• 한국재료학회지
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• 제25권11호
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• pp.590-597
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• 2015

In this article, poly methyl triethoxy silane was compounded with an inorganic waterproof admixture at a certain ratio to improve the performance of gypsum products; a new type of high-efficiency compound water-proofing additive was also investigated. Furthermore, the waterproof mechanism and the various properties on the hardened gypsum plaster were investigated in detail by XRD and SEM. The results show that the intenerate coefficient of gypsum plaster increased to more than 0.9; the water absorbing rate decreased to less than 10 %. Both the bending strength and the compressive strength of gypsum plaster increased by various degrees. The intenerate coefficient reached a maximum value of 0.73 and the strength of the samples showed almost no change when 5% cement alone was added. In this new type of the high-efficiency compound with waterproof additive, the optimal technological parameters for formulas were obtained to be: 5% cement, 18 % mineral powder, and 0.8% poly methyl triethoxy silane, to compound gypsum plaster. Meanwhile, the production of high performance gypsum as a building material has become possible.

• Geomechanics and Engineering
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• 제17권3호
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• pp.307-316
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• 2019

Dam deformation should be strictly controlled for the construction of 300 m-high rockfill dams, so the rockfill materials need to have low porosity. A method of using composite grout is proposed to reduce the porosity of rockfill materials for the construction of high rockfill dams. The composite grout is a mixture of fly ash, cement and sand with the properties of easy flow and post-hardening. During the process of rolling compaction, the grout admixture sprinkled on the rockfill surface will gradually infiltrate into the inter-granular voids of rockfill by the exciting force of vibratory roller to reduce the porosity of rockfill. A visible flowing test was firstly designed to explore the flow characteristics of composite grout in porous media. Then, the compressibility, shear strength, permeability and suffusion susceptibility properties of composite grout-modified rockfill are studied by a series of laboratory tests. Experimental results show that the flow characteristics of composite grout are closely related to the fly ash content, the water-to-binder ratio, the maximum sand size and the content of composite grout. The filling of composite grout can effectively reduce the porosity of rockfill materials, as well as increase the compression modulus of rockfill materials, especially for loose and gap-graded rockfill materials. Composite grout-modified rockfill tends to have greater shear strength, larger suffusion erosion resistance, and smaller permeability coefficient. The composite grout mainly plays the roles of filling, lubrication and cementation in rockfill materials.

• Computers and Concrete
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• 제10권2호
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• pp.95-104
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• 2012

This study uses recycled green building materials based on a Taiwan-made recycled mineral admixture (including fly ash, slag, glass sand and rubber powder) as replacements for fine aggregates in concrete and tests the properties of the resulting mixtures. Fine aggregate contents of 5% and 10% were replaced by waste LCD glass sand and waste tire rubber powder, respectively. According to ACI concrete-mixture design, the above materials were mixed into lightweight aggregate concrete at a constant water-to-binder ratio (W/B = 0.4). Hardening (mechanical), non-destructive and durability tests were then performed at curing ages of 7, 28, 56 and 91 days and the engineering properties were studied. The results of these experiments showed that, although they vary with the type of recycling green building material added, the slumps of these admixtures meet design requirements. Lightweight aggregate yields better hardened properties than normal-weight concrete, indicating that green building materials can be successfully applied in lightweight aggregate concrete, enabling an increase in the use of green building materials, the improved utilization of waste resources, and environmental protection. In addition to representing an important part of a "sustainable cycle of development", green building materials represent a beneficial reutilization of waste resources.

• 한국건축시공학회지
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• 제13권3호
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• pp.218-226
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• 2013

건설재료 중 시멘트 및 철강은 대표적으로 탄산가스를 발생시키는 재료산업이다. 건설 산업에서의 탄소 배출량 감소를 위해서는 이러한 재료의 사용을 감소시키는 것이 가장 효과적이라고 할 수 있다. 본 연구에서는 시멘트의 사용량을 감소시킨 저발열형 혼합시멘트의 개발을 목적으로 하고 있다. 시멘트 혼합 비율을 10 %로 낮춘 저탄소 배출형 저발열 혼합시멘트의 수화 특성 및 콘크리트의 온도상승 특성을 검토하였다. 시험 결과, 혼화재의 반응 활성화를 위해서는 CaO 및 $SO_3$의 공급원 필요하며, 석고 및 생석회를 적정 배합비율 적용할 경우 초기에는 강도 발현이 다소 지연되지만 장기재령에서는 기존의 저발열 혼합시멘트와 유사한 성능을 확보 가능한 것으로 나타났다. 특히 저탄소 저발열 혼합시멘트의 경우 콘크리트의 수화열도 기존 저발열 혼합시멘트에 비해 감소시킬 수 있는 것으로 나타났다.

• Applied Biological Chemistry
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• 제2권
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• pp.23-28
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• 1961

된장, 간장용 고일(一)지 원료(原料)의 배합비율(配合比率)을 달리하여 만든 고일(一)지의 효소역가(酵素力價)와 이에서 만든 된장의 숙성과정(熟成過程)을 조사(調査)한 결과(結果)는 다음과 같다. 1). 콩이나 보리를 단용(單用)한 고일(一)지보다 대두(大豆):정맥(精麥):소맥(小麥)의 비율(比率)을 $40{\sim}60:$60{\sim}40::20으로 배합(배합)한 고일(一)지가 호정화력(糊精火力), 당화력(糖化力), 단백질분해력(蛋白質分解力)에서 훨씬 우수(優秀)하였다. 2). 보리고일(一)지로 담근 된장보다 효소력(酵素力)이 강(强)한 배합고일(一)지로 담근 된장이단백질분해력(蛋白質分解力)와 환원당생성(還元糖生成)이 더 빠르며 많았다. 3) 국균(麴菌)의 당화력(糖化力). ${\alpha}-Amylase$력(力), Protease활성(活性)의 식염(食鹽)에 의(依)한 영향을 시험한 결과 3자(三子)가 각각 다른 정도오 억제(抑制)되는것을 알았다.

• 한국구조물진단유지관리공학회 논문집
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• 제14권3호
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• pp.144-151
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• 2010

본 연구에서는 고비용의 실리카흄의 대체재로서 인산부산석고와 카올린을 활용한 시멘트매트릭스의 화학적, 기계적 성질에 대하여 분석하였다. 실험을 위하여 인산부산석고는 이수석고 형태인 건조석고, 반수석고, III형 무수석고, II형 무수석고로 실험용시료를 제조하였으며, $900^{\circ}C$에서 소성된 카올린은 서냉과 급냉의 형태로 제조된 메타카올린의 형태로 제조하였다. 또한 이재료를 활용하여 혼합시멘트를 제조하였으며, 제조된 시멘트를 사용하여 실리카 흄을 혼입한 시멘트 매트릭스와 재료적 성능을 비교 평가하였다. 실험결과 급냉 제조된 메타카올린이 다른 재료에 비하여 성능이 우수한 것으로 분석되었다.

• 한국재료학회지
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• 제25권2호
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• pp.75-80
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• 2015

The carbon dioxide($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical method to reducing $CO_2$ for building materials is the addition of slag and fly ash, like pozzolan material, while another method is reducing $CO_2$ production by carbon negative cement development. The MgO-based cement was from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements could improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as main starting materials, as well as silica fume, fly ash and blast furnace slag for the mineral admixture, were carried out for industrial waste material recycling. In order to increase the hydration activity, $MgCl_2$ was also added. To improve hydration activity, $MgCO_3$ and serpentinite were fired at $700^{\circ}C$ and autoclave treatment was conducted. In the case of $MgCO_3$ as starting material, hydration activity was the highest at firing temperature of $700^{\circ}C$. This $MgCO_3$ was completely transferred to MgO after firing. This occurred after the hydration reaction with water MgO was transferred completely to $Mg(OH)_2$ as a hydration product. In the case of using only $MgCO_3$, the compressive strength was 3.5MPa at 28 days. The addition of silica fume enhanced compressive strength to 5.5 MPa. In the composition of $MgCO_3$-serpentine, the addition of pozzolanic materials such as silica fume increased the compression strength. In particular, the addition of $MgCl_2$ compressive strength was increased to 80 MPa.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.781-786
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• 2001

The Salt attack is one of the primary factors that cause the deterioration of durability in steel reinforced concrete structure. And to depreciate the deterioration from the Salt attack in concrete structure, pozzolanic materials are used widely in recent years. In this study, experiments about the resistance of chloride infiltration of concrete according to the replacement rations of Activated Hwangtoh and various pozzolanic materials(silica fume, fly ash, blast furnace slag and non Activated/Activated Hwangtoh) are performed and the results of this study were shown as follows; 1) As the replacement ratios of Activated Hwangtoh were getting higher, the strength of concrete was increased and in case of various pozzolanic materials, strength of Activated Hwangtoh in specimen was better than that of fly ash, blast furnace slag and non Activated Hwangtoh. 2) As the replacement ratios of Activated Hwangtoh were getting higher, the resistance of chloride infiltration of concrete was increased and in case of various pozzolanic materials, silica fume is better than any other pozzolanic materials and Activated Hwangtoh was better than that of fly ash, blast furnace slag and non Activated Hwangtoh.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.425-430
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• 2002

The needs of the times, a cement plays an important roll in the materials field. So, in this research we would like to study on the properties of Photocatalytic Cement for waste gas reduction. The fundamental phenomena of the Photocatalytic Cement were observed by the NOx Analyzer, Bonding strength, SEM, Flow and Surface hardness(Pencil tester). As a result of this study, the Photocatalytic Cement used Photocatalytic powder, admixture and other materials can obtain its physical properties, also photocatalytic efficiency. If we have added a various experiment, we could have to develop the Photocatalytic Cement.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.245-250
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• 1998

The Elastic modulus depends on the elastic property of composition materials, the gravity of aggregate, the bond strength of binder, the usage and quantity of admixture, curing and measuring method, etc. Accordingly, the aim of this study, by manufacturing concrete of practical high strength range(600~ 1000kg/$\textrm{cm}^2$) with the specific cement and mineral admixtures, is to compare elastic modulus with the existing equations and also to estimate elastic property of use materials. As a result, it could be confirmed that the existing equations which were proposed by the ACI 363, CEB-FIP Code, and New-RC have a tendency to the overestimation in general. However, it could be confirmed that the KCI-96 and Norwegian NS 3473 equations are closed to measuring results, and that the elastic modulus property have a different tendency due to types of cements.