• 제목/요약/키워드: Air Extraction

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The Effect of Extraction Conditions and Film Side on the Molecular Conformation of Silk Sericin Film

  • Jo, Yoon Nam;Bae, Do Gyu;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • 제26권2호
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    • pp.113-118
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    • 2013
  • In this study, silk sericin films were prepared using different extraction methods, and the molecular conformation of sericin was examined using Fourier-transform infrared spectroscopy with attenuated total reflection geometry. Additionally, the effect of the film side (air-facing side or plate-facing side) on the molecular conformation of the sericin films was investigated. Interestingly, the molecular conformation of the sericin film depended on the film side. The molecular conformation of air-facing side of the sericin film was significantly influenced by extraction solution and time. The ${\beta}$-sheet crystallization and the crystallinity index of the sericin film markedly increased with an increase in the extraction time in hot water. The order of the crystallinity indices for the sericin films obtained with different extraction solutions was as follows: citric acid solution > urea solution >> hot water. In contrast, no remarkable differences were observed in the molecular conformation of the plate-facing side of the sericin film after extraction in hot water for different time periods. Urea and citric acid solution extractions showed remarkably higher crystallinity indices for sericin than those obtained after hot water extraction. However, no significant differences were observed in the crystallinity index of sericin between urea and citric acid solution extraction in plate-facing side of the film.

유류로 오염된 철로지역의 지중정화를 위한 영향반경 산정과 공기주입법/토양증기추출법의 적용성 평가 (Calculation of Radius of Influence and Evaluation of Applicability of Air Sparging/Soil Vapor Extraction system for the Remediation of Petroleum Contaminated Rail Site)

  • 조장환;박정구;김용덕;서창일;김해금;최상일
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권1호
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    • pp.1-6
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    • 2015
  • The objectives of this study were to calculate the radius of influence (ROI) of well for an air-sparging (AS)/soil vapor extraction (SVE) system and to evaluate the applicability of the system applied for the remediation of the petroleum contaminated rail site. For air permeability test, three monitoring wells were installed at a location of 1.3 m, 2.3 m, 3.0 m from the extraction well. And the pressure of each monitoring well was measured by extracting air from the extraction well with the pressure and flow of $(-)2,600mmH_2O$ and $1.58m^3/min$. The ROI for an extraction well was calculated as 4.31 m. Air was injected into the injection well with the pressure and flow of $3,500mmH_2O$ and $0.6m^3/min$ to estimate the radius of influence for oxygen transfer. Oxygen concentrations of air from three monitoring wells were measured. The ROI of an injection well for oxygen transfer was calculated as 3.46 m. The 28 extraction wells and 19 injection wells were installed according to the ROI calculated. The AS/SVE system was operated eight hours a day for five months. The rail site was contaminated with the petroleum and concentrations of benzene, toluene, and xylene were over the 'Worrisome Standard' of the 'Soil Environment Conservation Act'. The contaminated area was estimated as $732m^2$ and contaminants were dispersed up to (-)3 m from the ground. During the operation period, soil samples were collected from 5 points and analyzed periodically. With the AS/SVE system operation, concentrations of benzene, toluene, and xylene were decreased from 7.5 mg/kg to 2.0 mg/kg, from 32.0 mg/kg to 23.0 mg/kg, from 35.5 mg/kg to 23.0 mg/kg, respectively. The combined AS/SVE system applied to the rail site contaminated with volatile organic compounds (VOCs) exhibited a high applicability. But the concentration of contaminants in soil were fluctuated due to the heterogeneous of soil condition. Also the effect of the remediation mechanisms was not clearly identified.

초임계유체추출과 GC/MS를 이용한 도심 대기분진 중 PAH들의 신속한 분석법에 관한 연구 (A Rapid Method for Analysing Polycyclic Aromatic Hydrocarbons (PAH's) in Urban Dust Using Supercritical Fluid Extraction (SFE) and Gas Chromatography/Mass Spectrometry (GC/MS)허귀석, 김달호)

  • 허귀석;김달호
    • 대한화학회지
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    • 제38권10호
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    • pp.726-733
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    • 1994
  • 대기부유분진(air particulate material)중에 존재하는 다환방향족탄화수소(polycyclic aromatic hydrocarbons, PAH)를 신속하고 정확하게 분석하기 위하여 대기부유분진 시료를 10ml의 초임계유체($N_2O$ )로 30분간 추출 후 별도의 전처리와 농축과정 없이 GC/MS에서 분석하여 분석시간과 분석과정을 단축 및 단순화하였다. 시료로서 NBS 대기부유분진 인증표준기준물질(certified particulate reference material, CRM)1649와 서울의 도심에서 채취한 대기부유분진 시료를 이용하여 기존의 추출법 및 분석방법과 비교하였다. 그 결과 본 분석방법은 기존의 분석법에 비해 회수율은 상대적으로 작았으나 재현성이 좋았으며 분석과정이 간단하고 분석시간이 현저히 단축됨을 알 수 있었다.

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LNG추출과정과 냉열이용의 열역학적 해석 (Thermodynamic Analysis of the Extraction Process and the Cold Energy Utilization of LNG)

  • 이근식;장영수;노승탁
    • 설비공학논문집
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    • 제7권1호
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    • pp.120-131
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    • 1995
  • Thermodynamic analysis of extraction process from the constant pressure LNG(Liquefied Natural Gas) vessel was performed in this study. LNG was assumed as a binary mixture of 90% methane and 10% ethane by mole fraction. The thermodynamic properties such as temperature, composition, specific volume and the amount of cold energy were predicted during extraction process. Pressure as a parameter ranges from 101.3kPa to 2000kPa. The result shows the peculiar phenomena for the LNG as a mixture. Both vapor and liquid extraction processes were investigated by a computer model. The property changes are negligible in the liquid extraction process. For the vapor extraction process, the temperature in the vessel increases rapidly and the extracted composition of methane decreases rapidly near the end of extracting process. Specific volume of vapor has the maximum and that of liquid has the minimum during the process. When pressure is increased, specific volume of vapor decreases and that of liquid increases. It was found that specific volume of vapor phase had a major effect on the heat absorption at constant pressure during vapor extraction process. If the pressure of the vessel increases, the total cold energy which can be utilized from LNG decreased.

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대구 지하철역 제연의 문제점과 대책 II. 배기방식 제연설비의 풍량 (A Numerical Simulation of Smoke Control in Daegu Subway Stations II. Air Flowrate of Extraction System)

    • 한국화재소방학회논문지
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    • 제17권4호
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    • pp.105-110
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    • 2003
  • II부에서는 I부에서 3가지 기계제연방식 중에서 가장제연성능이 우수한 것으로 나타난 배기방식의 풍량 0.6∼2.4 ㎥/s와 두 화재크기 200 ㎾와 2 ㎿에 대한 공간내 온도와 연기입자의 분포를 조사하였다. I 부와 동일한 수치법을 동일한 계산영역에 적용한 결과, 배기풍량은 제연성능에 큰 영향을 미치는 것으로 나타났고, 두 화재크기에서 풍량의 증가가 제연성능을 개선하는 비슷한 경향을 보였다. 주어진 조건에서 대피로의 온도를 $60^{\circ}C$ 이하로 유지하기 위해서는 2.4 ㎥/s 이상의 배기풍량이 필요함을 알 수 있었다.

가스상 물질의 농도변화를 이용한 오염토양 복원의 타당성 평가 (The Effective Evaluation of Soil Remediation Technology by Gas Phase Concentration Trend)

  • 박덕신;정우성;강순기;김무훈
    • 대한환경공학회지
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    • 제22권7호
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    • pp.1233-1241
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    • 2000
  • 디젤로 오염된 토양에서 토양증기추출(soil vapor extraction)과 생물학적통풍(bioventing)을 혼합한 파일럿 테스트를 실시하여 기술의 적용 가능성과 운전조건을 파악하였다. 본 연구에서는 오염된 지역의 복원율을 평가하는 중요한 인자인 공기투과도(air permeability)와 가스상 물질의 농도변화를 구하였다. 실험결과 공기투과도는 1985~1194 darcy로서 토양증기추출의 적용에 적합한 것으로 나타났다. 생물학적통퐁 실험에서는 실험결과 $3.5m^3/hr$의 유량으로 공기를 주입했을 때 미생물 활성도에 따른 생분해율이 가장 높았으며, 연구결과 이 지역과 같이 디젤로 오염된 지역에서 혼합형 시스템을 적용하는 것이 바람직할 것으로 판단된다.

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두경부 수술후 발생한 인두피부누공의 치료 (Pharyngocutaneous Fistula after Head and Neck Surgery)

  • 정은재;정광윤
    • 대한기관식도과학회지
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    • 제14권1호
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    • pp.5-7
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    • 2008
  • Subcutaneous cervicofacial, mediastinal emphysemas are complications associated with head and neck surgery, trauma, infectious processes, tooth extraction. Drill cooling stream and dental syringe air ject are the sources of high pressure air that may enter exposed soft tissue. Since the introduction of the high-speed air turbine drill in the 1960s, The incidence of iatrogenic subcutaneous emphysema has increased. Most cases begin to resolve after 2 to 3 days and residual swelling is usually minimal at the end of 7 to 10 days. Surgical approach is not advised because it is likely to be ineffective. The differential diagnosis of neck swelling after dental procedure includes hematoma, cellulitis, angioedema, allergic reaction, subcutaneous emphysema. We report a rare case of patient with subcutaneous cervicofacial emphysema and mediastinal emphysema secondary to third molar extraction.

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순환 공기 유량의 변화를 고려한 열펌프 건조기의 성능 해석 (Analysis on the Drying Performance with the Flow Rate of Circulation Air in a Heat Pump Dryer)

  • 이공훈;김욱중;이상열
    • 설비공학논문집
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    • 제21권1호
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    • pp.1-8
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    • 2009
  • The simulation of a heat pump dryer has been carried out to figure out the effect of air flow rate on the drying performance represented by MER, SMER, and so on. The simulation includes the analyses of one-stage heat pump cycle and simple drying process using the drying efficiency. The heat pump cycle with Refrigerant 134a has been considered. In the dryer, some of drying air from the drying chamber flows through the heat pump system, the rest of air bypasses the heat pump system. The two air flows joins before the drying chamber inlet. The performance parameters considered in the present study are MER, SMER, the temperature and humidity of drying air. Those parameters are compared for different total air flow rate or bypass air flow rate.

Introduction of Modifying Solvents to Carbon Dioxide in Supercritical Extractions

  • 이정미정;David J. Chesney
    • Bulletin of the Korean Chemical Society
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    • 제19권12호
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    • pp.1351-1355
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    • 1998
  • A simple apparatus for adding a modifying solvent to supercritical CO2 extractant was described. Small, fixed volumes (typically 100 μL) of liquid modifying solvents were delivered during the extraction process by use of an in-line high pressure loop injector and an air pump. Without disconnecting the extraction cell from the supercritical fluid extraction system, the modifying solvent was repeatedly delivered. The solvent modification device was optimized during the extraction of carbaryl and bis(acetylacetonato) copper(Ⅱ). Extraction recoveries from spiked filter paper and soil samples ranged between 22% and 109%, depending on the analyte and matrix components. The addition of polar modifying solvents were necessary to improve the extractability of the nonpolar CO2.

토목섬유 연직배수재를 활용한 토양증기추출복원시스템의 수치해석 (Numerical Analysis of Soil Vapour Extraction Remediation System using Prefabricated Vertical Drain)

  • 신은철;박정준;이규웅
    • 한국지반신소재학회논문집
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    • 제7권4호
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    • pp.1-8
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    • 2008
  • 토양증기추출공법(SVE)은 불포화 지반상태에서 휘발성 유기화합물(VOCs)과 유류오염 물질을 제거하는데 효과적이고 경제적인 공법중의 하나이다. 그러나 토양증기추출공법은 투기계수가 1 Darcy보다 작은 실트질 흙과 같이 낮은 투기계수를 가진 지반에서는 비효율적이다. 본 연구의 목적은 연직배수재를 토양증기추출기술중 관정으로서의 적용성과 공기 흐름 패턴에 대한 해석적 방법이다. 즉, 연직배수재를 이용한 실내 모형실험의 공기 추출 시험 결과를 바탕으로 하여 단일 배수재로서의 수치해석 모델을 검증하였다. 또한, 추출 시험결과로 투기계수를 결정하여 단순 분석적 접근의 유효성도 평가하였다.

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