• Title/Summary/Keyword: Al203

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Creep Behaviour of Al-Zn-Mg Ternary Aluminum Alloy (Al-Zn-Mg 3원계 알루미늄 합금의 크리프 거동)

  • 윤종호;황경충
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.203-208
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    • 2004
  • To make practical applications of Al-Zn-Mg ternary aluminum alloy effectively in various field, a series of static creep tests under the 16 temperature-stress combination conditions had been performed. The creep tester with constant stress loading was designed and made by the authors and used in this study. The higher the creep temperature rose, the less the stress exponents became. The bigger the applied stresses became, the less values the creep strain activation energy showed. The life prediction constant of Larson-Miller parameter was calculated as about 2.3. In the fractography, the ductile fracture with dimples by intergranular breakage was primarily observed. We can make practical use of these test data in the design, the life prediction and the prevention of the accidents of the thermal facilities, etc.

$Ni/\gamma -Al_2O_3$ Catalyst Prepared by Liquid Phase Oxidation for Carbon Dioxide Reforming of Methane

  • 정경수;조병율;이호인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.89-94
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    • 1999
  • Carbon dioxide reforming of methane on Ni/γ-Al2O3 catalyst was studied. A new 10 wt% Ni/γ-Al2O3 catalyst prepared by the liquid phase oxidation method (L10O) exhibited much higher activity as well as resistances to both sintering and coke formation during the reaction than the catalyst prepared by the conventional impregnation method (D10). The electrically strong attractive interaction between nickel and support during the liquid phase oxidation process and the resultant high nickel dispersion made the L10 have superior activity and stability to the D10. To elucidate the results, the experiments with nickel catalysts on the other supports as well as 7-AI203 were performed. The effect of sodium as a promoter was also studied.

Effects of Adding Mg to AlSi Coating for Hot Stamping Steel (자동차용 핫스탬핑 AlSi 도금중 Mg 첨가효과)

  • Yang, Wonseog;Lee, Jeamin;Kim, Changkyu;Ahn, Seungho;Castaneda, Homero
    • Corrosion Science and Technology
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    • v.20 no.4
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    • pp.196-203
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    • 2021
  • To improve corrosion resistance and reduce the hydrogen uptake of 22MnB5, up to 5% Mg was added to the AlSi coating of 22MnB5. After hot-stamping and electrocoating were done on the metallic-coated specimen, the surface characteristics of the steel, hydrogen uptake content, and corrosion resistance were examined by transmittance electron microscopy, thermal desorption spectrometry, cyclic corrosion testing, and electrochemical impedance spectroscopy. Mg was investigated as MgO on the surface layer after hot-stamping while it existed as Mg2Si before hot-stamping. The total hydrogen content of 22MnB5 was decreased along with the Mg content. However, there was no difference at 0.2 wt% or more. When a small amount of Mg was added, the coating corrosion resistance was decreased, but when it was added at around 1.0 wt%, the greatest corrosion resistance increase was seen. However, when 3 wt% or more was added excessively, the corrosion resistance was decreased. MgO on the surface was considered to suppress H uptake by the AlSi melting solution and increase the barrier effect of the coating.

A Study on the Background Variables in the Patients with TMJ Dysfunction (악관절 기능장애의 원인에 관한 연구)

  • 정성창;고명연;김연중
    • Journal of Oral Medicine and Pain
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    • v.8 no.1
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    • pp.69-76
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    • 1983
  • Background variables in 203 patients with TMJ pain dysfunction showing no bony change, ranging from 11 to 76 of age, were studied by use of the modified form of self-administered questionnaires deviced by Carlsson et al intended to give a review of the patient's history. All the patients were identified in the Dept. of Oral Diagnosis and Oral Diagnosis and Oral Medicine, Seoul National University Hospital, during the period from Feb. 1983 to Nov. 1983. The questions concerning general somatic and psychic health, educational and social condition were dealt with in this article. The obtained results were as follows : 1. The main symptoms reported by 203 patients were difficulties in opening the mouth wide(74.4%), clicking of TMJ(70.9%), chewing difficulties(69.0%), and pain on movement of mandible(57.6%) 2. The most fequently reported medical symptoms or histories were stomach disease (21.2%), insominia(15.3%), ENT disease(13.8%) and skin disease (12.8%) 3. Seventy-eight percent of the patients denied having had a nervous or psychic disorders while 4% were currently under treatment for such disorders. 4. Eleven percent of 203 patients with TMJ dysfunction thought their family situation was distressing(8.4%) or very troublesome(3.4%).

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The Influence of Vanadium Addition on Fracture Behavior and Martensite Substructure in a Ni-36.5at.%Al Alloy (Ni-36.5at.%Al 합금에서 V 첨가가 파괴거동 및 마르텐사이트 내부조직에 미치는 영향)

  • Kim, Young Do;Choi, Ju;Wayman, C. Marvin
    • Analytical Science and Technology
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    • v.5 no.2
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    • pp.203-211
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    • 1992
  • Fracture behavior and martensite substructure of Ni-36.5at.%Al alloy were investigated with the addition of vanadium which is known as scavenging element of grain boundary. The fracture surfaces were examined by scanning electron microscopy and the EDX spectrometer was applied for composition analysis of fracture surfaces. The substructure of martensite was studied by transmission electron microscopy. By addition of vanadium, fracture surfaces show mixed modes of intergranular and transgranular fracture and more Al content is found on the grain boundaries. For Ni-36.5at.%Al alloy, the planar faults observed in the martensite plates are the internal twins. By increasing the vanadium content, the modulated structure with stacking faults and dislocations dominates while the twinned martensite disappears. The stacking fault is determined to be extrinsic due to the substitution of V for Al. It is concluded that the segregation of sulfur on the high-energy state stacking fault area suppresses the intergranular fracture.

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Acid Structure of MgO-SiO₂Binary Oxide Catalyst and Activity for Acid Catalysis

  • 손종락;박은희;김하원
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.203-208
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    • 1997
  • A series of MgO-SiO2 catalysts were prepared by coprecipitation from the mixed solution of magnesium chloride and sodium silicate. Some of the sample were modified with 1 N H2SO4 and used as modified catalysts. The addition of MgO to SiO2 caused the increase of acidity and the shift of O-H and Si-O stretching bands of the silanol group to a lower frequency in proportion to the MgO content. The acid structure of MgO-SiO2 agreed with that proposed by Tanabe et al.. Catalytic activity for 2-propanol dehydration increased in relation to the increase of acidity and band shift to a lower frequency.

$NiFe/Co/Al_2O_3/Co/IrMn$ 접합의 터널링 자기저항효과

  • 홍성민;이한춘;김택기
    • Journal of the Korean Magnetics Society
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    • v.9 no.6
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    • pp.291-295
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    • 1999
  • $NiFe/Co/Al_2O_3/Co/IrMn$ tunneling junctions were grown on (100)Si wafer and their spin-valve tunneling magnetoresistance (TMR) was studied. The tunneling junctions were grown by using a 5-gun RF/DC magnetron sputter. $Al_2O_3$ barrier layer was formed by exposing Al layer to oxygen atmosphere at 6$0^{\circ}C$ for 72 hours. Strong exchange coupling interaction is observed between the ferromagnetic Co and the antiferromagnetic IrMn of Co/IrMn bilayer when IrMn is 100$\AA$ thick. $NiFe(183\;{\AA})/Co(17\;{\AA})/Al_2O_3(16\;{\AA})/Co(100\;{\AA})/IrMn(100\;{\AA})$ tunneling junction shows best TMR ratio of about 10% in the applied magnetic field range of $\pm$20 Oe. The TMR ratio is improved about 23% and electrical resistance is decreased about 34% when annealed at 200 $^{\circ}C$ for 1 hour in magnetic field of 330 Oe, parallel to the bottom electrode. With increasing the active area of junction the TMR ratio increases while electrical resistance decreases.

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Effects of Sintering Temperature and Atmosphere on Densification of Hypereutectic Al-Si Alloy Powders (Al-20Si-5.5Fe-1.2Mg-0.5Mn 합금분말의 치밀화에 미치는 소결온도와 분위기의 영향)

  • Lee, Jae-Wook;Park, Sang-Bin;Yang, Sang-Sun;Kim, Yong-Jin
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.196-203
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    • 2008
  • The densification behavior of Al-20Si-5.5Fe-1.2Mg-0.5Mn powders was investigated through micro-structure analysis of sintered specimens. The specimens sintered in vacuum or in high purity (99.999%) nitrogen showed porous near-surface microstructures. The densification of near-surface part was enhanced by means of ultra-high purity (99.9999%) nitrogen atmosphere. The relationship between slow densification and oxide surfaces of Al alloy powders was discussed. And the effects of Mg addition, nitrogen gas, and humidity on densification were discussed. In addition, the rapid growth of primary Si crystals above the critical temperature was reported.

Size Distribution of Asian Dust Measured at Seoul during the Spring of 2002 (2002년 봄철 서울에서 관측된 황사 입자의 크기분포)

  • 배귀남;임득용;김민철;문길주;심상규
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.202-203
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    • 2002
  • 황사는 아시아 대륙의 중심부에 위치한 건조지대와 황토지대의 작은 모래나 황토가 공중에 부유하거나 상층 바람을 타고 멀리 수송되어 다시 지면 가까이 낙하하는 현상을 말한다(오성남 등, 1999). 최근 황사가 빈번하게 발생됨에 따라 황사에 대한 관심이 고조되고 있으며, 국내에서도 1990년대 초부터 황사에 대한 연구가 활발하게 수행되고 있다(배귀남 등, 2002b; Chun et al., 2001; 오성남 등, 1999). 본 연구에서는 2002년 봄철에 발생된 황사기간 동안 측정한 에어로졸의 농도 및 크기분포 특성을 고찰하였다. (중략)

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Fabrication of Al2O3/Fe-Ni Nanocomposites by Atmosphere-controlled Sintering and their Properties (소결분위기 제어에 의한 Al2O3/Fe-Ni 나노복합재료의 제조 및 특성)

  • Lee, Hong-Jae;Jeong, Young-Keun;Oh, Sung-Tag;Lee, Jai-Sung;Sekino, Tohru
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.199-203
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    • 2002
  • To investigate an effect of sintering atmosphere on microstructure and properties of metallic particle dispersed ceramic based composites, the powder mixtures of $Al_2O_3$/Fe-Ni, synthesized by chemical solution process, were hot-pressed under different atmospheres such as hydrogen or argon gas and different sintering temperature. Hot-pressed composite in a hydrogen atmosphere exhibited less reaction phase of $FeAl_2O_4$ and enhanced mechanical properties than that in an argon atmosphere. Furthermore, decreasing hot-pressing temperature produced a refinement of ceramic matrix and metallic dispersion particles as well as improvement of mechanical properties. The change of mechanical properties in the composites with different sintering conditions was explained by microstructural characteristics relating to reaction phase formation.