• Title/Summary/Keyword: Al-4.5%Cu alloy

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Effect of Cu Addition on Thermal Properties of Mg-6Zn-xCu alloys (Mg-6Zn-xCu 합금의 열적 특성에 미치는 Cu 첨가의 영향)

  • Ye, Dea-Hee;Kim, Hyun-Sik;Kang, Min-Cheol;Jeong, Hae-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.4
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    • pp.67-74
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    • 2015
  • In this study, Mg-Zn alloys are investigated in terms of their thermal properties after an addition of Cu. Al element is added to improve the mechanical properties and castability in general case. However, it was excluded here because it significantly decreases the thermal conductivity. On the other hand, Zn was added as a major element, which had less influence on reducing the conductivity and can complement the mechanical properties as well. Cu was also added, and it improved the heat transfer characteristics as the amount was increased. The composition ranges of Zn and Cu are 6 wt.% and 0~1.5 wt.%, respectively. Mg-6Zn-xCu alloy was prepared by a gravity casting method using a steel mold and then the thermal conductivity and the microstructure of the as-cast material were investigated. By measuring the density_(${\rho}$), specific heat_(Cp) and thermal diffusivity_(${\alpha}$), the thermal conductivity_(${\lambda}$) was calculated by the equation ${\lambda}={\rho}{\cdot}Cp{\cdot}{\alpha}$. As the amount of Cu increased in the Mg-6Zn-xCu alloy, the heat transfer characteristics were improved, resulting in a synergistic effect which is slow when the added Cu exceeds 1 wt.%. In order to investigate the relative thermal conductivity/emission of the Mg-6Zn-xCu alloy, AZ91 and AZ31 were experimentally evaluated and compared using a separate test equipment. As a result, the Mg-6Zn-1.5Cu alloy when compared to AZ91 showed improvements in the thermal conductivity ranging from 30 to 60% with a nearly 20% improvement in the thermal emission.

Effects of Coating Materials on Fluidity and Temperature Loss of Molten Metals from Runner Systems in Full Moulds.

  • Cho, Nam-Don;Kim, Yong-Hyun;Choi, Jung-Kwon
    • Journal of Korea Foundry Society
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    • v.10 no.1
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    • pp.31-42
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    • 1990
  • The full mould casting process in one of the newly developed techniques which has many advantages. Unbonded sand mould has been prepared for the major mould and $CO^2$ gas mould has been used occasionally for comparison. Patterns were built up with expanded polystyrene and coated with three different materials. Silica, graphite and zircon were used for the coating layer. The effects on fluidity and temperature loss of molten metals were investigated. The molten metals were Al-5% Si alloy, Cu-30% Zn alloy and gray iron of approximately 4.0% of carbon equivalent. Experimental variables were runner section area, superheat, sprue height, coating materials, coating thickness and apparent density of EPS pattern. The effects of coating materials on fluidity and temperature loss of the molten metals during transient pouring are summarized as follows : As runner section area, superheat and sprue height increased, fluidity increased. Temperature loss decreased as runner section area and sprue height increased. However, reversed effects were observed in the case of superheat increment. The coating materials decreased the fluidity of each alloy in the order of silica, graphite and zircon. Zircon brought to the highest temperature loss among the coating materials used. The fluidity increased in the order gray iron, Cu-30% Zn and Al-5% Si alloy while temperature loss in the reverse order. Especially in case of reduced pressure process, the fluidity was increased apparently. Al-5% Si alloy showed the lowest temperature loss among the alloys. The increment of the apparent density of EPS pattern resulted in the fluidity decrease and temperature loss increase. The relation between fluidity and temperature loss of each alloy can be expressed by the following equation within the coating thickness limit of 0.5-1.5㎜. F^*={\frac{a}{T^*-b}}-c$ where, $F^*$ : fluidity in the Full mould, $T^*$ : temperature loss in the mould. a : parameter for full mould. b, c : constants.

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Bending Behaviors of Stainless Steel Tube Filled with Al5Si4Cu4Mg Closed Cell Aluminum Alloy Foam (발포 Al5Si4Cu4Mg 알루미늄 합금이 충진된 304 스테인리스강 원통의 굽힘저항 특성)

  • Kim, Am-Kee;Lee, Hyo-Jin;Cho, Seong-Seock
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.10
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    • pp.1686-1694
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    • 2003
  • The foam-filled tube beams can be used for the front rail and firewall structures to absorb impact energy during frontal or side collision of vehicles. In the case of side collision where bending is involved in the crushing mechanism, the foam filler would be effective in maintaining progressive crushing of the thin-walled structures so that much impact energy could be absorbed. In this study, bending behaviors of the closed-cell-aluminum-alloy-foam-filled stainless steel tube were investigated. The various foam-filled specimens including piecewise fillers were prepared and tested. The aluminum-alloy-foam filling offered the significant increase of bending resistance. Their suppression of the inward fold formation at the compression flange as well as the multiple propagating folds led to the increase of load carrying capacity of specimens. Moreover, the piecewise foams would provide the easier way to fill the thin-walled shell structures without the drawback of strength.

Microstructure and Wear Properties in an Engine Oil Environment of Extruded Hyper-eutectic Al-15wt.%Si Alloy and Gray Cast Iron (과공정 Al-15wt.%Si 압출재와 회주철의 미세조직 및 엔진 오일 환경에서의 마모 특성)

  • Kang, Y.J.;Kim, J.H.;Hwang, J.I.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.27 no.6
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    • pp.339-346
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    • 2018
  • This study investigated the microstructure and wear properties of extruded hyper-eutectic Al-Si (15wt.%) alloy in an engine oil environment. The wear mechanism of the material was also analyzed and compared to conventional gray cast iron. In microstructural observation results of Al-15wt.%Si alloy, primary Si phase ($45.3{\mu}m$) and eutectic Si phase ($3.1{\mu}m$) were found in the matrix, and the precipitations of $Mg_2Si({\beta}^{\prime})$, $Al_2Cu({\theta}^{\prime})$ and $Al_6(Mn,Fe)$ were also detected. In the case of gray cast iron, ferrite and pearlite were observed. It was also observed that flake graphite ($20-130{\mu}m$) were randomly distributed. Wear rates were lower in the Al-Si alloy as compared to those of gray cast iron in all load conditions, confirming the outstanding wear resistance of Al-15wt.%Si alloy in engine oil environment. In the $4kg_f$ condition, the wear rate of gray cast iron was $6.0{\times}10^{-5}$ and that of Al-Si measured $0.8{\times}10^{-5}$. The microstructures after wear of the two materials were analyzed using scanning electron microscope (SEM) and electron backscatter diffraction (EBSD). The primary Si and eutectic Si of Al-Si alloy effectively mitigated the abrasive wear, and the Al matrix effectively endured to accept a significant amount of plastic deformation caused by wear.

Microstructure and Wear Property of $Al-5Mg-X(Si,Cu,Ti)/SiC_p$ Composites Fabricated by Pressureless Infiltration Method (무가압 침투법에 의해 제조된 $Al-5Mg-X(Si,Cu,Ti)/SiC_p$ 복합재료의 조직 및 마멸특성)

  • Woo, Kee-Do;Kim, Sug-Won;Ahn, Haeng-Keun;Jeong, Jin-Ho
    • Journal of Korea Foundry Society
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    • v.20 no.4
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    • pp.254-259
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    • 2000
  • Metal matrix composites(MMCs) reinforced with hard particles have many potential application in aerospace structures, auto parts, semiconductor package, heat resistant panels, wear resistant materials and so on. In this work, the effect of SiC partioel sizes(50 and 100 ${\mu}m$) and additional elements such as Si, Cu and Ti on the microstructure and the wear property of $Al-5Mg-X(Si,Cu,Ti)/SiC_p$ composites produced by pressureless infiltration method have been investigated using optical microscopy, scanning eletron microcopy(SEM) with EDS(energy dispersive spectrometry), hardness test, X-ray diffractometer(XRD) and wear test. In present study, the sound $Al-5Mg-X(Si,Cu,Ti)/SiC_p$(50 and 100 ${\mu}m$) composites were fabricated by pressureless infiltration method. The $Al-5Mg-0.3Si-O.1Cu-O.1Ti/SiC_p$ composite with $50 {\mu}m$ size of SiC particle has higher hardness and better wear property than any other composite with $100{\mu}m$ size of SiC particle produced by pressureless infiltration method. The hardness and wear property of $Al-5Mg/SiC_p$(50 and 100 ${\mu}m$) composites were enhanced by the addition of Si, Cu and Ti in Al-5%Mg matrix alloy.

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The Effect of Ageing on Grain Refinement of CuAlNi Shape Memory Alloy (CuAlNi 형상기억합금의 결정립 미세화에 따른 시효효과)

  • Yang, G.S.;Park, C.S.;Jang, W.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.65-74
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    • 1995
  • This research was performed to investigate the effect of ageing on grain refinement of 82wt%Cu-13.5wt%Al-4.5wt%Ni-0.1wt% misch metal alloy with ageing temperature and time. The results obtained in this study are as follows; The variation of transformation temperature with ageing temperature had very influence on ageing time at $300^{\circ}C$. But it had not influence on ageing time at $100^{\circ}C$. The variation of transformation temperature after second reversed transformation cycle was not occured in martensitic phase ageing, but $M_s$ point was appeared equally with third reversed transformation cycle in parent phase ageing. The variation of $M_s$ point was not nearly with ageing time at $100^{\circ}C$ ageing temperature. But it was decreasing with ageing time at $300^{\circ}C$ ageing temperature and $A_s$ point was increasing with ageing time. Structure of parent phase ageing was being M18R martensitic and N2H martensitic phase. It was found that ${\alpha}$ and ${\gamma}_2$ phase were created by ageing of long time at $300^{\circ}C$ ageing temperature.

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Effects of In on the Precipitation Phenomena of Al-2.1Li-2.9Cu Alloy by Differential Scanning Calorimetry (열분석법에 의한 Al-2.1Li-2.9Cu합금이 석출현상에 미치는 In 첨가의 영향)

  • Park, Tae-Won;Song, Young-Beum;Lee, Yong-Yun
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.4
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    • pp.237-245
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    • 1997
  • A study was conducted to examine the effects of In addition on the precipitation behaviors of Al-2.1Li-2.9Cu alloy by differential scanning calorimetry, transmission electron microscopy and micro-hardness tester. DSC analysis was measured over the temperature range of $25{\sim}550^{\circ}C$ at a heating rate of $2{\sim}20^{\circ}C$/min. The heat evolution peaks due to the formation of GP zone and ${\delta}$'phase shift to higher temperature and the peaks to $T_1$ and ${\theta}$'phases shift to lower temperature by In addition. From this result, it was proved that the formation of GP zone and ${\delta}$'phase is suppresed whereas that of $T_1$ and ${\theta}$'phases are accelerated by the In addition of 0.15wt%. The age hardening curve aged at $190^{\circ}C$ showed that the In bearing alloy(alloy B) has more faster age hardening response and a higher peak hardness than In-free alloy(alloy A), attributed to the fine and homogeneous distribution of $T_1$ and ${\theta}$'phases. The activation energies for the formation of ${\delta}$'phase in In-free and In-bearing alloys are 22.3kcal/mol and 18.6kcal/mol, respectively. Those for $T_1(+{\theta}^{\prime})$ phase of In-free and In-bearing alloys are 24.3 and 37.5kcal/mol, respectively. Quenched-in excess vacancies play an important role to the formation of precipitates.

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Decomposition Behavior of Secondary Solidification Phase During Heat Treatment of Squeeze Cast Al-Cu-Si-Mg (용탕단조 Al-Cu-Si-Mg합금의 열처리시 제2응고상의 분해거동)

  • Kim, Yu-Chan;Kim, Do-Hyang;Han, Yo-Sub;Lee, Ho-In
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.560-568
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    • 1997
  • The dissolution behavior of secondary solidification phases in squeeze cast Al-3.9wt%Cu-1.5wt%Si-1.0wt%Mg has been studied using a combination of optical microscope, image analyzer, scanning electron microscope(SEM), energy dispersive spectrometer(EDS), X-ray diffractometer(XRD) and differential thermal analyzer (DTA). Special emphasis was placed on the investigation of the effects of the nonequilibrium heat treatment on the dissolution of the second solidification phases. Ascast microstructure consisted of primary solidification product of ${\alpha}-Al$ and secondary solidification products of $Al_2Cu$, $Mg_2Si$ and $Al_2CuMg$. Equilibrium and non-equilibrium solution treatments were carried out at the temperatures of $495^{\circ}C$, $502^{\circ}C$ and $515^{\circ}C$ for 3 to 5 hours. The amount of the dissolved secondary phases increased with increasing solution treatment temperature, for example, area fractions of $Al_2Cu$, $Mg_2Si$ and $Al_2CuMg$ were approximately 0%, 1.6% and 4.2% after solution treatment at $495^{\circ}C$ for 5hours, and were approximately 0%, 0.36% and 2% after solution treatment at $515^{\circ}C$ for 5hours. The best combination of tensile properties was obtained when the as-cast alloy was solution treated at $515^{\circ}C$ for 3hours followed by aging at $180^{\circ}C$ for 10 hours. Detailed DTA and TEM study showed that the strengthening behavior during aging was due to enhanced precipitation of the platelet type fine ${\theta}'$ phase.

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Phase Transformation Behavior on Aging Treatment in CuAINi Shape Memory Alloy (CuAINi 형상기억합금의 시효처리에 따른 상변태 거동)

  • Yang, G.S.;Kang, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.213-222
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    • 1993
  • This research was performed to investigate the transformation behavior and shape memory effect of Cu-13.5Al-4.5Ni(wt%) alloy with various aging temperature and time. The results obtained in this study are as follows: Transformation temperature was very increased when aging temperature is at $250^{\circ}C$. The variation of transformation temperature in first reverse transformation cycle and second was very significant, but there was little difference in case of 2nd and 3rd. Transformation temperature at various aging temperature was increased with increasing of aging temperature and time. Microvickers hardness was increased with increasing of aging temperature and time. It was found that ${\alpha}$ and ${\gamma}_2$ phase were created by aging of long time at high temperature.

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