• Title/Summary/Keyword: Al-Co

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DC Influence Between Pixel Electrode and Alignment Layer in In-plane Switching Mode LCD

  • Lim, Young-Nam;Lee, Tae-Rim;Park, Byoung-Gyu;Roh, Seung-Kwang;Kim, Hyun-Chul;Kim, Hyun-Seung;Kim, Kyeong-Jin;Shin, Hyun-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.677-680
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    • 2009
  • DC influence between pixel electrode and alignment layer (AL) in in-plane switching mode LCD was analyzed through DC equivalence-circuit equation induction, DC charge-discharge simulation, luminance and residual-DC measurement systems using test patterned (TP) cell. DC discharging rate (DDR) of single layer electrode was faster than that of double layer electrode and DDR of low resistance AL was faster than that of high resistance AL. DC discharging characteristics had a close relation to layer number and resistance between two electrodes.

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Coating and Characterization of Al2O3-CoO Thin Films by the sol-gel Process (졸-겔법을 이용한 Al2O3-CoO계 박막의 제조와 특성에 관한 연구)

  • Shim, Moonsik;Lim, Yongmu
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.123-128
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    • 1999
  • This paper reports the preparation and characterization of colored coatings of $Al_2O_3$-CoO. Films of 25mol% CoO doped $Al_2O_3$, have been prepared on soda-lime-silica slide glasses by the sol-gel process from Al-alkoxide and Co-nitrate. The films have been characterized by a photospectroscopy and hardness tester. The color, spectral reflectance and spectral transmittance of the films was expressed in Lab color chart and on spectra plot. Microhardness of the films increased with increasing of the heating temperature. Transmittance and reflectance of the films decreased with increase of the heating temperature and coating times. The coating films showed various light-yellow, deep-yellow, greenish-yellow color as a function of the coating times and heating temperature.

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Fabrication and Its Characteristics of YSZ Composite with Added Transition Metal Oxides (천이금속산화물이 첨가된 YSZ 복합체의 제조 및 그 특성)

  • 최성운;박재성
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.4
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    • pp.341-349
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    • 2002
  • Electrical, mechanical and sinterability properties of yttria-stabilized zirconia doped with 5.35wt% $Y_2$O$_3$(Y$_2$O$_3$- containing stabilized zirconia : YSZ) were studied as a function of $Al_2$O$_3$, CoO, Fe$_2$O$_3$ and MnO$_2$ addition. The ratio of monoclinic phase to tetragonal phase was changed by the addition of $Al_2$O$_3$, CoO, Fe$_2$O$_3$ and MnO$_2$ to 8.00 wt% and sintered density decreased with increasing $Al_2$O$_3$, CoO, Fe$_2$O$_3$ and MnO$_2$ addition. Fracture toughness increased with the increase of monoclinic to tetragonal phase ratio and was maximum at about 18%. When transition metals such as CoO, Fe$_2$O$_3$ or MnO$_2$ was added more than 1.5 wt%, the electrical conductivity of YSZ increased. But $Al_2$O$_3$ hardly affected the electrical conductivity of YSZ. The addition of $Al_2$O$_3$, CoO, Fe$_2$O$_3$ and MnO$_2$ into YSZ resulted in the more complex behavior of fracture toughness and hardness variation and the specimen with 1.5wt%-Fe$_2$O$_3$, 3.0wt%-Al$_2$O$_3$ and 1.5wt%-CoO showed the monoclinic to tetragonal phase ratio of 18% and the highest toughness of 10.8 MPa.m$^{1}$2/ and Vickers hardness of 1201 kgf/mm$^2$.

Effect of MgF2 Surface Modification for LiNi0.8Co0.15Al0.05O2 Cathode Material on Improving Electrochemical Characteristics (LiNi0.8Co0.15Al0.05O2 양극활물질의 전기화학적 특성 향상을 위한 MgF2 표면처리 효과)

  • Jin, Su-Jin;Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.52-58
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    • 2020
  • Electrochemical characterization and thermal stability were investigated for MgF2 coated LiNi0.8Co0.15Al0.05O2 cathode. The ratio of MgF2 was controlled by 0.5, 1, 3 wt%. Cyclic voltammetry, charge-discharge profiles, rate capability, cycle life were measured for electrochemical properties. DSC analysis was measured for thermal stability. The first discharge capacities of MgF2 coated LiNi0.8Co0.15Al0.05O2 were decreased at 0.1C-rate compared to pristine LiNi0.8Co0.15Al0.05O2. But the rate capability and cycle life of MgF2 coated LiNi0.8Co0.15Al0.05O2 were improved at 2C-rate. In DSC analysis result, the exothermic temperature of MgF2 coated LiNi0.8Co0.15Al0.05O2 was increased and peak height was decreased.

N2O Decomposition Characteristics of Dual Bed Mixed Metal Oxide Catalytic System using Partial Oxidation of Methane (메탄의 부분산화를 이용한 이중 혼합금속산화물 촉매 반응시스템의 N2O 분해 특성 연구)

  • Lee, Nan Young;Woo, Je-Wan
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.82-87
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    • 2008
  • $N_2O$ decomposition characteristics of dual bed mixed metal oxide catalytic system was investigated. The partial oxidation of methane at first reactor of dual bed catalytic system was performed over Co-Rh-Al (1/0.2/1) catalyst under the optimized condition of $8,000h^{-1}$ GHSV, gas ratio ($CH_4:O_2=5:1$) at $500^{\circ}C$. In the dual bed system investigated herein, the second catalyst bed was employed for the $N_2O$ decomposition using product of partial oxidation of methane at first bed. An excellent $N_2O$ conversion activity even at lower temperature ($<250^{\circ}C$) was obtained with Co-Rh-Al (1/0.2/1) or Co-Rh-Zr-Al (1/0.2/0.3/1) catalyst by combining Co-Rh-Al (1/0.2/1) hydrotalcite catalyst for the partial oxidation of methane in a dual-bed system. The $N_2O$ conversion activity is drastically reduced in the presence of oxygen in second bed of a dual-bed system over Co-Rh-Al (1/0.2/1) catalyst at $300^{\circ}C$.

Study on the NiAl Coating for Corrosion Resistance of Stainless Steel in Molten Carbonate Salt (용융탄산염에 대한 스테인레스강의 내식성 향상을 위한 NiAl 피복에 관한 연구)

  • Hwang, Eung-Rim;Gang, Seong-Gun
    • Korean Journal of Materials Research
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    • v.7 no.1
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    • pp.76-80
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    • 1997
  • '4 NiAl coating process was applied on 316 stainless steel to retard the corrosion of the wet- seal area of separator for the molten carbonate fuel cell. The Nit11 phasc on the stainless steel substrate could be formed by pre-coating with Ni, plated with A1 and ther, heat treated at $800^{\circ}C$ for 3 hr in $H_2/N_2$ gas atmosphere. The corrosion protection behavior of YiAl coating layer was stuilied under immersion condition in molten cxhonate salt($62^{m}/_{o}Li_2CO_3-38^{m}/_{o}/K_{2}CO_{3}$) at $650^{\circ}C$. The NiAl coating layer ticposited on the AiSi 316 stainless steel had high corrosion resistance in molten carbor. dte salt. The corrosion resistance of XiAl (~~jpoared to be associated with the .A1 oxide formed on the surface of coating layer.

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Electrochemical Properties of Al Doped Li(Ni1/3Co1/3Mn1/3-xAlx)O2, Cathode Materials (알루미늄이 첨가된 Li(Ni1/3Co1/3Mn1/3-xAlx)O2 양극활물질의 전기화학적 특성)

  • Kim Seon-Hye;Shim Kwang-Bo;Kim Chang-Sam
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.64-69
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    • 2006
  • Cathode materials of Al-doped $Li(Ni_{1/3}Co_{1/3}Mn_{1/3-x}Al_x)O_2$ (x=0.0, 0.005, 0.01 0.05) for lithium ion batteries were synthesized with ultra-sonic spray pyrolysis method and single-step heat treatment. No secondary phases were found in all synthesized powders. The intensity ratio of $I_{003}\;to\;I_{104}$, however, slightly decreased and the particle size increased with the Al contents. The cells with bare, 0.5 and 1.0 at% Al-doped powders showed the initial discharge capacities of 182, 180 and $184mAhg^{-1}$ in a voltage range of $3.0\sim4.5V$ at 1C rate, and the capacity retentions of 81, 77 and 78% at the end of 30 cycles, respectively. But in the voltage range of $3.0\sim4.6V$, the Al-doping significantly enhanced the cycle stability. For example, the discharge capacity after 50 cycles was maintained to 70% in the 0.5 at% Al-doped sample compared to only 30% in no doped sample. The improvement of the cycle stability was thought to be due to $Mn^{3+}$ ion decrease as the Al doping from the XPS analysis results.

A Study on the Erosion Behavior of the Ceramic Sprayed Coating Layer in the Molten 55% Al-Zn (용융 55%Al-Zn 중에서 세라믹 용사 피막의 침식 거동에 관한 연구)

  • 강태영;임병문;최장현;김영식
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.51-59
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    • 2000
  • Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

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Secondary Growth of Sodium Type Faujasite Zeolite Layers on a Porous $\alpha-Al_2O_3$ Tube and the $CO_2/N_2$ Separation (Na형 Faujasite 제올라이트 분리막 형성 및 $CO_2/N_2$ 분리)

  • Cho, Churl-Hee;Yeo, Jeong-Gu;Ahn, Young-Soo;Han, Moon-Hee;Kim, Yong-Ha;Hyun, Sang-Hoon
    • Membrane Journal
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    • v.17 no.3
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    • pp.254-268
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    • 2007
  • Sodium type faujasite(FAU) zeolite layers with diverse materials characteristics(Si/Al ratio, thickness, and structural discontinuity) were hydrothermally grown on a porous $\alpha-Al_2O_3$ tube, and then the $CO_2/N_2$ separation was evaluated at $30^{\circ}C$ for an equimolar mixture of $CO_2$ and $N_2$. Among hydrothermal conditions, $SiO_2$ content in hydrothermal solution seriously affected materials characteristics: with an increment in the $SiO_2$ content, Si/Al ratio, thickness, and structural discontinuity of grown FAU zeolite layer simultaneously increased. The present study reveals that structural discontinuity(intercrystalline voids due to an incomplete densification and cracks induced by GIS Na-P1 phase) is the most important variable affecting the $CO_2/N_2$ separation. Also, it was suggested that the $CO_2$ desorption in permeate side be the rate-determining(slowest) step in the overall $CO_2$ permeation.

CO2 Reforming of Methane over Co-Pd/Al2O3 Catalysts

  • Itkulova, Sh. S.;Zhunusova, K.Z.;Zakumbaeva, G.D.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.2017-2020
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    • 2005
  • The supported bimetallic Co-containing catalysts promoted by the different amount of noble metal (Pd) have been studied in the dry reforming of methane. The activity, selectivity, stability and resistance to the carbon deposition of Co-Pd/$Al_2O_3$ catalysts depend on both the catalyst composition and process conditions. It has been observed that the Co-Pd/$Al_2O_3$ catalysts produce the various oxygenates from $CO_2$ + $CH_4$ at moderate pressures.