• 제목/요약/키워드: Adhesion properties

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광개시제의 함량에 따른 UV 경화형 분체도료의 물리적 특성 (Physical Properties of UV-Curable Powder Coatings with Different Photoinitiator Contents)

  • 문제익;최재훈;황현득;김현중;김남홍
    • 접착 및 계면
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    • 제9권2호
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    • pp.32-37
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    • 2008
  • 광개시제 함량이 0.5 wt%, 1 wt%, 2 wt%인 UV 경화형 분체도료를 배합하고 낮은 온도에서도 용융되는 수지를 선택하여 열민감성 기재에 적용이 가능함을 알아보았다. 열민감성 기재로는 PVC와 목재제품(MDF, 합판 등)을 선택하여 표면경도, 광택, 부착력을 통해서 기재와의 상관관계를 알아보았다. 광개시제 양이 증가할수록 가교밀도가 증가하여 도막이 brittle해지는 경향을 보였고, 그에 따라 부착력이 감소하였다. 열민감성 기재에 적용한 결과, 표면경도는 기재에 영향을 받지 않았지만 광택은 기재에 따라서 차이가 나타났다. 그리고 UV 경화형 분체도료의 부착력은 열민감성 기재에 적용하기에 충분하였다. 본 연구 결과, UV 경화형 분체도료에서 광개시제 함량이 중요한 인자이며 열민감성 기재에 적용이 가능함을 확인하였다.

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계면구조와 박막의 접착 (Interface Structure and Thin Film Adhesion)

  • 이호영;김성룡
    • 접착 및 계면
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    • 제3권4호
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    • pp.37-43
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    • 2002
  • 표면 개질 또는 박막 공정을 위하여 많은 박막 증착 기술들이 지속적으로 개발, 발전되어 왔다. 그러나, 증착된 박막의 접착성이 불량하여 사용 도중에 기판으로부터 분리된다면 아무리 좋은 성질을 가진 박막일지라 할지라도 제대로 사용될 수 없을 것이다. 이처럼 박막의 접착성은 박막의 기능 못지않게 매우 중요하다. 본 원고에서는 계면 구조와 박막의 접착력 사이의 관계와 박막의 접착력에 영향을 주는 인자들을 살펴보았다. 박막의 접착력에 영향을 주는 인자들에는 박막 및 기판의 화학 조성 및 구조, 박막과 기판의 반응성, 기판의 표면 거칠기, 박막의 잔류 응력 등과 같은 내부 인자와 하중, 온도, 습도, 부식환경 등의 외부 인자가 있는데, 이들을 어떻게 조절하여 박막의 접착력을 향상 또는 유지시키는 방법을 알아보았다.

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수용성염에 의한 고무의 접착특성 및 기계적 강도 (A Study on Adhesion of Mechanical Properties of Rubber by Water-soluble salt)

  • 김성혜;전준하;엄기용
    • 접착 및 계면
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    • 제19권2호
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    • pp.55-59
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    • 2018
  • 본 연구는 신발의 겉창인 고무 접착공정에서 버핑, 산, 알칼리 프라이머 전처리 공정을 생략하여 공정의 간소화로 생산 효율을 높이기 위해 수용성염을 포함하는 고무에 대한 접착특성과 기계적 특성을 고찰하였다. 산성염, 염기성염, 중성염을 평가한 결과, 염기성염을 포함된 고무 성형물의 경우 수성 접착제에 대해 우수한 접착효과를 보였다. 이는 염기성염이 하이드로옥시염으로 존재함에 따라 고무표면이 친수화 되면서 수성접착제에 우수한 접착효과를 보였다. 이것은 접촉각 및 IR측정으로 확인할 수 있었다. 또한, 염기성염이 포함된 고무 성형물의 경우 가교밀도가 증가되어 마모 특성 및 경도는 증가하지만 가교시간을 지연시키는 요인으로 작용하였다.

콘크리트 보수용 폴리머 복합재료의 접착강도 특성 (Adhesion Properties of Polymer Composite Materials for Concrete Repair)

  • 지경용;연규석;이윤수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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    • pp.330-335
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    • 1998
  • This research was conducted to evaluate the adhesion in tension of the polymer mortars for cement concrete repair. Various polymer types, binder ratios, and wet/dry conditions of the surface were considered in this study. Styrene-butadiene rubber (SBR) and ethylen vinyl acetate (EVA) used for polymer cement mortars. Epoxy resin (EP), and unsaturated polyester resin (UP) were used for polymer mertars. Adhesion in tension for the dry condition of the substrate surface was higher than that for the wet condition of the substrate surface under the same binder ratio. Therefore, in repairing concrete, the dry surface condition was effective on adhesion.

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Characterization of Adhesion of Bifidobacterium sp. BGN4 to Human Enterocyte-Like Caco-2 Cells

  • Kim, In-Hee;Park, Myung-Soo;Ji, Geun-Eog
    • Journal of Microbiology and Biotechnology
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    • 제13권2호
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    • pp.276-281
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    • 2003
  • The adhesion of probiotic bacteria to the intestinal mucosa is one of the desirable properties for their colonization in the intestinal tract, where these bacteria constantly compete with other bacteria. The adhesion of different strains of bifidobacteria to Caco-2 cells was compared. Among the strains examined, BGN-4 showed the highest adhesion level and the greatest cell surface hydrophobicity (CSH). No close relationship was found between the adhesion and CSH of the strains. Upon protease and heat treatment, the adhesion of the BGN-4 to the Caco-2 cells decreased significantly. The cells grown at $42^{\circ}C$ showed a lower CSH and self-aggregation levels than cells grown at $37^{\circ}C$. The treatment of EGTA did not have any effect on the adhesion. The degree of adhesion did not differ among the experimental groups in which galactose, mannose, or fucose were added in the adhesion assay mixture. The results suggest that the adhesion of the Bifidobacterium to the epithelial cells may be affected by the composition and structure of the cell membrane and interacting surfaces.

폴리우레탄 수지의 물성 및 접착특성에 관한 연구 (A Study on the Physical Properties and Adhesion Characteristics of Polyurethane Resin)

  • 김영준;장기영;김구니;전용철;유종선;박상욱
    • Elastomers and Composites
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    • 제31권2호
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    • pp.104-110
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    • 1996
  • The polyurethane was synthesized by the reaction of polycaprolactone diol(Mw 2000), 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the chain extender. Also, the modified polyurethane polymers based on liquid polybutadiene as a part of soft segment and dimethylolpropionic acid as a chain extender, giving polyurethane with various polarity, were synthesized. The thermal, mechanical, adhesion properties and water contact angles of the polyurethanes were examined. From the result of the water contact angle, the polarity of the acid modified PU containing 6% acid content was unchanged but mechanical and adhesion properties were improved. The water contact angles on polybutadiene modified PU films were increased with increasing polybutadiene content. The mechanical properties of the polybutadiene modified PU were higher than that of acid modified PU. However, the mechanical properties were reduced as polybutadiene content increased. The result is presumably due to phase separation between hard segment and soft segment. The peel strength of the polyurethane introduced with 5wt% polybutadiene was improved about 150% than that of unmodified PU. The same as the mechanical properties, the more polybutadiene was introduced, the lower peel strength was obtained.

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열화처리에 따른 고무와 강선코드간 접착계면의 변화 (Changes in Adhesion Interface between Rubber and Steel Cord with Aging Treatment)

  • 서곤;손봉영
    • 공업화학
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    • 제5권4호
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    • pp.630-636
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    • 1994
  • 열화처리 후 고무와 황동이 피복된 강선코드의 접박계면 변화를 오제 광전자 분광기와 주사 전자현미경으로 조사하였다. 열열화 후에는 접착층의 부분 산화와 추가 성장이, 습윤열화 후에는 접착층과 황동의 부분 소실이, 동적열화 후에는 접착층의 파괴와 철심의 부식이 관찰되었다. 이러한 접착계면의 변화를 인장시험에서 측정된 접착 성질과 관련지어 고찰하였다.

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Development of Polymeric Layer for Enhancing The Adhesion of Nano-devices Fabricated by The Nanotransfer Molding Method

  • 이기석;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.634-634
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    • 2013
  • Transfer molding methods have a problem that weak adhesion between nanostructures and substrates. It is important to make various nano scale applications, also the stability of nanostructure on substrate is related with device performance. We studied an effect of poly 4-vinylphenol (PVP) as the polymeric adhesion layer between organic nanowires and a Si substrate when the nanowires are transferred by liquid-bridge-mediated nanotransfer molding method (LB-nTM). Their structural stability was examined by optical microscopy, scanning electron microscopy as multiple transfer molding and washing process. Field-effect transistors were fabricated with organic semiconductor nanowires on a polymeric adhesion layer and their electrical properties showed no significant difference as the one without the adhesion layer. As a result, adhesion layer can be used in the washing process and making multi-layer nano-scale patterns.

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Improved Adhesion of DLC Films by using a Nitriding Layer on AISI H13 Substrate

  • Park, Min-Seok;Kim, Dae-Young;Shin, Chang-Seouk;Kim, Wang Ryeol
    • 한국표면공학회지
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    • 제54권6호
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    • pp.307-314
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    • 2021
  • Diamond-like carbon (DLC) is difficult to achieve sufficient adhesion because of weak bonding between DLC film and the substrate. The purpose of this study is to improve the adhesion between substrate and DLC film. DLC film was deposited on AISI H13 using linear ion source. To improve adhesion, the substrate was treated by dual post plasma nitriding. In order to define the mechanism of the improvement in adhesive strength, the gradient layer between substrate and DLC film was analyzed by Glow Discharge Spectrometer (GDS) and Scanning Electron Microscope (SEM). The microstructure of the DLC film was analyzed using a micro Raman spectrometer. Mechanical properties were measured by nano-indentation, micro vickers hardness tester and tribology tester. The characteristic of adhesion was observed by scratch test. The adhesion of the DLC film was enhanced by active screen plasma nitriding layer.

에폭시 매입금구 표면거칠기에 따른 전기적, 기계적 특성 연구 (A Study on Mechanical and Electrical Properties at Interfaces Between Epoxy and ifs Molded Metal)

  • 김수연;하영길;이성진;김영성;박완기;김성진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.226-229
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    • 1999
  • Epoxy compound has been used as insulation material in electrical equipment for a long time because of its excellent electrical, mechanical and chemical properties. Nowdays, becoming higher voltage system, the properties of interface between epoxy and metal insert become more important. The breakdown voltage of epoxy compound for electric material is variable according to the surface roughness of metal insert. Generally, with metal insert sanding, the adhesion strength is enhanced and the breakdown strength is reduced. But in this study, we knew that the adhesion strength became enhanced but the breakdown strength didn\`t reduced with metal insert sanding. So in this study sanding. So in this study, we suggest the optimum interface condition by adjusting the surface roughness.

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