• Journal of the Korean Geotechnical Society
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• v.20 no.3
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• pp.5-11
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• 2004

Characteristics of advective-diffusive transport of inorganic chemicals in clayey soils as well as in two hardened barrier materials of silica and lime are analyzed from the laboratory column test and compared with those of pure diffusive column test. The results show that the average dispersion coefficients of three materials are $4.39\times l0^{-10}\textrm{m}^2 /s,\; 1.98\times l0^{-10}\textrm{m}^2 /s,\; 1.99\times l0^{-10}\textrm{m}^2 /s$, respectively, and the value of clay is higher than that of hardened barrier materials. There was no significant difference between the dispersion coefficients of advective-diffusive column tests and the effective diffusion coefficients from the pure diffusive column tests, if advective velocity was lower than l0$^{-7}$$m^2$/s. The range of dispersion coefficients of advective-diffusive column tests was narrower than that of diffusion coefficients of pure diffusion tests.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.289-300
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• 2019

We have conducted a preliminary numerical analysis to understand the effects of double-diffusive convection on the molar flux at the crystal region during the growth of mercurous bromide ($Hg_2Br_2$) crystals in 1 g and microgravity (${\mu}g$) conditions. It was found that the total molar fluxes decay first-order exponentially with the aspect ratio (AR, transport length-to-width), $1{\leq}AR{\leq}10$. With increasing the aspect ratio of the horizontal enclosure from AR = 1 up to Ar = 10, the convection flow field shifts to the advective-diffusion mode and the flow structures become stable. Therefore, altering the aspect ratio of the enclosure allows one to control the effect of the double diffusive natural convection. Moreover, microgravity environments less than $10^{-2}g$ make the effect of double-diffusive natural convection much reduced so that the convection mode could be switched over the advective-diffusion mode.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.4
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• pp.187-198
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• 2003

Zinc selenide (ZnSe) single crystals hold promise for many electro-optics, acousto-optic and green laser generation applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method based on the dissociative sublimation. We investigate the effects of diffusive-convection on the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration. Our results show that for the ratios of partial pressures, s=0.2 and 2.9, the growth rate increases with the Peclet number and the temperature differences between the source and crystal. As the ratio of partial pressures approaches the stoichiometric value of 2, the rate increases. The mass fluk based on one dimensional (1D model) flow for low vapor pressure system fall within the range of the predictions (2D model) obtained by solving the coupled set of conservation equations, which indicates the flow fields would be advective-diffusive. Therefore, the rate and the flow fields are independent of gravity acceleration levels.

• Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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• 1995.10a
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• pp.108-109
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• 1995

Hypoxia has persisted during summer in the bottom water of the lower portion of the Rappahannock Estuary, a western shore tributary of Chesapeake Bay. A laterally integrated two-dimensional, real-time model, consisting of linked hydrodynamic and water quality models, was developed to study the contributing processes for hypoxia. The hydrodynamic model gives the information of physical transport processes, both advective and diffusive, to the water quality model, which simulates the spatial and temporal distributions of eight water quality state variables. (omitted)

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.3
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• pp.107-114
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• 2019

A computational analysis has been carried out to get a thorough and full understanding on the effects of convective process parameters on double-diffusive convection during the growth of mercurous bromide ($Hg_2Br_2$) crystals on earth and under ${\mu}g$ conditions. The dimensional maximum magnitude of velocity vector, ${\mid}U{\mid}_{max}$ decreases much drasticlly near Ar = 1, and, then since Ar = 2, decreases. The ${\mu}g$ conditions less than $10^{-2}g$ make the effect of double-diffusion convection much reduced so that adequate advective-diffusion mass transfer could be obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.5
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• pp.226-232
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• 2004

One predicts the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration based on one dimensional advection-diffusion and two-dimensional diffusion-convection model. The present results show that for the ratios of partial pressures, s = 0.2 and 2.9, the growth rate increases with the temperature differences between the source and crystal. As the ratio of partial pressure approaches the stoichiometric value, s = 2 from s = 1.5 (zinc-deficient case: s < 2) and 2.9 (zinc-rich case: s > 2), the rate increases sharply. For the ranges from 1.5 to 1.999 (zinc-deficient case: s < 2) and from s = 9 to 2.9 (zinc-rich case: s > 2), the rate are slightly varied. From the viewpoint of the order of magnitude, the one-dimensional model for low vapor pressure system falls within the 2D predictions, which indicates the flow fields would be advective-diffusive. For the effects of gravitational accelerations on the rate, the gravitational constants are varied from 1 g to $10^{-6}$ g for $\Delta$T = 50 K and s = 1.5, the rates remain nearly constant, i.e., 211 mg/hr, which indicates Stefan flow is dominant over convection.

• Proceedings of the Korean Environmental Health Society Conference
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• 2002.04a
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• pp.9-12
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• 2002

Diffusive transport of volatile organic compounds(VOCs) and their degradation by bacteria in unsaturated soils are couple by poorly understood mass transfer kinetics at the gas/water interface. Determination of the fate of VOCs in unsaturated soil is necessary to evaluate the feasibility of natural attenuation as a VOC remediation strategy. The objective of this study was to develop a mechanistically based mathematical model that would consider the interdependence of VOC transport, microbial activity, and sorptive interaction in a moist, unsaturated soil. Because the focus of the model was on description of natural attenuation, the advective VOC transport that is induced in engineered remediation processes such as vapor extraction was not considered. The utility of the model was assessed through its ability to describe experimental observations form diffusion experiments using toluene as a representative VOC in well-defined soil columns that contained a toluene degrading bacterium, Pseudomonas Putida, as the sole active microbial species. The coefficient for gas-liquid mass-transfer, K$\sub$LA/, was found to be a key parameter controlling the ability of bacteria to degrade VOCs. This finding indicates that soil size and geometry are likely to be important parameters in assessing the possible success of natural attenuation of VOCs in contaminated unsaturated soils.

• 한국해양학회지
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• v.30 no.6
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• pp.543-549
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• 1995

The inverse method has been used to estimate a surface velocity field from sequential AVHRR/SST data. In the model, equation system was composed of heat equation and horizontal divergence minimization and the velocity field contained in the advective term of the heat equation, which was linearized in grid system, was estimated. A constraint was the minimization of horizontal divergence with weighting factor and introduced to compensate the null space(Menke, 1984) of the velocity solutions for the heat equation. The experiments were carried out to set up the range of weighting factor and the matrix equation was solved by SVD(Singular Value Decomposion). In the experiment, the scales of horizontal temperature gradient and divergence of synthetic velocity field were approximated to those of real field. The neglected diffusive effect and the horizontal variation of heat flux in the heat equation were regarded as random temperature errors. According to the result of experiments, the minimum of relative error was more desirable than the minimum of misfit as the criteria of setting up the weighting factor and the error of estimated velocity field became small when the weighting factor was order of $10^{-1}$

• Journal of Soil and Groundwater Environment
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• v.16 no.3
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• pp.17-27
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• 2011

Recently, a physically based model of water-table fluctuation due to precipitation is developed based on aquifer water balance model. In the model, it was assumed that the water infiltration into ground surface is advection dominant and immediately reaches to water-table. The assumption may be suited for the sites where the water-table is shallow and/or the permeability of the unsaturated zone is high. However, there are more cases where the model is not directly applicable due to thick and low permeable unsaturated zone. For the low permeability unsaturated zone, the pattern of water flux passing through unsaturated zone is diffusive as well as advective. In this study, to improve the previously developed water-table fluctuation model, we combined the delayed drainage model, which has long been used in well hydraulics, to the water-table fluctuation model. To test the validity of the development, we apply the developed model to 5 different domestic sites. The model parameters are calibrated based on the groundwater hydrograph and the precipitation time series, and the correlation analyses among the parameters are pursued. The overall analyses on the delineated model parameters indicate that the delayed drainage parameters or delay index used in the developed model are able to reveal drainage information in the unsaturated zones.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.33 no.1
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• pp.13-29
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• 2021

A 3-D hydrodynamic model is applied in the Han River Estuary system, Gyeonggi Bay, to understand the mechanisms of salt transport. The model run is conducted for 245 days (January 20 to September 20, 2020), including dry and wet seasons. The reproducibility of the model about variation of current velocity and salinity is validated by comparing model results with observation data. The salt transport (FS) is calculated for the northern and southern part of Yeomha channel where salt exchange is active. To analyze the mechanisms of salt transport, FS is decomposed into three components, i.e. advective salt transport derived from river flow (QfS0), diffusive salt transport due to lateral and vertical shear velocity (FE), and tidal oscillatory salt transport due to phase lag between current velocity and salinity (FT). According to the monthly average salt transport, the salt in both dry and wet seasons enters through the southern channel of Ganghwa-do by FT. On the other hand, the salt exits through the eastern channel of Yeongjong-do by QfS0. The salt at Han River Estuary enters towards the upper Han River by FT in dry season, whereas that exits to the open sea by QfS0 in wet season. As a result, mechanisms of salt transport in the Han River Estuary depend on the interaction between QfS0 causing transport to open sea and FT causing transport to the upper Han River.