)의 유해물감소(有害物減少)에 관한 연구(硏究)[제이보(第二報)] -용매추출(溶妹抽出)의 영향(影響)-)

  • Park, Taek-Kyu;Kim, Ki-Hwan
    • Applied Biological Chemistry
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    • v.22 no.1
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    • pp.58-63
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    • 1979
  • The solvent extracting of the tobacco has been carried out in order to find out any effects for the removal and/or reduction of nicotine from tobacco without affecting the tobacco flavor. We have now completed the physico-chemical characterization of the solvent untreated/treated tobaccos and 2) the contents of the tar and nicotine in the smoke. The results obtained ate like followings; 1. 3% alcohol extraction reduced the total nitrogen content for the Bright by 36.4%. However, it could not reduce the sugar content. 2. Nicotine content in tobacco leaves was inversely proportional to the dipping time Essentially same results were obtained in anacidic solution and even in a solution containing both alkali and acid. 3. Derivative thermogravimetric(DTG) curves indicated test extraction was effective by removing tobacco leaf components which could decompose or volatilize between the temperature of $150^{\circ}C\;and\;350^{\circ}C$. 4. 3% alcohol extracted leaf have the substantial improvements as following; (1) bulk filling power of 10% and 24% for Burley and Bright tobacco, respectively, (2) combustibility shortening of about 3 minute and 2 minute for Burley and Bright tobaccos, respectively, (3) reduction ratio(%) of nicotine was found to be shout 61.5% and 54.5% for Burley and Bright tobacco, respectively, (4) reduction ratio (%) of tar was obtained to he about 25% and 15% for Burley and Bright tobacco, respectively.

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The Sorption Properties of Cs on the Surface of Artificially Weathered Illite (인위적으로 풍화시킨 일라이트 표면의 Cs 흡착 특성)

  • Kim Yeongkyoo;Lee Eun Jung
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.235-243
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    • 2004
  • Illite has been known to adsorb Cs preferentially to other alkali cations, especially at lower Cs concentration due to the frayed edge site. This frayed edge site was only verified by isotherm experiments, but not by other analytical methods. To investigate the Cs sorption properties on the surface of illite, artificially weathered illite with increasing frayed edge sites was reacted with Cs at different solution concentrations. The illite was weathered f3r 1 hour, 2 days, 14 days in 0.001 M HCl solution. With increasing reaction time, increasing amount of K in solution was observed, indicating formation of frayed edges by weathering, which was also verified by XRD, SEM, and TEM analysis. Original and weathered illites were converted to the homoionic Na form and reacted with $10^{-3}$ / ~ $10^{-7}$ M CsCl solutions for 24 hour. The aspect of Cs sorption was clearly distinguished around $10^{-5}$ M Cs concentration. The relative Cs amount sorbed on illite at low concentration (<10$^{-5}$ M) was higher than high concentration and increased with decreasing Cs concentration. In general, the amount of sorbed Cs increases with increasing weathering time and this trend is more noticeable at lower concentration while not much differentiated with weathering time at high concentration. These results indicate that the selective Cs sorption site exists in illite at low concentration, known as frayed edge site, and the number of those sites increases with weathering time.

Quantitative X-ray Diffraction Analysis of the Yellow Sea Surface Sediments; 2nd Yellow Sea Cruise Samples in 2001 (황해 표층 퇴적물의 X선 광물정량분석; 2001년 황해 2차 탐사 시료)

  • Moon, Dong-Hyuk;Kim, Soon-Oh;Yi, Hi-Il;Shin, Dong-Hyeok;Shin, Kyung-Hoon;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.203-212
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    • 2007
  • Mineral compositions of 89 Yellow Sea surface sediments collected at the second cruise in 2001, were determined using the high resolution X-ray diffractometer and Siroquant v.3.0 program. Yellow Sea surface sediments are composed of major minerals (quartz 57.8%, plagioclase 16.0% and alkali feldspar 10.0%), clay minerals, and calcite. Illite (8.7%) is the most abundant clay mineral, chlorite (2.6%) is the second, and kaolinite (0.6%) is few. however smectite is not detected. Quartz content is very high around the margin of the Yellow Sea, however is very low along the northwest to southeast direction extending from southeast of Sandong Peninsula to southwest of Jeju Island. It has similar distribution pattern with that of coarse sediment (sand). The coarse sediment, is mainly consisted of quartz, may be much supplied from the eastern part and southwestern part of the Yellow Sea. Illite distribution pattern is opposite to that of quartz. It is similar to those of clay and mud particles, therefore it can be suggested that fine sediment may be largely supplied from the northwestern part of the Yellow Sea. It is necessary to continue this kind of investigation, because it is difficult to interpret the sediment provenance of the Yellow Sea only from the result of this study.

Modeling Study on Deterioration of Stone Monuments in the Gyeongju Namsan Mountain by Acid Rain (산성비에 의한 경주남산지역 석조문화재의 손상 임상연구)

  • Do, Jin-Young;Choi, Gi-Joo;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.1
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    • pp.35-47
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    • 2009
  • The deteriorations of stone monuments located in Gyeongju area are predicted in a modeling study. Artificial rain and accelerated weathering test are here applied to the Gyeongju Namsan granite and cement mortar. They are reacted with pH 4.0, pH 8.0 and pH 5.6 rain, respectively. The two former values are the limited acidity values in the Gyeongju (the acidity of rain of the Gyeongju were pH $4.93{\sim}6.39$ in 2005) and the latter is the limited acidity of acid rain. The rains of pH 5.6 and pH 8.0 reach close to a value of pH 7.0 after the reaction with the Gyeongju Namsan granite. After application of the artificial rain and weathering test, the weight of specimens were reduced and the contents of soluble ions in the specimens were increased. These results are attributable to solution of minerals in the specimens. At first, the microlithic have dissolved in ground from the reaction with acid rain. And then mainly quartz, plagioclase and orthoclase bound by the microlithic are disintegrated. The cement mortars are dissolved after the reaction with not only acid but alkali rain. The concentrations of ions in the dissolved cement mortar are higher than those in granite.

Mineral Distribution of the Southeastern Yellow Sea and South Sea of Korea using Quantitative XRD Analysis (정량X선회절분석법을 이용한 황해 남동부, 한국남해 및 제주도 남단 표층퇴적물의 광물분포 연구)

  • Moon, Dong-Hyeok;Yi, Hi-Il;Shin, Kyung-Hoon;Do, Jin-Young;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.1
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    • pp.49-61
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    • 2009
  • We studied the mineral composition and mineral distribution pattern of 131 surface sediments collected at the cruise in 2000 and 2007 from Southeastern Yellow Sea, South Sea of Korea and Southern part of Jeju Island. Mineral compositions of surface sediments were determined using the quantitative X-ray diffraction analysis. Surface sediments were composed of rock forming minerals (quartz 37.4%, plagioclase 11.7%, alkali feldspar 5.5%, hornblende 3.1%), clay minerals (illite 19.2%, chlorite 4.7%, kaolinite 1.8%) and carbonate minerals (calcite 10.7%, aragonite 3.4%). Distribution of clay minerals is very similar with fine-grained sediments, and especially same as the distribution of HSMD (Hucksan Mudbelt Deposit), SSKMD (South Sea of Korea Mudbelt Deposit) and JJMD (Jeju Mudbelt Deposit). The coarse sediment seemed to be relic sediment during the last glacial maximum and mainly consisted of rock forming minerals. Whereas the fine sediments mainly composed of clay minerals. Based on the clay mineral composition, main ocean current and geographical factor, HSMD and SSKMD might have derived from the rivers around the Korean Peninsula. However, JJMD is complex mudbelt deposit, which formed by Korean rivers and oceanic sediments.

Studies on Photosensitive Polymers (X). Studies on Photosensitivity and Spectral Sensitivity of Naphthoquinone-1,2-diazide-5-sulfonyl Esters (感光性 樹脂에 關한 硏究 (第10報). Naphthoquinone-1,2-diazide-5-sulfonyl Esters의 感光性과 分光感度)

  • Shim Jyong Sup;Kang Doo Whan
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.269-279
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    • 1975
  • Photosensitive properties of naphthoquinone-1,2-diazide-5-sulfonyl esters (PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin condensate(BE) and polyvinyl alcohol(PVA) were investigated by the change of solubility before and after exposing to light. Various samples coated on glass or quartz plates were exposed to light under various conditions and steeped in aqueous alkali solution, and then the yield of residual film(W/W0) was determined. The yield of residual film, which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. In polymer homologs, the sensitivity was dependent on the degree of polymerization(the higher, the better). And also, it was most effective when 5 % of sensitizers to esters was used. The minimum exposed time was 0.6 min. for PGND-1, 1.0 min. for BEND-1, and 3.0 min. for PVAND-1. Most effective sensitizers for PGND, BEND and PVAND among those used here were benzanthrone, 5-nitroacenaphthene and picramide, respectively. The spectral sensitivities of PGND, BEND and PVAND were examined by comparing their spectrograms with UV-spectra in a solid state. Also, the sensitization and spectral sensitivity of the above polymers were studied. All the polymers containing the sensitizers showed optical sensitization. From the fact that in either case of sensitized or unsensitized sample, the ranges of absorption-maximum wave length were almost consistent with sensitivity maximum wave length, it was proved that the light absorbed by a sample served efficiently for photochemical reactions. Benzanthrone was found to be an excellent sensitizer for PGND.

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Preparation and Characteristics of Konjac Noodle-added Mugwort (쑥을 첨가한 곤약국수의 제조 및 특성)

  • Kim, Seog-Ji
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.5
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    • pp.613-619
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    • 2013
  • Konjac gel is known as a low calorie food, because the main component is water. Mugwort has been used for food and medicine for a long time due to itsfunctional property, which contains a lot of vitamins and minerals. Therefore, konjac noodle-added mugwort was prepared. The konjac gel was made by from a centrifuge after adding water, alkali and mugwort power in konjac flour. The centrifuge was used to remove air in the gel. After centrifuging by heating the gel in boiling water for one hour, konjac noodle was made by pressing using a flat heating press. The results are as follows. In the drying process of mugwort freeze drying after blanching in 1% $NaHCO_3$ solution is better than other drying methods. The physical properties (hardness, elasticity, cohesiveness, gumminess) of konjac gel were measured with a Rheometer. The optimum processing conditions were decided by these measured values. The optimum condition of making konjac gel is 9% concentration of konjac flour, a ph of 12.0, $Na_3PO_4$ coagulant and 1.5% concentration of mugwort power in konjac flour.

A Fundamental Study on Nano-cement by Chemical Synthesis (화학적 방법에 의한 나노시멘트 개발에 관한 기초 연구)

  • Jo, Byung-Wan;Kang, Seok-Won;Yoon, Kwang-Won;Choi, Ji-Sun
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.713-718
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    • 2009
  • Advanced industries-IT, BT, NT and ET are rapidly developing in 21 century. And the cement industry is becoming the principal factor in air pollution because of the creation of $CO_2$ during manufacturing. Also, the cement industry will be faced with a crisis due to the exhaustion of natural resources. In this study, nano cement by Bottom-up method of a chemical synthesis was developed. The generation of $CO_2$ during the plasticization process of cement manufacturing was avoided. The purpose was to produce building materials that have both high strength and durability as the high value-added growth engine industry of the 21 century. The nano cement was developed using hydrothermal synthesis. This is a method of mixing after ripening, by manufacturing the high density gel and low gel, which does not require special test equipment or pressure conditions to produce. Particle size, SEM, EDX, and porosity tests were conducted. This study investigated the compressive strength of concrete with various compositions. Specimens were tested for compressive strength at 3, 7, 14 and 28 days. The medium-sized (50% by weight) cement particles created by chemical synthesis were less than 168 nm. The compressive strength of the mortar prepared using this cement was 53.9 MPa. But it was judged that succeeding study will be necessary for development of nano building materials with high ability and economical analysis.