• 상하수도학회지
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• 제32권1호
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• pp.47-53
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• 2018

This study investigated phosphorus removal from secondary treated effluent using coagulation-membrane separation hybrid treatment to satisfy strict regulation in wastewater treatment. The membrane separation process was used to remove suspended phosphorus particles after coagulation/settlement. Membrane separation with $0.2{\mu}m$ pore size of micro filtration membrane could reduce phosphorus concentration to 0.02 mg P/L after coagulation with 1 mg Al/L dose of polyaluminum chloride (PACl). Regardless of coagulant, the residual concentration of phosphorus decreased as the dose increased from 1.5 to 3.5 mg Al/L, while the target concentration of 0.05 mg P/L or less was achieved at 2.5 mg Al/L for the aluminum sulfate (Alum) and 3.5 mg Al/L for PACl. Moreover, alum showed better membrane flux as make bigger particles than PACl. Alum showed a 40% of flux decrease at 2.5 mg Al/L dose, while PACl indicated a 50% decrease of membrane flux even with a higher dose of 3.5 mg Al/L. Thus, alum was more effective coagulant than PACl considering phosphorus removal and membrane flux as well as its dose. Consequently, the coagulation-membrane separation hybrid treatment could be mitigate regulation on phosphorus removal as unsettleable phosphorus particles were effectively removed by membrane after coagulation.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.420-420
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• 2012

ZnO seed layer were deposited on quartz substrate by sol-gel method and prism-like Al-doped ZnO nanorods (AZO nanorods) were grown on ZnO seed layer by hydrothermal method with various Al concentration ranging from 0 to 2.0 at.%. Structural and optical properties of the AZO nanorods were investigated by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), photoluminescence (PL). The diameter of the AZO nanorods was smaller than undoped ZnO nanorods and its diameter of the AZO nanorods decreased with increasing Al concentration. In XRD spectrum, it was observed that stress and full width at half maximum (FWHM) of the AZO nanorods decreased and the 'c' lattice constant increased as the Al concentration increased. From undoped ZnO nanorods, it was observed that the green-red emission peak of deep-level emission (DLE) in PL spectra. However, after Al doping, not only a broad green emission peak but also a blue emission peak of DLE were observed.

• Steel and Composite Structures
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• 제19권3호
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• pp.777-787
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• 2015

Production and properties of metal matrix composites reinforced with an in-situ high aspect ratio $AlB_2$ flake have been investigated. Boron 2.2wt.% was dissolved in pure Al and Al-Cu alloy at $1300^{\circ}C$ by adding directly boron oxide which resulted in 4 vol.% reinforcing phase. The in-situ $AlB_2$ flake concentration was increased up to 30 vol.% in order to increase the tensile strength of the composites. Hardness, compressive strength and tensile strength of the composite were measured and compared with their matrix. Results showed that 30 vol.% $AlB_2/Al$ composite show a 193% increase in the compressive strength and a 322% increase in compressive yield strength. Results also showed that ductility of composites decreases with adding $AlB_2$ reinforcements.

• 분석과학
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• 제14권6호
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• pp.494-498
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• 2001

크로메이트를 대체하기 위한 새로운 표면처리 화합물로서 cerium nitrate를 사용하고 Al도금강판에 적용하였을 때, 그 표면의 특성을 정밀하게 분석하였다. 그 결과, cerium nitrate로 처리된 Al도금강판의 표면층에서 cerium은 (+4) 산화 상태와 (+3) 산화 상태의 혼합된 형태로 존재하며 각각의 상대적 비율은 57 % 및 43 %인 것으로 나타났다. 이러한 cerium 화합물의 피막은 Al도금층의 자연산화막과 더불어 도금강판의 표면에 보호 피막을 형성하여 Al도금강판의 표면 부식을 방지하게 된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.27-27
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• 2008

The different concentration Indium doped ZnO:Al films were grown on glass substrates (Corning 1737) at $200^{\circ}C$ by pulsed laser deposition. The indium doping in AZO films shows the critical effect on the crystallinity, resistivity, and optical properties of the films. The AZO films doped with 0.3 atom % indium content exhibit the highest crystallinity, the lowest resistivity of $4.5\times10^{-4}\Omega$-cm, and the maximum transmittance of 93%. The resistivity of the indium doped-AZO films is strongly related with the crystallinity of the films. The carrier concentration in the indium doped-AZO films linearly increases with increasing indium concentration. The mobility of the AZO films with increasing indium concentration was reduced with an increase in carrier concentration and the decrease in mobility was attributed to the ionized impurity scattering mechanism. In an optical transmittance, the shift of the optical absorption edge to shorter wavelength strongly depends on the electronic carrier concentration in the films.

• 한국산림과학회지
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• 제90권1호
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• pp.74-82
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• 2001

Al과 Mn을 여러가지 농도로 조정한 배양액을 채운 포트에 소나무(Pinus densiflora) 2년생 묘목을 이식하여 수경재배법에 의해 90일간 온실내에서 육성한 후 소나무 묘목의 생장, 영양상태 및 가스교환속도에 미치는 Al과 Mn의 영향을 조사하였다. 배양액의 Al농도는 4수준(0, 10, 30, 60ppm)으로 처리하였으며, 이들 각각의 Al처리에 Mn농도를 3수준(0, 30, 60ppm)으로 처리하여 총 12처리구의 2요인배치법(two-factor design)의 실험을 실시하였다. Al과 Mn은 소나무 묘목의 건물생장에 상호작용효과(interaction effects)를 나타내지 않았으나, 소나무 묘목의 건물생장에 대한 Al과 Mn의 각각의 단독영향(main effects)은 유의적인 차이가 나타났다. 소나무 묘목의 건물생장은 Al은 10ppm이상, Mn은 60ppm의 농도에서 생장저하를 초래하였으며, 이는 소나무 묘목의 건물생장에 대한 Al의 독성이 Mn에 비해 클 수 있음을 시사한다. 뿌리의 암호흡속도는 Al의 경우 60ppm에서, Mn의 경우는 30ppm이상의 농도에서 저하하였다. 또한, 크로로필함량에 있어서는 Al의 영향은 인정되지 않았으나, 60ppm의 Mn처리구에서 낮아지는 경향을 보였다. 배양액의 Al과 Mn농도가 증가함에 따라서 소나무 묘목의 상대생장율(RGR) 및 순동화율(NAR)이 저하하였으며, 이는 광합성 효율의 감소가 원인으로 생각된다. 비록 본 연구결과는 수경재배법에 의하여 얻어진 결과이지만, 장래 우리나라에서 실제로 발생할 수 있는 산성강하물에 의한 수목피해 예측 및 산성화된 토양의 임지에서도 이와 유사와 현상이 발생될 수 있음을 시사하고 있다.

• 자원리싸이클링
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• 제28권4호
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• pp.44-50
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• 2019

국내 전기로 공정에서 산화 반응열 및 탄소 연소열 등으로 인한 화학에너지는 전체 투입 에너지 대비 30%정도로 알려져 있다. 전기로에서 $CO_2$를 저감하기 위해서는 전기로 용해 구간 중에 사용되는 전력에너지를 줄이고 화학에너지 사용을 높여야 한다. 일반적으로 용강 중 탄소를 단독으로 투입할 경우, 탄소가 용강에 용해되기 전 낮은 밀도로 인해 슬래그 층으로 부유한다. 용강 중 탄소 농도가 높을 시 취입하는 산소와 용강 중 탄소의 연소반응으로 인해 전력에너지를 낮추며 화학에너지 사용량을 높일 수 있다. 따라서 탄소 연소열의 효율을 높이기 위해서는 용강 중 새로운 탄재 장입 조건이 필요하다. 한편, Al 제련 후의 부산물로 알려져 있는 Al 드로스는 금속성 Al을 25 mass% 이상 함유하고 있으며 Al은 탄소와 비교하여 높은 산화열을 가지고 있다. 그러나 Al 드로스는 재활용이 어려워 거의 매립하고 있으며, Al 드로스 내 Al의 산화열을 효과적으로 활용하기 위해서는 철강 공정 적용에 대한 연구가 필요하다. 본 연구에서는 화학 에너지의 활용 증대를 위한 기반연구로서, 분코크스와 Al 드로스를 화학에너지 연료로서 활용하여 다양한 배합비 및 반응 온도에서 용강 중 탄소 및 알루미늄의 용해 농도와 용해효율을 조사하였다.

• 한국광학회:학술대회논문집
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• 한국광학회 2007년도 하계학술발표회 논문집
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• pp.159-160
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• 2007

• 환경영향평가
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• 제12권2호
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• pp.99-108
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• 2003

We collected and analyzed PM10 samples to account for the characteristics of heavy metallic elements for yellow sand and non-yellow sand during springtime of 2002 at Busan, The mean PM10 mass concentration for springtime of 2002 was $219.82{\mu}g/m^3$ with the maximum $787.50{\mu}g/m^3$ and the minimum $19.44{\mu}g/m^3$. The mean concentration of metallic elements contained in PM10 are shown as follows : Si>Ca>Fe>Al>Na, respectively. The ratio of mean PM10 mass concentration for yellow sand($362.7{\mu}g/m^3$) to that for non-yellow sand($48.3{\mu}g/m^3$) was 7.5, the significant positive correlation (P<0.05) was found between yellow sand and non-yellow sand. The metallic elements concentration ratios of yellow sand to the non-yellow sand were over 10 times for Al, Ca, Mg, 4~8 times for Fe, Si, Mn. But the concentration of Na, Cu, Zn for non-yellow sand was higher than those of yellow sand. The crustal enrichment factor of Cd, Cu, Pb, Zn, Cr, K, Mn, Na, Ni for yellow sand was higher that of non-yellow sand over 10 times, and concentration rate of soil particles of yellow sand was increased 2.3 times that of nonyellow sand.

• 한국세라믹학회지
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• 제28권8호
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• pp.593-602
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• 1991

Al2O3 and NiO-doped Al2O3 powders were prepared from the ethanol solution of Al (NO3)3$.$9H2O and Ni(NO3)2$.$6H2O by spray pylolysis method using two-fluid nozzle. As a result of spraying test with 0.3 mol/{{{{ iota }} concentration starting solution, mean droplet sizes varied with 8.99∼9.69$\mu\textrm{m}$ and those standard deviation were 4.57∼5.12. As-prepared powders which were synthesized at 1000$^{\circ}C$ have spherical shape, sizes of 0.1∼3.0$\mu\textrm{m}$ and specific surface area of 22.34∼24.20㎡/g. Most powders consisted of {{{{ gamma }}-Al2O3 phase and transforned into ${\alpha}$-A;2O3 phase by calcination at 1100$^{\circ}C$ for 1 hr. NiO-doped Al2O3 sintered bodies had better sinterability than those of pure Al2O3 and 0.3 wt% NiO-doped Al2O3 had near theoretical density and dense microstructure.