• 한국주조공학회지
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• 제17권4호
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• pp.338-346
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• 1997

Mechanical properties of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites fabricated by the reaction squeeze casting were compared with those of ($15%Al_2O_3{\cdot}SiO_2$)/Ai composites. Al-Ni intermetallic compounds ($10{\sim}20 {\mu}m$) formed by the reaction between nickel powder and molten aluminum were uniformly distributed in the Al matrix. These intermetallic compounds were identified as $Al_3Ni$ using X-ray diffraction analysis and they resulted in beneficial effects on room and high temperature strength and wear resistance. Microhardness values of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composite were greater by about 100Hv than those of ($15%Al_2O_3{\cdot}SiO_2$)/Al composite. Wear resistance of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites was superior to that of ($15%Al_2O_3{\cdot}SiO_2$)/Al composites regardless of the applied load. While tensile and yield strength of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites were greater at room temperature and $300^{\circ}C$, strength drop at high temperature was much smaller in hybrid composites.

• 한국재료학회지
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• 제24권5호
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• pp.236-242
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• 2014

Fabrication of reaction-bonded $Al_2O_3$ (RBAO) ceramics using Al-Zn-Mg alloy powder was studied in order to improve traditional RBAO ceramic processing using Al powder. The influence on reaction-bonding and microstructure, as well as on physical and mechanical properties, of the particulate characteristics of the $Al_2O_3$-Al alloy powder mixtures after milling, was revealed. Variation of the particulate characteristics of this $Al_2O_3$-Al alloy powder mixture with milling time was reported previously. To start, the $Al_2O_3$-Al alloy powder mixture was milled, reaction-bonded, post-sintered, and characterized. During reaction-bonding of the $Al_2O_3$-Al alloy powder mixture compacts, oxidation of the Al alloy took place in two stages, that is, there was solid- and liquid-state oxidation of the Al alloy. The solid-state oxidation exhibited strong dependence on the density of surface defects on the Al-alloy particles formed during milling. Higher milling efficiency resulted in less participation of the Al alloy in reaction-bonding. This was because of its consumption by chemical reactions during milling, and subsequent powder handling, and could be rather harmful in the case of over-milling. In contrast to very little dependence of oxidation of the Al alloy on its particle size after milling, the relative density, microstructure, and flexural strength were strongly dependent on particle size after milling (i.e., on milling efficiency). The relative density and 4-point flexural strength of the RBAO ceramics in this study were ~98% and ~365 MPa, respectively, after post-sintering at $1,600^{\circ}C$.

• 청정기술
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• 제17권2호
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• pp.166-174
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• 2011

지지체의 구성비가 일산화탄소 산화반응에 미치는 영향을 조사하기 위하여 다양한 몰 비의 Al/(Al+Ce) 산화물을 공침법으로 제조하고 백금을 담지한 촉매를 함침법으로 제조하였다. 제조한 촉매의 물리 화학적 특성을 알아보고 반응 활성과 연관시키기 위하여 X-선 회절분석(XRD), 질소 흡착 탈착분석($N_2$ sorption), 수소/일산화탄소-승온환원분석($H_2$/CO-TPR)의 특성분석을 수행하였다. Pt/xAl-yCe 촉매에서 지지체의 몰 비에 따른 최적 활성을 조사한 결과, 건식 및 습식 반응조건에서 Pt/1Al-9Ce 촉매가 가장 좋은 활성을 나타냈으며, 이를 기준으로 회산형 형태의 반응 곡선을 나타냈다. 반응물에 5%의 수분이 존재 할 때, 50%의 전환율 온도가 건조 반응조건에서의 활성보다 약 $30^{\circ}C$ 저온으로 이동하였다. CO-TPR 분석에서Pt/1Al-9Ce 촉매 상의 이산화탄소 탈착피크가 가장 크게 관찰되었고, CO-TPR 결과는 반응결과와 잘 일치하였다. 이는 다른 촉매에 비해 Pt/1Al-9Ce 촉매의 표면 흡착점이 가장 많고 지지체로부터 산소공급이 용이함을 의미한다. 또한 $^{27}Al$ NMR 분석에서 오면체로 배위된 $Al^{3+}$ 점의 양과 반응 활성이 비례관계에 있음을 확인하였다.

• 대한기계학회논문집A
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• 제26권11호
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• pp.2374-2382
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• 2002

Aluminum alloy/aramid fiber reinforced plastic(Al/AFRP) laminates consists of high strength metal(A15052) and laminated aramid fiber with structural adhesive bond. The mixture ratio effect of epoxy resin curing agent accelerator on the tensile strength and T-peel strength characteristic in Al AFRP laminates were investigated in this study. The epoxy. diglycidylether of bisphenol A(DCEBA), It'as cured by methylene dianiline(MDA) with or without an accelerator(K-54). Eight different kinds of resin mixture ratios were selected for the test , five kinds of Al/AFRP laminates were named as Al/AFRP(1) and three others of Al/AFRP laminates were named as Al/AFRP(2). The comparison of tensile strength and T-peel strength with variation of resin mixture ratio were studied. Respectively. Al/AFRP(1) and Al/AFRP(2) indicated approximately 6.0 times and 7.0 times more improved maximum tensile strength in comparison with those of monolithic A15052. Al/AFRP(2) indicated approximately 1.5 times more impoved maximum T-peel strengths in comparison with those of Al/AFRP(1). As results. Al/AFRP(2) turned out to have more effective characteristics on the tensile strength and T-peel strength than those of Al/AFRP(1).

• 한국세라믹학회지
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• 제38권3호
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• pp.225-230
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• 2001

저전압용 형광체로 주목받고 있는 SrTiO$_3$:Pr,Al 형광체를 고상반응법으로 제조하였다. 부활성체 Al이 23 mol% 첨가되었을 때 SrTiO$_3$:Pr 형광체는 최대 발광 강도를 보여주었다. 최대 발광 강도를 보인 형광체에 대해 제한시야회절상과 투과전자현미경을 이용하여 SrTiO$_3$:Pr,Al 적색 형광체내 2차상 형성에 대한 연구를 행하였고 또한 에너지 분산 분광 분석을 행하여 SrTiO$_3$:Pr,Al 형광체내 주입된 부활성제 Al의 함량을 결정하였다. 제한시야회절상의 결과에 의하면 SrTiO$_3$:Pr,Al 적색 형광체내에 단사정 SrAl$_2$O$_4$, 삼사정 Ti$_4$O$_{7}$, 육방정 SrAl$_{12}$O$_{19}$가 2차상으로 존재함을 보여 주었다. 에너지 분산 분광 분석 결과 부활성제 Al의 함량 중 일부는 SrTiO$_3$:Pr,Al 적색 형광체 격자에 고용되고 일부 Al은 SrAl$_{12}$O$_{19}$와 SrAl$_2$O$_4$의 2차상을 형성하는데 소모됨을 보여주었다.주었다.

• Journal of Advanced Marine Engineering and Technology
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• 제37권7호
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• pp.711-717
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• 2013

Titanium (Ti) metal and its alloys are desirable materials for ship hulls and other structures because of their high strength, light weight and corrosion-resistance. And light weight and corrosion-resistant aluminum (Al) is the ideal metal for shipbuilding. The joining of Ti and Al dissimilar metals is one of the effective measures to reduce weight of the structures or to save rare metals. Ti and Al have great differences in materials properties, and intermetallic compounds such as Ti3Al, TiAl, TiAl3 are easily formed at the contacting surface between Ti and Al. Thus, welding or joining of Ti and Al is considered to be extremely difficult. However, it was clarified that ultra-high speed welding could suppress the formation of intermetallic compounds in the previous study. Results of tensile shear strength increases with an increase in the welding speed, and therefore extremely high welding speed (50m/min in this study) is good to dissimilar weldability for Ti and Al. In this study, therefore, full penetration dissimilar lap welding of Ti (upper) - Al (lower) and Al (upper) - Ti (lower) with single-mode fiber laser was tried at ultra-high welding speed, and the microstructure of the interface zones in the dissimilar Al and Ti weld beads was investigated.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2011년도 춘계학술논문집 2부
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• pp.970-973
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• 2011

유색 금 합금 중의 하나인 퍼플골드(purple gold)는 특유의 적자색(보라색)이 나는 78wt%Au-22wt%Al의 조성으로 이루어진 금 합금으로 많은 각광을 받고 있다. 본 연구에서는 78wt%Au-22wt%Al(이후 Au1)인 기준 조건보다 Al의 상대조성이 커짐에 따라 보라색과 기계적 물성의 변화를 확인하기 위해 76wt%Au-24wt%Al(이후Au2), 74wt%Au-26wt%Al(이후 Au3), 72wt%Au-28wt%Al(이후 Au4)으로 Al 조성을 22~26%Al까지 변화시키고 이때의 비커스 경도, 광학현미경, EDS, UV-VIS-NIR 색차분석 실험을 실시하였다. 비커스경도 측정결과 Al의 함유량이 증가함에 따라 경도값은 감소하는 경향성을 보였으며, 26wt%Al 이상의 조성에서 Au1 조성에 상응하는 경도 값을 유지할 수 있음을 확인하였다. 광학현미경을 이용한 미세구조 분석결과 Al의 함유량이 증가함에 따라 적자색을 띄는 결정립 $AuAl_2$의 분포는 감소하며, 결정립계에 석출하는 Al-rich 상의 분포와 크기는 증가하는 경향을 확인하였다. EDS를 이용한 성분분석 결과 실제 목표했던 조성과 분석오차를 고려하면 잘 일치함을 확인하였다. UV-VIS-NIR를 이용한 색차 분석결과 Au3 조성까지도 보라색을 유지할 수 있음을 확인하였다. 따라서 비커스경도와 색을 고려하면 기존 19K인 Au1보다 18K의 Au2 조성에서도 퍼플골드 구현이 가능하였다. 이후 Au2 조성으로 블랙홀과 아라크네를 모티브로 하여 실제 주얼리 제품을 성공적으로 제조하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1993년도 추계학술대회 논문집
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• pp.112-115
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• 1993

We have studied a property of arachidic acid Langmuir-Blodgett films at room temperature with two different electrodes ; Al/LB/Al and Au/LB/Au. Since a natural oxide layer is formed on top of the Al electrode, the appropriate structure of AL/LB/Al is Al/Al$_2$O$_3$/LB/Al. To obtain a property of Pure LB film, Aua/LB/Au structure was made. In Al/Al$_2$O$_3$/LB/Al structure, a conductivity of 3.7${\times}$10$\^$-14/ S/cm was obtained by using current-voltage(I-V) characteristics. In Au/LB/AU structure, however, I-V curve was not able to be measured because of short current even in 51 layers of the LB film. A status of defects in the film was confirmed by copper decoration method. We have clearly seen a rather big difference of defect in those two above structures.

• 한국세라믹학회지
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• 제34권11호
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• pp.1129-1138
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• 1997

Al2O3/20 vol%YAG composite containing equiaxed grains and Al2O3/20 vol%LaAl11O18 composite containing elongated grains were fabricated using Al2O3-Y2O3 composition and Al2O3-La2O3 composition, respectively, by hot-pressing. In order to investigate the influence of microstructural control of second phase on toughening effect of toughened ceramic composites, AE (acoustic emission) measurements have been coupled with fracture toughness experiments(SENB and SEPB method). A separation of the fracture toughness and analysis of toughening mechanism was possible using the AE technique. The fracture toughness of hot-pressed materials was estimated to be 3.2 MPam0.5 for monolithic alumina, 4.7 MPam0.5 for Al2O3/20 vol%YAG composite and 6.2 MPam0.5 for Al2O3/20 vol%LaAl11O18 composite. In monolithic Al2O3, toughening does not occur as a result of either microcracking or grain bridging, whereas, composites exhibit toughening effects by both microcracking in the frontal zone and gain bridging in the wake zone, resulting in an improvement of fracture toughness as compared with monolithic Al2O3. The fracture toughness of Al2O3/20 vol%LaAl11O18 composite is higher than that of Al2O3/20 vol%YAG composite. It may be attributed to the elongated microstructure of Al2O3/20 vol%LaAl11O18 composite, resulting relatively greater bridging effect.

• Journal of Advanced Marine Engineering and Technology
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• 제38권2호
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• pp.133-139
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• 2014

Titanium (Ti) metal and its alloys are desirable materials for ship hulls and other ocean structures because of their high strength, corrosion-resistance and light weight properties. And light weight and corrosion-resistant aluminum (Al) is the ideal metal for shipbuilding. The joining of Ti and Al dissimilar metals is one of the effective methode to reduce weight of the structures. Ti and Al have great differences in materials properties, and intermetallic compounds such as $Ti_3Al$, TiAl, $TiAl_3$ are easily formed at the contacting surface between Ti and Al. Thus, dissimilar welding and joining of Ti and Al are considered to be very difficult. However, it was clarified that ultra-high speed welding could suppress the formation of intermetallic compounds in the previous study. Results of tensile shear strength increases with an increase in the welding speed, and therefore extremely high welding speed (50 m/min) is good to dissimilar weldability for Ti and Al. In this study, therefore, full penetration dissimilar lap welding of Ti (upper) - Al (lower) and Al (upper) - Ti (lower) with single-mode fiber laser was tried at ultra-high welding speed, and the microstructure of the interface zones in the dissimilar Al and Ti weld beads was investigated.