• Title/Summary/Keyword: Al concentration

Search Result 1,843, Processing Time 0.024 seconds

Concentration distribution of aldehydes in various indoor microenvironments (다양한 실내 구역에서의 알데히드류의 농도 분포)

  • 이지호;박성은;신동천
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2000.11a
    • /
    • pp.439-440
    • /
    • 2000
  • 알데히드류는 실내의 다양한 오염원에서 발생되어 하루의 대부분을 실내에서 보내고 있는 현대인들에게 건강상 영향을 미치는 것으로 알려져 관심의 대상이 되어왔으며, 특히, 포름알데히드는 발암성 물질로 알려진 대표적인 실내 환경 오염 물질이기도 하다(Zhang junfeng et al., 1999). 포름알데히드는 urea 또는 phenol-formaldehyde 수지를 합성하는 주요 물질이며, 건축물 단열재, 가구의 염료 및 광택제, 접착제, 합판, particle board, 악취 제거제, 제지, 가스 스토브, 담배연기, 화장용품, 세제등 생활 용품에서 공업용품에 이르기까지 광범위하게 사용되며, 그 사용량도 증가되고 있다(Thomas J. Kelly et al., 1999). (중략)

  • PDF

Polymerization of Anisole Derivatives Containing Allyl or Chloromethyl Group Through Aromatic Electrophilic Substitution Reaction

  • 장지영;박필정;한만정
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.12
    • /
    • pp.1288-1291
    • /
    • 1997
  • 4-Allylanisole was polymerized with AlCl3 as a catalyst. The polymerization was carried out in nitroethane at various temperatures with changing the ratio of the initiator to the monomer concentration. The weight averge molecular weights measured by gel permeation chromatography in chloroform with polystyrene standards were between 1,500 and 4,700. 1H NMR spectroscopy showed that the polymerization proceeded through a stepwise aromatic electrophilic substitution reaction along with a minor chain-reaction, resulting in a branched polymer. 4-Chloromethylanisole was also polymerized with AlCl3 in nitroethane through an aromatic electrophilic substitution reaction to give a high molecular weight polymer (Mw=88,000).

Dyeing properties and functionality of silk fabrics dyed with Salicornia bigelovii extracts (함초 추출물을 이용한 견직물의 염색성과 기능성)

  • Kim, Sangyool
    • The Research Journal of the Costume Culture
    • /
    • v.24 no.5
    • /
    • pp.577-587
    • /
    • 2016
  • Natural dye extracted from Salicornia bigelovii was applied to silk fabrics by dip dyeing process. The dyeing properties and the functionalities of the silk fabrics were determined. Factors affecting the dyeing properties such as dyestuff concentration, temperature, time and pH were studied. The colorimetric parameters $L^*$, $a^*$, $b^*$, and H, V/C values were measured to select the optimal mordanting conditions. The color-fastnesses of the dyed and mordanted fabrics were estimated for practical use; in addition, the antibacterial property, ultraviolet protection properties were evaluated. The dyeabilities of silk increased depending on the increasing dye concentration, dyeing time, and dyeing temperature. And optimum dyeing results were achieved when dyeing with 300% (o.w.f.) of dye concentration at $90^{\circ}C$ for 100 minutes and at pH 3. The dyed silk fabrics without mordants produced yellow (Y) color and showed yellow (Y) or green yellow (GY) colors depending on the mordants type. The light fastness of dyed and Al mordanted silk fabrics were found to be excellent, and the drycleaning and rubbing fastness were good. The dyed silk fabrics showed no antibacterial property, but Al and Cu mordanted silk fabrics showed 99.9% reduction rate. The ultraviolet protection properties of the dyed silk fabric was improved. And the ultraviolet protection properties of mordanted samples showed very good ultraviolet protection properties.

Study of chemical coagulation conditions for a disperse red dye removal from aqueous solutions

  • Tiaiba, Mohammed;Merzouk, Belkacem;Mazour, Mohammed;Leclerc, Jean P.;Lapicque, Francois
    • Membrane and Water Treatment
    • /
    • v.9 no.1
    • /
    • pp.9-15
    • /
    • 2018
  • Coagulation process using aluminum sulfate ($Al_2(SO_4)_3$) and ferric chloride ($FeCl_3$) was employed as a treatment method for decolorization of a synthetic textile wastewater containing red dye in this paper. Factors such as initial pH, coagulant dosage, initial concentration, conductivity and mixing conditions that influence color removal efficiency were experimentally tested. It was found that $Al_2(SO_4)_3$ is more efficient than $FeCl_3$ as coagulant. When $40mgL^{-1}$ aluminum sulfate was used, results showed that color induced by the red dye was efficiently removed (> 90 %) and was obtained in a large range of initial pH from 4 to 8 with, and for a dye concentration lower than $235mg\;L^{-1}$. After addition of the coagulant, the medium had to be mixed for 30 min at 60 rpm, then allowed to settle for 40 min. The effects of water conductivity in the range $0.035-2.42mS\;cm^{-1}$ and dye concentration up to $380mg\;L^{-1}$ were also followed and discussed.

The Chemical Nature of Individual Size-resolved Raindrops and Their Residual Particles Collected during High Atmospheric Loading for PM2.5

  • Ma, Chang-Jin;Sera, Koichiro
    • Asian Journal of Atmospheric Environment
    • /
    • v.11 no.3
    • /
    • pp.176-183
    • /
    • 2017
  • Although it is well known that rain plays an important role in capturing air pollutants, its quantitative evaluation has not been done enough. In this study, the effect of raindrop size on pollutant scavenging was investigated by clarifying the chemical nature of individual size-resolved raindrops and their residual particles. Raindrops as a function of their size were collected using the raindrop collector devised by our oneself in previous study (Ma et al., 2000) during high atmospheric loading for $PM_{2.5}$. Elemental analyses of solid residues and individual residual particles in raindrops were subsequently analyzed by Particle Induced X-ray Emission (PIXE) and Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray Analysis (EDX), respectively. The raindrop number concentration ($m^{-2}h^{-1}$) tended to drastically decrease as the drop size goes up. Particle scavenging rate, $R_{sca.}$ (%), based on the actual measurement values were 38.7, 69.5, and 80.8% for the particles with 0.3-0.5, 0.5-1.0, and $1.0-2.0{\mu}m$ diameter, respectively. S, Ca, Si, and Al ranked relatively high concentration in raindrops, especially small ones. Most of the element showed a continuous decrease in concentration with increasing raindrop diameter. The source profile by factor analysis for the components of residual particles indicated that the rainfall plays a valuable role in scavenging natural as well as artificial particles from the dirty atmosphere.

Elasticity and Conduction analysis of multi-Phase, Misoriented Metal matrix Composites (방향분포를 가진 다상 금속복합재료의 탄성 및 전도해석에 관한 연구)

  • 정현조
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.19 no.9
    • /
    • pp.2181-2193
    • /
    • 1995
  • The effective elasticity and conduction of composite materials containing arbitrarily oriented multiple phases has been analyzed using the concept of orientation-dependent average fields and concentration factors. The analysis provided closed form expressions for the effective stiffnesses and conductivities. Under the prescribed boundary conditions, the concentration factors were evaluated by the equivalent inclusion principle, through which the interaction between various phases is approximated by the Mori-Tanaka mean-field approximation. SiC particulate(SiC$_{p}$) reinforce aluminum(Al) matrix composites were fabricated and their elastic constants and electrical conductivities were measured together with a careful study of their microstructure. The measured properties showed a systematic anisotropy and this behavior could be attributed to the preferred orientation of SiC$_{p}$. The theoretical model developed was applied to the computation of the anisotropic properties of these composites. Both two-phase and three-phase composites were considered based on the microstructural information. The SiC$_{p}$ was modeled as an ellipsoid with planar random orientation distribution in the extruded Al/SiC$_{p}$ composites. The effect of extraneous phase such as intermetallic compounds was also investigated.tigated.

The Effect of Cerium Reduction on Light Emission in Cerium-containing 20Y2O3-25Al2O3-55SiO2 Glass

  • Maeng, Jee-Hun;Choi, Sung-Churl
    • Journal of the Optical Society of Korea
    • /
    • v.16 no.4
    • /
    • pp.414-417
    • /
    • 2012
  • The effect of cerium concentration and the addition of $Sb_2O_3$ on the light emission of cerium-contained glass were investigated. The glass matrix composition was $20Y_2O_3-25Al_2O_3-55SiO_2$, the $CeO_2$ concentration ranged from 0.05 to 0.5 mol%, and $Sb_2O_3$ was added at concentrations of 0.02 to 0.1 mol%. The $Ce^{3+}$ and $Ce^{4+}$ absorption bands were observed at approximately 330 nm and 240 nm, respectively. A broad emission band at 400 nm, due to the 4f-5d transition of the $Ce^{3+}$ ion, was observed under illumination by a UV light at 330 nm. The photoluminescence intensity of $Ce^{3+}$ had a maximum value at a $CeO_2$ concentration of 0.1 mol%. Adding $Sb_2O_3$ decreased the $Ce^{4+}$ absorption intensity and enhanced the light emission intensity of $Ce^{3+}$ by about 45%.

Dyeing Property and Functionality of Silk Fabrics Dyed with Rhododedron brachycarpum Extracts (만병초 추출물에 의한 견직물의 염색성 및 기능성)

  • Kim, Sangyool
    • Journal of Fashion Business
    • /
    • v.23 no.3
    • /
    • pp.23-34
    • /
    • 2019
  • The aim of this study is to explore the possibility utilizing Rhododedron brachycarpum as a new natural dye resource. It was dyed in silk fabric according to different dyeing conditions such as dye concentration, dye bath temperature, dyeing time and dye bath pH. The effect of the mordanting conditions were estimated as dyeability and color changes. Additionally, the colorfastness, antibacterial property, ultraviolet protection properties of the dyed and mordanted silk fabrics were examined. The water-soluble dye of Rhododedron brachycarpum extracted with distilled water was expressed as Yellow Red color. The dye-abilities of silk generally increased depending on the increasing values of dye concentration, dye bath temperature and dyeing duration. The highest K/S values were obtained at a dye concentration of 100% (v/v), a dye bath temperature of $90^{\circ}C$, a dyeing duration 120 minutes and a dyeing of pH 2. The light fastness of dyed and Cu mordanted silk fabrics were found to be 4 grade while Al, Fe mordanted silk fabrics were found to be 2~3 grade. The dry cleaning and rubbing fastness were excellent or good. The fade of washing fastness was not good, however, the stain of washing fastness was excellent. The dyed and Al, Cu mordanted silk fabrics indicated 99.9% reduction rate. The dyed and the mordanted fabrics showed very good ultraviolet protection factors.

Effects of pH and Chloride Concentration on Corrosion Behavior of Duplex Stainless Steel and Titanium Alloys Ti 6Al 2Nb 1Ta 1Mo at Elevated Temperature for Pump Impeller Applications

  • Aymen A., Ahmed;Ammar Yaseen, Burjes;Ammar Yaseen, Burjes
    • Corrosion Science and Technology
    • /
    • v.21 no.6
    • /
    • pp.454-465
    • /
    • 2022
  • The objective of this study was to determine effects of temperatures and pH of sodium chloride solution with MgCl2 ions on corrosion resistance of duplex stainless-steel X2CrNiMoN22-5-3 (DSS) and Ti 6Al 2Nb1Ta1Mo (Ti). Effects of sodium chloride concentration on corrosion resistance were also studied. Corrosion behavior and pitting morphology of duplex stainless steel (DSS) and Ti alloys were evaluated through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). It was found that a decrease in pH significantly reduced the corrosion resistance of both alloys. Changes in chloride concentration and temperature had more substantial impact on corrosion behavior of DSS than on Ti alloys. Pitting corrosion was formed on DSS samples under all conditions, whereas crevice corrosion was developed on Ti samples with the presence of magnesium chloride at 90 ℃. In conclusion, magnesium chloride ions in an exceedingly strong acidity solution appear to interact with re-passivation process at the surface of these alloys and influence the resulting surface topography.