• Title/Summary/Keyword: Ag$^{}$ +/ions

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Characteristics of Ag Etching using Inductively Coupled Halogen-based Plasmas

  • Park, Sang-Duk;Lee, Young-Joon;Kim, Sang-Gab;Choe, Hee-Hwan;Hong, Moon-Poe;Yeom, Geun-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.860-863
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    • 2002
  • In this study, Ag thin films deposited on LCD-grade glass were etched using inductively coupled fluorine-based plasmas and the effect of various $CF_4$-based gas mixtures on the Ag etching characteristics were studied. When $CF_4$-based gas mixtures were used with $N_2$, due to the very low vapor pressure of etch products, etch products remained on the substrate after the etching. However, when $CF_4$ used with Ar, residue-free Ag etching could be obtained due to the removal of etch product by sputtering by $Ar^+$ ions.

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Ferricyanide-Sensing Electrodes

  • Ihn, Gwon-Shik
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.36-38
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    • 1986
  • The Ferricyanide-sensing electrodes were prepared with $Ag_2S\;and\;Ag_3Fe(CN)_6$ (mole ratio 3:1-7:1). The 5:1 $(Ag_2S:Ag_3Fe(CN)_6)$ composition is superior to others in terms of potentiometric response, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}M{\sim}10^{-6}M\; Fe(CN)_6^{3-}$ at pH 6.8 with constant ionic strength. The concentration-potential curve was linear and coincided with the Nernstian slope (19.7 mV/decade). Interfering ions were $I^-,\;Br^-,\; SCN^-\;and\;Fe(CN)_6^{4-}$ and the life time of this electrode was 3 weeks. This electrode could be used as the indicator electrode for measuring the ferricyanide and ferrocyanide.

Nanoparticles Modified With Cationic Thiol Surfactant as Efficient Inhibitors for the Corrosion of Carbon Steel

  • Azzam, Eid M.S.;Sami, Radwa M.;Alenezi, Khalaf M.;El Moll, Hani;Haque, A.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.308-316
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    • 2021
  • In this work, we report synthesis, characterization and corrosion inhibition properties of cationic thiol surfactant-capped silver (SC-Ag-NPs) and gold (SC-Au-NPs) nanoparticles. SC-Ag-NPs and SC-Au-NPs were characterized using regular techniques include TEM. Corrosion study was carried out using carbon steel (CS) in 3.5% NaCl aqueous solution and characterized using multiple electrochemical techniques. Our results suggest that the paint containing SC-Ag-NPs and SC-Au-NPs endow efficient corrosion protection to the CS. Especially, SC-Au-NPs based paint form a stronger barrier between the metal and the corrosive ions, leading to better inhibition properties.

Characteristics of Products in the Reaction 40 MeV/nucleon $^{14}N+Ag$

  • Chung, Yong-Hee;Porile, N. T.
    • Bulletin of the Korean Chemical Society
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    • v.15 no.11
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    • pp.971-975
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    • 1994
  • Cross sections and recoil properties have been measured for the fragments produced in the interaction of silver with 40 MeV/nucleon $^{14}N$ ions using off-line ${\gamma}$-ray spectroscopy. The data were used to obtain the isobaric-yield distribution, the mass yield distribution, and the fractional momentum transfer. The values of forward-to-backward ratios were measured to be very large, indicating that substantial momentum transfer occurs at this energy regime. The results are compared with other studies of the interaction of silver with intermediate-energy heavy ions.

Study on Adsorption of Heavy Metal tons by Cheju Scoria (제주 송이(Scoria)를 이용한 중금속 흡착에 관한 연구)

  • 이민규;서근학
    • Journal of Environmental Science International
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    • v.5 no.2
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    • pp.195-201
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    • 1996
  • This study was conducted for the efficient utilization of a scoria, which is abundantly found in Cheju island, as adsorbent and the scoria was examined for its performance in clarification of adsorption of heavy metal ions. The order in heavy metal ions adsorbed on scoria was; Pb+>Cd^{2+}$>Cu^{2+}$>Ag^+$>Co^{2+}$>Zn^{2+}$>Cr^{3+}$>Cr^{6+}$. This tendency was relatively consistent with the decreasing order of radius of hydrated metal ion. Also, the smaller scoria size and the larger amounts of scoria showed higher removal efficiency for heavy metal ions. The same scoria size showed more effective removal efficiency for heavy metal ions at lower initial concentration than at higher initial concentration. The adsorption abilities of original scoria and chemically treated scoria were compared. Adsorption isotherm of scoria was generally obeyed to Freundlich formula than langmuir formula and Freundlich constant, than was obtained in the range of 0.2~0.4.

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A Study on the Desorption Behaviors of Some Heavy Metals on Duolite GT-73 Chelating Resin

  • Kim, Sook-Young;Lee, Jae-Suk;Kim, Young-Man;Choi, Beom-Suk
    • Analytical Science and Technology
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    • v.14 no.6
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    • pp.530-534
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    • 2001
  • Effect of stripping solutions on the Duolite GT-73 chelating resin for ten elements, Ag(I), Al(III), Ca(II), Cd(II), Cu(II), Fe(II), Hg(II), Mn(II), Pb(II), and Zn(II), was investigated. Relation between affinities of the metal ions and solubility products of metal sulfides was studied. The smaller the solubility product of metal sulfideis, the larger the affinitie with the ionsis. The ions which have the solubility products larger than $10^{-23}$ could be effectively desorbed with nitric acid. Complexation with chloride ion enhanced the desorption efficiencies of the ions having moderately strong affinity with the resin. The ions which have very strong affinity by the chelating resin can be desorbed by complextion with thiourea and hydrochloric acid.

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Cu-doped Ge-Se 박막의 스위칭 특성

  • Nam, Gi-Hyeon;Jeong, Won-Guk;Jeong, Hong-Bae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.157-157
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    • 2010
  • Programmable Metallization Cell (PMC) is a memory device based on the electrolytical characteristic of chalcogenide materials. PMC components of Ge-Se doped with Ag ions were studied with help of the previous studies and copper was used for metallic ions taking into account of economy of components. In this study, we investigated the nature of thin films formed by photo doping of Cu ions into chalcogenide materials for use in solid electrolyte of programmable metallization cell devices. We were able to do more economical approach by using copper which play role of electrolyte ions. The results imply that a Cu-rich phase separates owing to the reaction of Cu with free atoms from chalcogenide materials.

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Synthesis and Crystal Structure of Cyclodimetric Ag(I) Complex with 2,3-Bis(2-pyridyl)pyrazine (고리 이합체 2,3-비스(2-피리딜)피라진(트라이플루오르아세테이토)은(I) 착물의 합성 및 결정 구조)

  • Kim, Yun-Ju;Lee, Young-A;Lee, Uk;Jung, Ok-Sang
    • Korean Journal of Crystallography
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    • v.11 no.1
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    • pp.28-33
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    • 2000
  • The slow of 2,3-bis(2-pyridyl)pyarzine(bpp) with Ag(CF₃CO₂) produces crystalline product suitable for X-ray crystallography. Crystallographic characterization of the crystal (C/sub 32/H/sub 20/-F/sub 6/N/sub 8/O₄Ag₂: triclinic P1, a=8.518(5)Å, b=9.546(2)Å, c=10.632(1)Å, α=81.11(1)°, β=87.61(3)°, γ=75.66(3)°, V=827.5(5)ų, Z=1, R=0.0431) has provided that the complex is a cyclic dimer [Ag(bpp)(CF₃CO₂)]₂. Each bpp ligand connects two tetrahedral silver(I) ions in a tridentate mode (Ag-N, 2.26()-2.43(2)Å), and the trifluoroacetato anion is bonded to each silver(I) atom in a monodentate fashion (Ag-O, 2.38(1); 2.39(2) Å). The skeletal cyclic dimer is stable up to 212℃, and drastically decomposes around this temperature.

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Photocatalytic performance of graphene/Ag/TiO2 hybrid nanocomposites

  • Lee, Jong-Ho;Kim, In-Ki;Cho, Donghwan;Youn, Jeong-Il;Kim, Young-Jig;Oh, Han-Jun
    • Carbon letters
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    • v.16 no.4
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    • pp.247-254
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    • 2015
  • To improve photocatalytic efficiency, graphene/Ag/TiO2 nanotube catalyst was synthesized, and its surface characteristics and photocatalytic activity investigated. For deposition of Ag nanoparticles on the TiO2 nanotubes, a polymer compound containing CH3COOAg/poly(L-lactide) was utilized, and the silver particles were precipitated by reducing the silver ions during the annealing process. Graphene deposition on the Ag/TiO2 nanotubes was achieved using an electrophoretic deposition process. Based on the dye degradation results, it was determined that the photocatalytic efficiency was significantly affected by deposition of silver particles and graphene on the TiO2 catalyst. Highly efficient destruction of the dye was obtained with the new graphene/Ag/TiO2 nanotube photocatalyst. This may be attributed to a synergistic effect of the graphene and Ag nanoparticles on the TiO2 nanotubes.

Review on Facilitated Olefin Transport Membranes Utilizing Polymer Electrolytes and Polymer Nanocomposites (고분자 전해질과 고분자 나노복합체를 활용한 올레핀 촉진수송 분리막에 대한 총설)

  • Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.3
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    • pp.173-178
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    • 2016
  • In this short review, the polymer electrolyte membranes consisting of polymer and Ag salts were introduced and various approaches to solve the long-term stability were summarized. In particular, utilizing $AgNO_3$ as carriers with ionic liquid, the replacement of polymer matrix as poly(ethylene phthalate) (PEP) for strong coordinative interactions with Ag ions and the introduction of $Al(NO_3)_3$ to $polymer/AgBF_4$ complexes were introduced for long-term stable facilitated olefin transport membranes. For the polymer nanocomposite membranes, the role of electron acceptors as polarizer on the surface of AgNPs and the approach to solve the low permeance were introduced.