• 한국안전학회지
• /
• 제27권6호
• /
• pp.59-63
• /
• 2012

The use of dry chemical powder has been increased as it can be stored for a long period and sustain in stable condition compared to gas or liquid phase extinguishing agents. A new type of dry chemical powder using Zeolite was produced in the research. Chemical powder was adsorbed into Zeolite 13X, a porous material appearing negative catalytic effect, to create extinguishing powder obtaining core shell structure and measured physical properties and run a small scale fire extinguishment. SEM, XRD, TA analysis was also executed, and extinguishing characteristics were measured by fire extinguishing experiment on oil pool fire. The experiment showed that the average particle size of Zeolite 13X was equivalent, indicating about $3{\pm}1{\mu}m$ and thermal analysis result illustrated that Zeolite 13X showed exothermic reaction peaks at $900^{\circ}C$ due to solid-state transformation. Extinguishing characteristics on oil fire of $NaHCO_3$/Zeolite 13X and $NH_4H_2PO_4$/Zeolite were improved, influenced by adsorbed extinguishing powders on Zeolite 13X and Zeolite 13X that contains high phase transition temperature.

• 한국염색가공학회지
• /
• 제32권3호
• /
• pp.121-127
• /
• 2020

The analysis method of relative adsorption of disperse dyes on impregnated polyurethane resin and polyester fiber separately was investigated. The solvents for extracting the dyes from polyurethane resin and polyester fiber were determined by acetone and DMF, respectively. By extracting the dyed fibers with acetone at room temperature within 30 minutes, the dyes adsorbed only on the polyurethane resin could be extracted. And then by additional extracting the same fabrics with DMF at 95℃ for longer than 1 hour, the dyes adsorbed on polyester fabrics was extracted. This means that the dyes adsorbed on polyurethane and polyester could be extracted separately and that relative adsorption of the dyes on the both components could be analyzed quantitatively. Using this analysis method, the relative adsorption of a disperse dye was investigated after reduction clearing with various conditions.

• 신재생에너지
• /
• 제5권4호
• /
• pp.46-51
• /
• 2009

The purpose of this study is to investigate selective adsorption of $CO_2$ from LFG (Landfill gas) by using commercialized NaX-type zeolite adsorbent under the ambient temperature and pressure. The experiment of $CO_2$ adsorption was carried out by using simulated LFG. The $CO_2$ adsorption capacity and separation efficiency of NaX-type adsorbent were investigated by analyzing gas flow rate and gas composition at inlet and outlet of the adsorption reactor. The adsorbed $CO_2$ were desorbed under decompression condition which 0.5 Torr or by air purge. Through the result to use simulated LFG, when the method of VSA was used, 73.2~75.3 mg of $CO_2$ was adsorbed per 1 g commercial adsorbent, when the method of air purge was used, 78.4~83.2 mg of $CO_2$ was adsorbed per 1 g of commercial adsorbent.

• 한국염색가공학회지
• /
• 제4권4호
• /
• pp.81-89
• /
• 1992

Graft polymers of alginic acid-PMMA, different in composition and Mv of branched PMMA, were prepared by emulsion graft polymerization at various MMA concentrations. In aqueous dispersion solution, the adsorption of graft polymer on the montmorillonite was carried out to modify the surface property of powder, and the adsorption of PMMA in organic solvents (acetone, benzene) on the modified surface of powder were observed. The results obtained were as follows. 1. In emulsion graft polymerization of MMA on the sodium alginate in aqueous solution, SA conversion, MMA conversion and % grafting were increased with increasing MMA concentration where as graft efficiency was decreased. 2. The adsorption amount of graft polymer was increased with the elevation of temperature and the increased of dispersion concentration and with the increase of branched PMMA composition of graft polymer. 3. In organic solvent, the adsorption of PMMA on the surface modified particle was proceeded by the orientation along the stretched branched PMMA of adsorbed graft polymer which is in radial direction to the particle surface. 4. The adsorbed amount of PMMA was increased as the temperature and concentration of PMMA solution, the branching of adsorbed graft polymer and the solvency of solvent were increased.

• Bulletin of the Korean Chemical Society
• /
• 제21권8호
• /
• pp.779-784
• /
• 2000

Comparing the adsorption properties and dissociation on a Pt(111) iththat ona Fe(111) surface, we have con-sidered seven coordination modes of the adsorbed binding site: $di-${\sigma}$${\Delta}$\mu\pi/\mu$, 1-fbld,2-fold, and 3-fbld sites. On the Pt(111) surface, t he adsorbed binding site of carbon dioxide was strongestat the1-fold site and weakest at the $\pi/\mu-site.$ The adsorbed binding site on the Fe(111) surface was strongest at the di-бsite and weakest at the 3-fold site. We have found that the binding energy at each site that excepted 3-fold on the Fe(111) surface was stronger than the binding energy on the Pt(111) surface and that chemisorbed $CO_2bends$ because of metal mixing with $2\piu${\rightarrow}$6a_1CO_2orbital.$, The dissociation reaction occured in two steps, with an intermediate com-plex composed of atomic oxygen and ${\pi}bonding$ CO forming. The OCO angles of reaction intermediate com-plex structure for the dissociation reaction $were115^{\circ}Con$ the Pt(111), and $117^{\circ}C$ on the Fe(111) surface. We have found that the $CO_2dissociation$ rea11) surface proceeds easily,with an activationenergy about 0.2 eV lower than that on the Pt(111) surface.

• 한국의류학회지
• /
• 제43권5호
• /
• pp.753-767
• /
• 2019

Dyeing behavior of indigo leaf powder was examined in regards to the effect of the amount of pigments on color and dye adsorption for silk dyed by reduction and nonreduction dyeing. The amount of indigotin and indirubin pigments adsorbed in dyed silk was examined by HPLC-DAD analysis. The color of dyed silk showed 7.7BG - 2.7B hue when silk was dyed at $50^{\circ}C$, and 3.5G - 4.9BG when dyed at $70^{\circ}C$. Blue ($b^*$) and green ($a^*$) color decreased as the pH of dyebath increased. When silk was dyed using nonreduction, R (red) and RP (red purple) hue and R hue was more apparent in samples dyed at $90^{\circ}C$. In reduction dyeing, amount of indigotin detected from silk exceeded the amount that was initially contained in the input dye. The amount of indirubin was lower than indirubin that was initially in the powder. In nonreduction dyeing, silk showed a higher amount of indirubin adsorption compared to silk dyed by reduction. The amount of indigotin adsorbed in silk was lower than the amount initially contained in the input dye. The amount of indigotin and indirubin adsorption was primarily dependent upon the dyeing method-reduction or nonreduction along with dyeing temperature and the pH of dyebath.

• 한국지반환경공학회 논문집
• /
• 제12권10호
• /
• pp.23-28
• /
• 2011

본 연구에서는 생계면활성제, SWA 1503, Triton X-100 및 SDS를 포함하는 다양한 계면활성제의 토양에 대한 흡착 특성을 조사하였다. 프로인드리히 흡착 등온 모델이 계면활성제의 실험 결과를 가장 잘 설명하는 것으로 나타났다. 실험결과 점토 함량의 증가에 따라 계면활성제의 토양에 대한 흡착량이 증가하였다. 이와 같은 결과는 점토가 모래에 비해 표면적이 넓어 점토의 토양표면과 공극에 계면활성제의 흡착이 많이 이루어지는 것에 기인한다. 시간에 따른 흡착실험의 경우 biosurfactant > SWA 1503 > Triton X-100 > SDS 순으로 흡착량이 높은 것으로 나타났다.

• Journal of the Korean Wood Science and Technology
• /
• 제10권2호
• /
• pp.3-11
• /
• 1982

우리나라에 있어서 목재는 중요(重要)한 자재(資財)의 하나이다. 그 이용(移用)에 중요(重要)한 성질(性質)의 하나인 평형함수율(平衡含水率)을 알기 위해 소나무, 미송(美松), 신갈나무 및 라왕등 널리 사용(使用)되고 있는 수종의 횡단면(橫斷面)으로 짝지워진 생재(生材)와 전건재(全乾材)를 공시(供試)하여 서울, 춘천(春川), 대전(大田), 경주(慶州), 진주(晋州), 광주(光州)등 6개 지방(地方)에 소재(所在)하는 임업시험장(林業試驗場)의 백엽상(白葉箱)을 이용(利用)하여서 4년간(四年間)(1970. 1 ~ 1973. 12) 시험(試驗)하여 구한 방습평형함수율(放濕平衡含水率)과 흡습평형함수율(吸濕平衡含水率) 그리고 기후치평형함수율(氣候値平衡含水率)등은 다음과 같다. 1. 소나무, 미송(美松), 신갈나무 및 레드라왕의 방습평형함수율(放濕平衡含水率)은 각각 14.8%, 13.7%, 14.0%, 14.2%이었고, 흡습평형함수율(吸濕平衡含水率)보다 크게 나타났다. 2. 중부지방(中部地方)(서울, 춘천(春川), 대전(大田))의 평형함수율(平衡含水率)은 남부지방(南部地方)(경주(慶州), 진주(晋州), 광주(光州)) 보다 크게 나타났다. 3. 년중(年中) 평형함수율(平衡含水率)은 지방(地方)에 따라 약간 차이가 있었으나 4월(月)이 최저(最低)였고, 8월(月)이 최고(最高)였다. 4. 전국(全國)의 평형함수율(平衡含水率)의 평균(平均)과 범위는 방습평형함수율(放濕平衡含水率) 12.3 ~ 14.2 ~ 15.7(%), 흡습평형함수율(吸濕平衡含水率) 11.3 ~ 13.2 ~ 14.7(%), 기후치평형함수율(氣候値平衡含水率) 12.0 ~ 14.1 ~ 16.4(%) 이었다.

• Journal of the Korean Wood Science and Technology
• /
• 제10권3호
• /
• pp.109-117
• /
• 1982

우리나라에 있어서 목재는 중요(重要)한 자재(資材)의 하나이다. 그 이용(利用)에 중요(重要)한 성질(性質)의 하나인 평형함수율(平衡含水率)을 알기위해 소나무, 미송(美松), 신갈나무 및 라왕등 널리 사용(使用)되고 있는 수종의 횡단면로 짝지워진 생재(生材)와 전건재(全乾材)를 공시(供試)하여 서울, 춘천(春川), 대전(大田), 경주(慶州), 진주(晋州), 광주(光州)등 6개 지방(地方)에 소재(所在)하는 임업시험장(林業試驗場)의 백엽상(白葉箱)을 이용(利用)하여서 4년간(四年間(1970. 1 ~ 1973. 12) 시험(試驗)하여 구한 방습평형함수율과 흡습평형함수율 그리고 기후치평형함수율(氣候値平衡含水率)등은 다음과 같다. 1. 소나무, 미송(美松), 신갈나무 및 레드라왕의 방습평형함수율은 각각 14.8%, 13.7%, 14.0%, 14.2%이었고, 흡습평형함수율보다 크게 나타났다. 2. 中部地方(중부지방)(서울, 춘천(春川), 대전(大田))의 평형함수율(平衡含水率)은 남부지방(南部地方)(경주(慶州), 진주(晋州), 광주(光州)) 보다 크게 나타났다. 3. 년중(年中) 평형함수율(平衡含水率)은 지방(地方)에 따라 약간 차이가 있었으나 4월(月)이 최저(最低)였고, 8월(月)이 최고(最高)였다. 4. 전국(金國)의 평형함수율(平衡含水率)의 평균(乎均)과 범위는 방습평형함수율 12.3 ~ 14.2 ~ 15.7 (%), 흡습평형함수율 11.3 ~ 13.2 ~ 14.7(%), 기후치평형함수율(氣候値平衡含水率) 12.0 ~ 14.1 ~ 16.4(%)이었다.

• 대한환경공학회지
• /
• 제22권11호
• /
• pp.1985-1994
• /
• 2000

본 연구는 페놀의 초기 홉착량, 온도, pH가 유기용매에 의한 페놀 탈착에 미치는 영향을 조사하기 위한 것으로 methanol, acetone, N,N-dimethylformamide(DMF)를 유기용매로 사용하였다. 초기 흡착량은 166.1mg/g, 180.7mg/g, 197.9mg/g의 세 경우, 온도는 $15{\sim}55^{\circ}C$까지 $10^{\circ}C$ 간격으로 다섯 온도 조건, pH는 산성, 중성, 염기성에서의 페놀 탈착율 변화를 살펴보았다. 페놀의 탈착은 용매의 극성 모멘트와 비례하여 methanol < acetone < DMF 순으로 나타났으며, acetone과 DMF의 경우에는 탈착율이 약 90% 정도로 유사하였다. 초기 흡착량이 증가할수록 용매에 의한 페놀 탈착율은 직선적으로 감소하였으며, DMF에 의한 탈착율 감소 정도가 가장 완만한 것으로 미루어 초기 흡착량이 DMF 탈착 성능에 미치는 영향이 가장 적은 것으로 나타났다. 온도가 높아질수록 페놀 탈착도 증가하였으며, methanol의 증가폭이 가장 큰 것으로 미루어 methanol에 의한 페놀 탈착반응이 온도에 가장 민감함을 알 수 있다. 용매 pH가 높아질수록 페놀 탈착율도 증가하였으며, 특히 methanol의 경우는 pH 12에서 페놀의 탈착율이 10% 이상 급격히 증가되었으며, 이는 methanol의 탈착 능력이 pH의 영향을 가장 많이 받는 것으로 추정된다. 세 용매 중에서 methanol의 페놀 탈착율이 가장 떨어졌으나, 온도와 pH를 조절하게 된다면 acetone, DMF와 유사한 탈착율을 보였으며, methanol이 가장 저렴하기 때문에 적정한 탈착 조건을 선정 적용한다면 경쟁력있는 재생 용매로서 가능성을 지니고 있다고 판단된다.