• 제목/요약/키워드: Ag 전극

검색결과 529건 처리시간 0.029초

Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성 (Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size)

  • 김현철;구할본;사공건
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.745-748
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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반도성 PTC $BaTiO_3$ 세라믹에서 전극의 접촉 저항 및 퇴화 (Contact Resistance and Electrode Degradation on Semiconducting PTC $BaTiO_3$ Ceramics)

  • 박철우;조경호;이희영;이재열
    • 한국세라믹학회지
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    • 제33권11호
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    • pp.1231-1236
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    • 1996
  • The electrode resistance of semiconducting PTC BaTiO3 ceramic material was studied in some detail. Comme-rical In-Ag paste In-Ga alloy and electroless plated Ni as well as evaporated Al were chosen as electrode. The contact resistance of electroded samples were measured by both dc resistivity and ac impedance analysis. The aging effect on contact resistance under cyclic loading from -1$0^{\circ}C$ to 85$^{\circ}C$ was also monitored for the prolonged period of time. In case of Al electroded samples the heat treatment and protective coating had effects on the stability against contact resistance degradation. It was also found that the samples with commercial In-Ag paste and electroless plated Ni electrode had good properties of contact resistance against aging.

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PTC $BaTiO_3$ 및 전극의 직류 및 교류 특성 (AC & DC Electrical Characterization of PTC $BaTiO_3$ and Electrodes)

  • 전표용;최경만
    • 한국세라믹학회지
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    • 제28권2호
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    • pp.101-108
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    • 1991
  • 0.2 mo1% La doped BaTiO3 samples were prepared by a wet chemical process (Pechini process) and electrical conductivity were measured from annealing temperatures(800-110$0^{\circ}C$) to room temperature continuously. 2 probe I-V characteristics showed that Pt electrodes were non-ohmic below about 80$0^{\circ}C$ for Ladoped sample. I-V curves showed varistor behavior and breakdown voltages showed PTC-like behavior. AC complex impedance of 0.2 La and 0.05 Mn mo1% doped BaTiO3 samples with three different electrodes (electroless Ni, Pt, Ag electrodes) were measured with temperature variation. Complex impedance plots showed that the samples with electroless Ni electrodes have negligible electrode resistance. Samples with Ag or Pt paste electrodes showed large electrode resistance. PTC effect, which is defined as the ratio of maximum resistance to minimum resistance, was found to be less than 10 for 0.2 mo1% La doped dense sample however greater than 105 with codoping of 0.05 mo1% Mn and 0.2 mol% La.

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전기화학적 방법의 TRC(Total residual chlorine) 측정 연구(I: Au전극 이용) (The Determination of TRC using an Electrochemical Method (I: Au electrode))

  • 이준철;박대원
    • 한국물환경학회지
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    • 제30권3호
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    • pp.298-303
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    • 2014
  • We measured by electrochemical method for TRC (total residual chlorine) in ocean. From the results of Au electrode used for working electrode through cyclic voltammetry test, we obtained charge in voltage ranged from 0.0V-1.0V, and analyzed correlations of charge for TRC. Reduction peak TRC was investigated to be approximately 0.65 V vs. Ag/AgCl, and in the case that salt concentrations and temperatures in ocean appeared different, charge was analyzed for being different in the same TRC. However, in the case that each condition was constant, charge was measured at highly correlations for TRC.

포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성 (Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand)

  • 김현철;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Photolithography 공정으로 제작한 touch screen panel 용 Ag, Al, Cu metal mesh film (Ag, Al and Cu metal mesh films prepared by photolithography for touch screen panel)

  • 김서한;유미영;송풍근
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.287-288
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    • 2015
  • 최근 투명 산화물 전극 (TCO)은 LED, electronic display, solar cell, touch screen panel (TSP) 등 다양한 분야에 많이 사용되고 있다. TCO는 높은 광 투과도와 전도성으로 인해 여러 분야에 많이 사용되고 있으며, 특히 ITO (Sn-doped indium oxide)가 display 분야에 많이 적용되고 있다. 하지만, ITO는 투과도와 면저항의 반비례 관계를 가지므로 더 낮은 면저항이 요구되는 대면적 TSP 분야에 적용되기에는 많은 개선이 필요하다. 따라서, 본 연구에서는 metal mesh film의 연구를 통해 TSP 분야에 사용되는 ITO를 대체하고자 한다. 제작된 mesh film은 모두 면저항은 $15{\Omega}/{\square}$ 이하, 광 투과도 90% (@550nm) 이상을 나타내었다.

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포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 따른 전기화학적 특성 (Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand)

  • 김현철;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-75, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a tent of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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수퍼커패시터용 산화망간전극의 산화처리에 의한 용량 변화 (Change of Capacitance on Maganese Dioxide Electrode for Supercapacitor by Oxidation Treatment)

  • 김한주;홍지숙;신달우;김용철;김성호;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.946-949
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    • 2000
  • Amorphous MnO$_2$$.$ nH$_2$O in 1M KOH aqueous electrolyte proves to be an excellent electrode for a faradic electrochemical capacitor cycled between -0.5 and +1.0 versus Ag/AgCl. In order to observe morphology and crystalline structure of MnO$_2$powder, we analyzed it by XRD and SEM. The effect of oxidation treatment on MnO$_2$electrode was observed by different oxidation voltages. A maximum capacitance of 364F/g was obtained by 1.1V oxidation treatment. This capacitance was attributed solely to a surface redox mechanism

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폴리부타디엔 결합재를 이용하여 만든 탄소반죽전극의 전기화학적 특성에 관한 연구 (Investigations with respect to the electrochemical properties of carbon paste electrode fabricated using polybutadiene binder)

  • 윤길중
    • 분석과학
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    • 제20권1호
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    • pp.49-54
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    • 2007
  • For the practical use as a biosensor, a rubber electrode bound by polybutadiene was newly devised for the determination of hydrogen peroxide. Then its electrochemical behaviors were investigated. The signal could be obtained at low electrode potential between 0.0 ~ -0.5 V (vs. Ag/AgCl) with a detection limit of $1.4{\times}10^{-4}M$ and its potential dependence was linear in the experimental range. Especially its Lineweaver-Burk plot showed a very good linearity giving the evidence of a good enzyme immobilization on the surface of the electrode. And mechanical stability of the electrode resulted from using rubber binder presented a new possibility for the practical use of biosensor.

열처리 방법에 따른 ZTO/Ag/ZTO 다층박막의 특성 개선

  • 공태경;문현주;손동일;최동혁;김대일
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.179.2-179.2
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    • 2015
  • 오늘날 평판표시장치(Flat Panel Display; FPD)는 대면적화, 고정밀화를 요구하고 있으며, 이에 따라 TCO에 요구되는 사양이 점점 까다로워지고 있다. ITO의 사용량을 절감하면서 동시에 우수한 투과도와 전기전도도를 얻기 위해 산화물/금속/산화물 구조와 같이 금속층을 투명 전도막 재료 사이에 삽입한 다층구조의 투명 전도성 필름에 대한 연구가 활발히 진행되고 있다. 산화물/금속/산화물 구조의 다층 박막은 기판상에 Antireflection 코팅으로 사용되어 왔으나 최근 투명 전극 분야에 응용되고 있다. 본 연구에서는 최적의 ZTO/Ag/ZTO 다층박막에 100, 200, $300^{\circ}C$ 열처리와 200W-300, 500, 700 eV 전자빔 조사를 실시하여 특성을 비교하여 보았다. 열처리는 $300^{\circ}C$, 전자빔조사는 200W-700 eV 일 때 가장 좋은 효과가 나타났다. 가장 좋은 두 조건을 비교했을 때 전자빔 조사의 경우 비저항 $7.25{\times}10^{-5}{\Omega}cm$, 투과도 84.2%, Figure of Merit $2.8{\times}10^{-2}[{\Omega}-1]$로 열처리에 비해 좋은 특성을 나타냄을 알수 있었다.

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