• Title/Summary/Keyword: Air-Water Interface

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Effect of Lidocaine Compounds on the Expansion of Lipid Monolayer at the Air/Water Interface (국부 마취제로 이용되는 Lidocaine 화합물들이 공기/물 계면에 형성된 지질 단분자 막의 팽창효과에 미치는 영향)

  • Choi, Suk-Young;Oh, Seong-Geun;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1090-1097
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    • 1998
  • Lidocaine compounds have widely been used as local anesthetics. Regarding the molecular mechanism for anesthesia by lidocaine, it is proposed that lidocaine molecules penetrate to the hydrophobic region of cell membrane and expand the membrane volume, producing a change in protein conformation that blocks sodium permeability or lidocaine molecules directly adsorb into lidocaine receptor in the protein channel without expanding the cell membrane. But these proposals have never been proven experimentally. In this study, the expansion of cell membrane by lidocaine compounds was investigated by employing lipid monolayer at the air/water interface as the mimetic system of cell membrane. It was found that oil-soluble lidocaine contracted the area/molecule of lipid in the monolayer of phosphatidyl choline, sphingomyelin, DS-PL95E and lipoid, but expanded the monolayer of phosphatidyl ethanolamine only in a certain range of mixing ratios. On the contrary, water-soluble lidocaine-HCl salt expanded the monolayers of all lipids used in this study.

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Influence of Gas Transfer Velocity Parameterization on Air-Sea $CO_2$ Exchange in the East (Japan) Sea

  • Hahm, Do-Shik;Rhee, Tae-Siek;Kang, Dong-Jin;Kim, Kyung-Ryul
    • Journal of the korean society of oceanography
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    • v.38 no.3
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    • pp.135-142
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    • 2003
  • Gas flux across the air-sea interface is often determined by the product of gas transfer velocity k) and the difference of concentrations in water and air. k is primarily controlled by wind stress on the air-sea interface, thus all parameterizations ofk involve wind speed, a rough indicator of wind stress, as one of the independent variables. We attempted to explore the spatial and temporal variations of k in the East (Japan) Sea using a database from Naet al. (1992). Three different parameterizations were employed: those of Liss and Merlivat (1986), Wanninkhof(1992), and Wanninkhofand McGillis (1999). The strong non-linear dependence of k on wind speed in all parameterizations leads us to examine the effect of time resolution, in which the binned wind speeds are averaged, on the estimation ofk. Two time resolutions of 12 hours (short-term) and one month (long-term) were chosen. The mean wind speeds were fed into the given parameterizations, resulting in six different transfer velocities of $CO_2$ ranging from 12 to 32 cm/h. In addition to the threefold difference depending on the choice of parameterization, the long-term average of wind speed results in a value ofk up to 20% higher than the short-term (12 hours) average of wind speed due to the non-Rayleigh wind distribution in the East (Japan) Sea. While it is not known which parameterization is more reliable, this study proposes that the time-averaged wind speed should not be used in areas where non-Ralyleigh wind distribution prevails such as the East (Japan) Sea. The net annual $CO_2$ flux was estimated using the value of k described above and the monthly ${\Delta}fCO_2$ of Oh et al. (1999); this ranges from 0.034 to 0.11 Gt-C/yr.

Dose Alterations at the Distal Surface by Tissue Inhomogeneity in High Energy Photon Beam (조직 불균질성에 의한 고에너지 광자선의 선량변화)

  • Kim, Young-Ai;Choi, Tae-Jin;Kim, Ok-Bae
    • Radiation Oncology Journal
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    • v.13 no.3
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    • pp.277-283
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    • 1995
  • Purpose : This study was performed to measure dose alteration at the air-tissue interface resulting from rebuild-up to the loss of charged particle equilibrium in the tissues around the air-tissue interfaces. Materials and Methods : The 6 and 10-MV photon beam in dual energy linear accelerator were used to measure the surface dose at the air-tissue interface The polystyrene phantom sized $25{\times}25{\times}5\;cm^3$ and a water phantom sized $29{\times}29{\times}48\;cm^3$ which incorporates a parallel-plate ionization chamber in the distal side of air gap were used in this study. The treatment field sizes were $5{\times}5\;cm^2,\;10{\times}10\;cm^2\;and\;20{\times}20\;cm^2$. Air cavity thickness was variable from 10 mm to 50 mm. The observed-expected ratio (OER) was defined as the ratio of dose measured at the distal junction that is air-tissue interface to the dose measured at the same point in a homogeneous phantom. Results : In this experiment, the result of OER was close or slightly over than 1.0 for the large field size but much less (about 0.565) than 1.0 for the small field size in both photon energy. The factors to affect the dose distribution at the air-tissue interface were the field size, the thickness of air cavity. and the photon energy. Conclusion : Thus, the radiation oncologist should take into account dose reduction at the air-tissue interface when planning the head and neck cancer especially pharynx and laryngeal lesions, because the dose can be less nearly $29{\%}$ than predicted value.

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An Experimental Study on the Deadrise Angle of a Falling Body upon a Free Surface Water (자유수면에 낙하하는 물체의 형상각에 관한 실험적 연구)

  • Lee, Jong-Boong;Lee, Ju-Yong
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.223-228
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    • 2001
  • This study was obtained the pressure distribution of a falling body that is deadrise angle $0^{\circ}$ and deadrise angle $5^{\circ}$ upon a water surface by the experiment with the impact machine. The theoretical equation was obtained the air region and the interface and the water region which devide 3 parties between the body and the water surface for an investigation of the complete phenomena. Pressure distributions and histories compare favorably with available experimental data. The numerical results are similar to the experimental results for the impact force type with $Fo(1+cos{\pi}t/tc)$.

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Time Series Simulation of Explosive Charges In Shallow Water Using Ray Approach

  • Hahn, Jooyoung;Lee, Seongwook;Na, Jungyul
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.3E
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    • pp.133-140
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    • 2003
  • A time series simulation is presented by a ray approach for the simulating the received waveform of a broadband acoustical signals interacting with the ocean boundaries. The environment is assumed to be horizontally stratified, and the seafloor is described in terms of homogeneous fluid half-space. The ray approach includes the effects of reflection from the air-water, water-sediment interface and phase shifts due to boundaries interaction. To generate time series, we assume that the acoustic energy propagates from source to receiver along eigenrays and represent the action of the bottom on the incident wave by a linear filter and characterized in the frequency domain by the transfer function. As example application, the time series for an explosive source in a shallow water environment is calculated and analyzed in terms of acoustical process. good agreement with measured time series is demonstrated.

Using LNAPL to Enhance in situ Oxygen Transfer: (II) Biotic Condition (LNAPL을 이용한 지중 산소전달 향상: (II) Biotic Condition)

  • Ha, Jeong-Hyub;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.3
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    • pp.337-342
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    • 2004
  • Previous experiment was performed under abiotic condition. Steady-state abiotic experiments in the sand-tank reactor with air flowing through the reactor headspace demonstrated that oxygen supply through the water table interface into the saturated zone was enhanced when an LNAPL (dodecane) pool was present at the water table. Biotic condition was considered in this study. Biotic experiments performed after inoculating the reactor with Pseudomonas putida mt-2, which does not grow on dodecane, indicated that the enhanced oxygen supply in the presence of the LNAPL pool also enhanced biodegradation of a solute (glucose) plume passing beneath the LNAPL pool at steady-state.

Water Vapour Permeable/Water Resistant and Heat Resistant Finishing of Footwear Fabric (신발용 직물의 투습방수 및 내열성 가공)

  • Lee, Jae Ho;Choi, Hae Wook
    • Journal of Adhesion and Interface
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    • v.7 no.3
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    • pp.16-25
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    • 2006
  • Water vapour permeable and water resistant film was laminated to made footwear woven fabric and non-woven fabrics by screen type with thermosetting reactive hot melt adhesive. Optimum conditions of each process were investigated, and the properties of film laminated fabric with optimum conditions are evaluated. The results are as follows. Thermosetting reactive polyurethane hot melt is retain proper heat resistance differently thermoplastic hot melt. Optimum melting adhesive process conditions are as follows ; drum temperature $95^{\circ}C$, hose temperature $97^{\circ}C$, feeding pipe temperature $100^{\circ}C$, screen temperature $105^{\circ}C$, pressure of opposite roller $1kgf/cm^2$, pressure of laminating roller $3kgf/cm^2$, finishing speed 15 m/min, melting temperature $120^{\circ}C$, cooling time 20 s, pressing temperature $130^{\circ}C$, pressing time 30 s. As the thickness of film was increased, the water vapour permeability was decreased but water resistance was increased, and the effect of film is dominant over all the others in the air permeability.

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Environmental Geochemistry of Atmospheric Mercury: Its Backgriound Concentrations and Exchange Across the Air-Surface Interface (대기수은의 환경지화학: 배경농도측정 및 대기-지표면간의 교환작용)

  • 김기현
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.2
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    • pp.189-198
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    • 1996
  • Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

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Heat and mass transfer analysis in air gap membrane distillation process for desalination

  • Pangarkar, Bhausaheb L.;Sane, Mukund G.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.159-173
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    • 2011
  • The air gap membrane distillation (AGMD) process was applied for water desalination. The main objective of the present work was to study the heat and mass transfer mechanism of the process. The experiments were performed on a flat sheet module using aqueous NaCl solutions as a feed. The membrane employed was hydrophobic PTFE of pore size 0.22 ${\mu}m$. A mathematical model is proposed to evaluate the membrane mass transfer coefficient, thermal boundary layers' heat transfer coefficients, membrane / liquid interface temperatures and the temperature polarization coefficients. The mass transfer model was validated by the experimentally and fitted well with the combined Knudsen and molecular diffusion mechanism. The mass transfer coefficient increased with an increase in feed bulk temperature. The experimental parameters such as, feed temperature, 313 to 333 K, feed velocity, 0.8 to 1.8 m/s (turbulent flow region) were analyzed. The permeation fluxes increased with feed temperature and velocity. The effect of feed bulk temperature on the boundary layers' heat transfer coefficients was shown and fairly discussed. The temperature polarization coefficient increased with feed velocity and decreased with temperature. The values obtained were 0.56 to 0.82, indicating the effective heat transfer of the system. The fouling was observed during the 90 h experimental run in the application of natural ground water and seawater. The time dependent fouling resistance can be added in the total transport resistance.

Approximate solutions on the absorption process of an aqueous LiBr falling film : effects of vapor flow (리튬브로마이드 수용액 유하액막의 흡수과정에 대한 근사 해법 : 증기 유동의 영향)

  • Kim, B.J.;Lee, C.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.2
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    • pp.144-152
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    • 1997
  • Film absorption involves simultaneous heat and mass transfer in the vapor-liquid system. In the present work, the absorption process of water vapor by an aqueous soluton of LiBr flowing inside of the vertical tube was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the heat and mass transfer rate. Particularly the effects of vapor flow conditions on the absorption process were investigated in terms of the vapor Reynolds number. As the vapor Reynolds number increased, the shear stress at the vapor-solution interface also increased. Consequently solution film became thinner at higher vapor flowrate under the co-currentflow condition. Thinner film was capable of higher heat transfer to the wall and leaded to higher absorption rate of the water vapor into the solution film.

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