• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.145-150
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• 1998

This study deals with the effect on performance of epoxy resign mortar mixed special cement for surface control and maintenance of aging concrete construction. The test of main property of epoxy resign in this study are the evaluation on the adhesive strength between substrate and epoxy resign mortar under the environment of wet or concrete substrate surface. We gained the test results of good adhesive strength over 15 kgf/$\textrm{cm}^2$ under the wet and dry condition of concrete surface.

• 폴리머
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• 제25권3호
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• pp.359-366
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• 2001

본 연구에서는 유리섬유/에폭시수지 복합재료의 등온물리시효 거동을 torsional braid analysis (TBA)-torsion pendulum을 이용하여 따양한 경화도(유리전이온도로 모니터된)와 등온시효온도(T$_{a}$ )에 대하여 조사하였다. 이때 시효온도는 1$0^{\circ}C$에서 $130^{\circ}C$로, 경화도는 $T_g$=$76^{\circ}C$에서 완전 경화물의$ T_g$=$177^{\circ}C$로 변화시켰다. 모든 경화도에서 등온물리시효 효과가 $T_g$ 부근의 일정온도 영역에서 탄성율과 대수감소율의 변화로 나타났다. 일정 시효온도에서 시효시간에 따른 탄성율의 변화로부터 결정된 등온물리시효속도는 $T_a$=$90^{\circ}C$ 아래에서 경화도가 증가함에 따라 감소하다가 증가하는 양상을 보였다. 시효속도와 ($T_g$-$T_a$)의 그림에서 평행과 수직 이동에 의해 중첩이 됨을 확인할 수 있었으며, 이는 물리시효과정이 경화반응에 의한 화학구조의 변화에 영향을 받지 않는다는 것을 의미한다. 본 연구에서는 약 $70^{\circ}C$ 아래의 시효온도에서는 등온시효동안 수분이 흡수되며 그것으로 인해 시효속도가 감소한다는 전을 알 수 있었다. 이는 물분자와 사슬의 히드록 시기와의 강력한 극성결합으로 사슬의 운동성감소에 기인하는 것으로 생각된다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1992년도 하계학술대회 논문집 B
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• pp.976-979
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• 1992

There are lots of problem which are delaminations and partial discharge of insulation materials in high-voltage rotating machines caused by mechanical, electrical and thermal aging. Several experiments have been aiming at finding the useful diagnostic parameters from the partial discharge characteristics by applying a new measurement techniques. This paper deals with the partial discharge characteristics (pulse height, pulse angle, pulse frequency spectrum and time interval), which may be a useful diagnostic concept in predicting insulation condition of mica/epoxy composite insulation materials, by using several measurement equipments (frequency spectrum analyzer. multichannel analyzer and time interval analyzer).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.199-202
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• 1998

In examining application of polymer as electrical insulators, it is very important to perform accelerated aging test substituted the process which polymer insulator is degraded for long-time by the process of short-time. The purpose of this paper is to examine the properties of water degradation which affect on the efficiency of epoxy insulator. To do this, the surface properties on epoxy insulating material have been investigated after long-time accelerated degradation in boiling water condition. The experimental results showed the contact angle and surface resistivity after treatment to decrease the sample of water treatment. In dielectric properties, dielectric constant was increased by the aging development with water treatments.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권2호
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• pp.59-65
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• 2003

Electrical properties such as permittivity and tan$\delta$ of unaged (control) and aged (72 h at 18$0^{\circ}C$) mica/epoxy composites of 130 ${\mu}{\textrm}{m}$ thickness were measured and their surface conditions were characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR), electron spectroscopy for chemical analysis (ESCA), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Both permittivity and tan6 of control specimens were higher than those of short-time aged specimens. FTIR results show a new peak at 1710 $cm^{-1}$ / for short-time aged specimens, originating from carbonyl group formed by the oxidation reaction during the aging process. ESCA results show that the binding energy at 532.9 eV representing the singlet state of oxygen ( $O_{1s}$) decreases by 13.7%, whereas that at 534.6 eV increases by 13.7%. Glass transition temperatures of control and short-time aged specimens are observed to be 95.4$^{\circ}C$ and 113.4$^{\circ}C$, which increase with the increase of aging time. TGA results indicate that the control specimens contain a smaller amount of volatile components than the short-time aged specimens.s.

• 한국문화재보존과학회:학술대회논문집
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• 한국문화재보존과학회 2006년도 제23회 학술대회 발표 논문집
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• pp.111-117
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• 2006

• Journal of Electrical Engineering and information Science
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• 제2권3호
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• pp.71-76
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• 1997

A lot of experiments and analyses have been done to determine the aging mechanism of mica-epoxy composite material used for large generator stator windings in order to estimate remaining life of the generator for last decades. After degrading artificially the mica-epoxy composite material, the surface analysis is performed to analyze breakdown mechanism of insulation in air and hydrogen atmosphere; i) In the case of air atmosphere, it is observed that an aging propagation from conductor to core by partial discharge effect and the formation of cracks between layers is widely carbonized surface. ii) In case of hydrogen atmosphere, the partial discharge effect is reduced by the hydrogen pressure (4kg/$\textrm{cm}^2$). Potassium ions forming a sheet of mica is replaced by hydrogen ions, which can lead to microcracks. It is confirmed that the sizes of crack by SEM analysis are 10∼20[$\mu\textrm{m}$] in length under air, and 1∼5[$\mu\textrm{m}$] in diameter, 10∼50[$\mu\textrm{m}$] in length under hydrogen atmosphere respectively. The breakdown mechanism of sttor winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the postassium ions of mica components are replaced by H\ulcorner, H$_3$O\ulcorner at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium enable creation of voids and cracks due to thermal, mechanical, electrical and environmental stresses.

• Composites Research
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• 제22권5호
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• pp.37-42
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• 2009

온도, 수분 및 자외선과 같은 자연환경을 모사할 수 있는 가속노화시험장치를 적용하여 복합적인 환경인자에 노출된 탄소섬유/에폭시 복합재의 열분석 특성과 화학구조분석을 수행하였다. 복합적인 환경인자의 최대 노출시간은 3000시간으로 노출시간에 따른 복합재의 열분석 특성과 화학구조는 Modulated DSE와 FTIR을 통해 조사하였다. Modulated DSC 시험을 통한 연우-결과에 따르면 노출시간이 증가할수록 복합재 내에 치밀한 망사 구조가 형성되어 유리전이온도는 증가함을 알 수 있었다. 또한 노출시간이 증가할수록 복합재의 특성에 영향을 미치는 물리시효가 발생하여 엔탈피 완화현상을 나타내는 흡열 피크가 관찰되었다. 아울러 FTIR 시험을 통해 관찰된 피크의 위치는 노출시간에 큰 영향을 받지 않지만 피크의 세기는 노출시간이 증가할수록 에폭시기에 발생되는 경화 반응으로 인해 점차 감소함을 알 수 있었다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2001년도 추계학술발표회요약집
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• pp.358.2-358
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• 2001

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2002년도 봄 학술발표회 논문집
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• pp.395-400
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• 2002

Epoxy coating and sealing used in nuclear plants for the protection of radiation degrades with aging and hazardous atmosphere. In order to evaluate the degradation of the epoxy, dependence of the acoustic impedance on the change of mechanical properties has been used. Unlike metals, the surface of the epoxy coating on a concrete liner is so wavy that the acoustic impedance is difficult to measure by using the reflectivity of the ultrasound on the interface surface because of the irregular reflection and propagation from the epoxy surface. SA(simulated annealing) algorithm is applied to calculate the acoustic impedance using a reflection wave from the rough epoxy surface. The surface waviness and acoustic impedance are taken into account and determined by SA method to evaluate the state of degradation quantitatively.