• Title/Summary/Keyword: Ag content

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Ag-Sb Minerals from the Yeonhwa 1 Mine (제 1 연화광산에서 산출되는 Ag-Sb계의 광물)

  • 정재일;김형수;전서령
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.2
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    • pp.141-146
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    • 1991
  • Minerals of system Ag-Sb have been found in iead-zinc (-silver) ores from the Dongjeom and the Taebaeg ore deposits, which were formed at later stage of the Yeonhwa 1 mine mineralization. The Ag-Sb minerals are intergrown intimately with galena, pyrargyrite and alabandite. Their chemical compositions as determined by electron microprobe analyser show that they are chracterized by relatively high content of S, up to 5.89 atomic percent. Also the composition of the minerals may be separated into two: Ag3.89 Sb1.00-Ag7.19 Sb1.00 and Ag2.96 Sb1.00-Ag4.00 Sb1.00.

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Ag-Cu Powders Prepared by Electrical Wire Explosion of Cu-plated Ag Wires (동도금한 은선재의 전기선폭발에 의해 제조한 Ag-Cu분말)

  • Kim, Won-Baek;Park, Je-Shin;Suh, Chang-Youl
    • Journal of Powder Materials
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    • v.14 no.5
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    • pp.320-326
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    • 2007
  • Ag-Cu alloy nano powders were fabricated by the electrical explosion of Cu-plated Ag wires. Ag wires of 0.2mm diameter was electroplated to final diameter of 0.220 mm and 0.307 mm which correspond to Ag-27Cu and Ag-68Cu alloy. The explosion product consisted of equilibrium phases of ${\alpha}-Ag$ and ${\beta}$-Cu. The particle size of Ag-Cu nano powders were 44 nm and 70 nm for 0.220 mm and 0.307 mm wires, respectively. The Ag-Cu nano powders contained less Cu than average value due to higher sublimation energy compared to that of Ag. As a result, micron-sized spherical particles formed from liquid droplets contained higher Cu content.

Compositional Variations of Sphalerites and Their Genetic Characteristics from Gold and/or Silver Deposits in Central Korea (한국 중부지역 금은광상산 섬아연석의 조성변화와 성인적 특성)

  • Choi, Seon-Gyu
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.135-143
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    • 1993
  • Chemical compositions of sphalerites from 25 gold and/or silver deposits in central Korea were obtained with an electron probe microanalyzer. The FeS contents of sphalerites depend generally upon the assemblage of associated iron sulphides (pyrite and/or pyrrhotite) especially. The sphalerites coexisting with pyrrhotite show a narrow range of FeS variation, but the sphalerites associated with pyrite and/or pyrrhotite have the variable and wide range of FeS contents. The sphalerites from Au-dominant deposits, which vary considerably in each deposit, are generally characterized by high CdS content and low MnS content. On the contrary, the sphalerites from Ag-dominant and Au-Ag deposits tend to be characterized by relatively high MnS and very low CdS content. Based upon the mineralogy, fluid inclusions and stable isotope data, the Au-dominant deposits were formed under higher temperature and deeper depth than the Ag-dominant and Au-Ag deposits. The results suggest the possibility that the diverse sources and evolution of ore fluid at the time of ore deposition are responsible for the deposition of Cd and Mn components in sphalerites.

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Chacterization and Preparation of SiO2-TiO2-AgO thin Films by the Chemical Solution Process (용액법에 의한 SiO2-TiO2-AgO계 박막의 제조 및 특성에 관한 연구)

  • Kim, Sangmoon;Shim, Moon-Sik;Lim, Yongmu;Hwang, Kyuseog
    • Journal of Korean Ophthalmic Optics Society
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    • v.3 no.1
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    • pp.217-222
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    • 1998
  • Coating films of $SiO_2-TiO_2-AgO$ have been prepared on soda-lime-silica slide glasses and single crystal silicon wafer by the sol-gel method using a spin-coating technique. Commercially available tetraethyl orthosilicate, titanium trichloride, and silver-nitrates were used as starting materials. The heat treatment temperature of this coating films was $500^{\circ}C$ properly, obtained from TG-DTA result. The films with thickness of 310 nm were prepared by 5 times coating. In the case of l0 mol% AgO, the film showed a crack-free and smooth surface, but the higher Ago content exhibited the more pin hole and the segregated cluster of AgO. The IR absorbance of the films decreased in the range of 400 nm to 700 nm with the increase of annealing temperature. And the reflectance of the coating films decreased and the color was changed light yellow to white yellow with the increase of Ago content.

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Properties of Bi-2223/Ag HTS tapes prepared using powders of varying lead content (Pb 함량을 달리한 전구체 분말에서의 Bi-2223/Ag 초전도 테이프의 특성 변화)

  • Ha, Dong-Woo;Yang, Joo-Saeng;Hwang, Sun-Yuk;Ha, Hong-Soo;Oh, Sang-Soo;Lee, En-Yong;Kwon, Young-Kil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.585-588
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    • 2003
  • Bi-2223 superconducting wires were fabricated by stacking, drawing process with different precursor powders and different heat-treatment histories. The precursor powders were 2 kinds of Pb content. And a part of the tapes were experienced pre-annealing process which caused tetragonal structure of Bi-2212 phase to orthorhombic structure of it was during drawing process. We confirmed the transformation of Bi-2212 phase from tetragonal structure to orthorhombic structure and reduction of second phases. AC magnetization analysis were performed in order to investigate the fraction of Bi-2223 phase in Bi-2223/Ag HTS tape. The cross sections of 55 filaments and 61 filaments were investigated after rolled in order to understand deformation mechanism of superconducting cores. We could achieve best Ic of 70 A class at the Bi-2223/Ag tape using low Pb content of precursor powder and experienced pre-annealing process. AC magnetization analysis was useful to investigate the fraction of Bi-2223 phase in the Bi-2223/Ag tape.

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A Study of Strength, Fracture Toughness and Superconducting Properties of YBCO-Ag Composite Superconductors (YBCO-Ag 복합초전도체의 강도, 파괴인성 및 초전도성질에 관한 연구)

  • Joo, Jin-Ho;Ur, Soon-Chul
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.394-398
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    • 1998
  • We have studied the effect of Ag additions on the microstructure and the related mechanical and supercon¬ducting properties of $ YBa_{2}$$Cu_{3}$$O_{7-\delta}$ (YBCO) superconductors. A 5-15 vol.% of Ag was added to YBCO in the forms of Ag and $AgNO_{3}$, powder and the resultant microstructural evolution was evaluated. It was observed that the strength and fracture toughness of YBCO increased with increasing Ag content. These improvements in strength and fracture toughness are believed to be due to the strengthening mechanisms caused by the presence of Ag. In addition, YBCO-Ag composite superconductors showed higher values of strength and fracture toughness when Ag was added in the form of AgNO, than those of which was added Ag. The higher mechanical properties of YBCO- Ag resulting from $AgNO_{3}$, addition are probably due to the microstructure of more finely and uniformly distributed Ag particles. The addition of Ag also showed slightly improved critical current density of YBCO superconductors.

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Wettability Evaluation of Sn-0.3Ag-0.7Cu Solder Alloy with Different Flux Activity and Indium Addition (플럭스 활성도 및 In 첨가에 따른 Sn-0.3Ag-0.7Cu 솔더 조성의 젖음 특성 변화)

  • Yu, A-Mi;Kim, Jun-Ki;Kim, Mok-Soon;Hyun, Chang-Yong;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.51-57
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    • 2008
  • In this paper, wetting and interfacial reaction properties for low Ag containing Sn-Ag-Cu Pb-free solder alloy, i.e., Sn-0.3Ag-0.7Cu were investigated and compared with those of Sn-1.0Ag-0.5Cu and Sn-3.0Ag-0.5Cu. Melting behavior and stress-strain curves of some Sn-xAg-xCu alloys were also measured using a differential scanning calorimeter(DSC) and a tensile test machine, respectively. In order to enhance insufficient wetting properties of Sn-0.3Ag-0.7Cu alloy, the improvement of wetting properties were analyzed by applying fluxes containing higher content of halide or indium adding of 0.2wt.% into the solder alloy. It was concluded that the small addition of indium is more effective for the improvement of wettability in low temperature range of $230{\sim}240^{\circ}C$ than applying flux containing higher content of halide.

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Preparation and characterization of expanded graphite/Ag nanoparticle composites for the improvement of thermal diffusion

  • Hong, Seok Hwan;Lee, Won Gyu
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.410-415
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    • 2018
  • Expanded graphite (EG)/Ag nanoparticle composites were synthesized by the chemical reduction of Ag ions, followed by the addition of expanded graphite into an Ag reducing solution. The prepared composites showed uniform dispersion of Ag nanoparticles on the surface of expanded graphite and exhibited relatively higher thermal conductivities than those of pure expanded graphite. In the case of 10% Ag content in the composite, the thermal conductivity in the thickness direction was 78% higher than the pure expanded graphite. We suggest that EG/Ag nanoparticle composites are a strong candidate for advanced heat spreading material.

Effects of Pretreatment and Ag Coating Processes Conditions on the Properties of Ag-Coated Cu Flakes (Ag 코팅 Cu 플레이크의 제조에서 전처리 및 Ag 코팅 공정 변화의 효과)

  • Kim, Ji Hwan;Lee, Jong-Hyun
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.617-624
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    • 2014
  • To elucidate the effects of a pretreatment process on the uniformity of Ag electroless plating on Cu flakes, pretreatment time was mainly considered with a mixed solution of 0.15 M ammonium hydroxide and 0.0375 M ammonium sulphate. Optical inspection of Ag-coated Cu flakes determined that the optimal pretreatment time is 120 s. Repetition of the sequence in which Ag plating was done immediately after the pretreatment of 120 s clearly enhanced the plating uniformity. Scanning electron microscopy revealed that holes were formed irregularly on some Cu flakes during the period from the asdropping of an Ag precursor solution to 5 min. The hole formation was judged to be due to continuous removal of Cu on the local surfaces by the repetitive formation and elimination of $Cu_2O$ or $Cu(OH)_2$ layers. However, the increase of the amount of Ag coating suppressed the hole creation and increasingly enhanced the antioxidant property.

Surface Tension of Molten Ag-Sn and Au-Cu Alloys at Different Oxygen Partial Pressures (다양한 산소분압에 따른 용융 Ag-Sn 및 Ag-Cu 합금의 표면장력)

  • Min, Soon-Ki;Lee, Joon-Ho
    • Korean Journal of Materials Research
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    • v.19 no.1
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    • pp.13-17
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    • 2009
  • A semi-empirical method to estimate the surface tension of molten alloys at different oxygen partial pressures is suggested in this study. The surface tension of molten Ag-Sn and Ag-Cu alloys were calculated using the Butler equation with the surface tension value of pure substance at a given oxygen partial pressure. The oxygen partial pressure ranges were $2.86{\times}10^{-12}$$1.24{\times}10^{-9}$ Pa for the Ag-Sn system and $2.27{\times}10^{-11}$$5.68{\times}10^{-4}$ Pa for the Ag-Cu system. In this calculation, the interactions of the adsorbed oxygen with other metallic constituents were ignored. The calculated results of the Ag-Sn alloys were in reasonable accordance with the experimental data within a difference of 8%. For the Ag-Cu alloy system at a higher oxygen partial pressure, the surface tension initially decreased but showed a minimum at $X_{Ag}$ = 0.05 to increase as the silver content increased. This behavior appears to be related to the oxygen adsorption and the corresponding surface segregation of the constituent with a lower surface tension. Nevertheless, the calculated results of the Ag-Cu alloys with the present model were in good agreement with the experimental data within a difference of 10%.