• Fire Science and Engineering
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• v.33 no.2
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• pp.47-55
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• 2019

The prediction performance of design fire curves was evaluated using a Fire dynamics simulator (FDS) for a solid fuel fire in a building space by comparing the results with experimental data. EDC 2-step mixing controlled combustion model was used in the FDS simulations and the previously suggested 2-stage design fire (TDF), Quadratic and Exponential design fire curves were used as the FDS inputs. The simulation results showed that smoke propagation in the building space was significantly affected by the design fire curves. The predictions of simulations using design fire curves for the experimental temperatures in the building space were reasonable, but the TDF was found to be the most acceptable for predicting temperature. The predictions with each design fire curve of species concentrations showed insufficient agreement with the experiments. This suggests that the combustion model used in this study was not optimized for the simulation of a solid fuel fire, and additional studies will be needed to examine the combustion model on the FDS prediction of solid fires.

• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.404-409
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• 2006

The catalytic combustion of toluene over Pd-Cu/USY zeolite has been examined by using FT-IR spectroscopy in a closed system under dry and humid conditions. The catalytic combustion of toluene (700 ppmv) in the temperature range of $80-220^{\circ}C$ has been investigated by using a fixed bed reactor. The Pd-Cu/USY catalyst showed the highest catalytic performance with respects to the PdO-CuO/USY and Pd/USY. Comparing to $PdO/Al_2O_3$ catalysts, the slight improvement in conversion was observed over PdO/USY catalysts under humid condition since USY zeolite is hydrophobic substrate and water give an additional oxygen source to zeolite surface like oxygen. The reduced catalysts showed more enhanced catalytic activity due to the reduced activation energy of combustion of toluene than oxidized catalysts such as PdO/USY and PdO-CuO/USY.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.9
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• pp.474-481
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• 2018

The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.5
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• pp.485-493
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• 2016

Recently submarine and unmanned underwater vehicle (UUV) are equipped with a fuel cell system as an air independent propulsion system. Methanol fuel processor can efficiently supply the hydrogen to the fuel cell system to improve the ability to dive. This study investigated the optimal conditions of the methanol fuel processor that may be used in the closed environment. For this purpose, the numerical model based on Gibbs minimization equation was established for steam reformer and three exhaust gas burners. After simulating the characteristics of steam reformer according to the steam-to-carbon ratio (SCR) and the pressure change, the SCR condition was able to narrow down to 1.1 to 1.5. Considering water consumption and the amount of heat recovered from three burners, the optimum condition of the SCR can be determined to be 1.5. Nevertheless, the additional heat supply is required to satisfy the heat balance of the methanol fuel processor in the SCR=1.5. In other to obtain additional amount of heat, the combustion of methanol is better than the increased of SCR in terms of system design.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.2
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• pp.121-127
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• 2010

The in-furnace desulfurization technique is applied to the $O_2/CO_2$ combustion system for the carbon capture and storage (CCS) process because this combustion system does not need an additional chamber for the desulfurization. $CaCO_3$ sorbent particles, which have a wide range in size from a few nanometers to several tens of micrometers, are used for this process. In this study, an experimental system which can simulate the $O_2/CO_2$ combustion system was developed. $CaCO_3$ sorbent particles were exposed to the high temperature reactor at $1200^{\circ}C$ with various residence times (0.33-1.46 s) in air and $CO_2$ atmospheric conditions, respectively. The sorbent particles were then sampled at the inlet and outlet of the reactor and analyzed qualitatively/quantitatively using SMPS, XRD, TGA, and SEM. The results showed that the residence time and atmospheric condition in a high temperature reactor can affect the characteristics of the $CaCO_3$ sorbent particles used in the in-furnace desulfurization technique, such as the calcination rate and reaction mechanism.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.1091-1096
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• 2004

It is necessary to consider the stability, economic environmental-friendly problems by the development of the road, supply of the automobile, environmental problem as designing the exhaust system. To reduce the noise and the vibration of the automobile. The need for stricter regulation limits emission and demand for lower fuel comsumption. According to motor vehicle company develop variable type muffler, dual muffler and active intelligence exhaust system unit. Improvement in engine performance and fuel consumption for demand information of pressure fraction and heat characteristics. To be able to determine these factor for we experiment on each case of exhaust system unit. In this study, in order to establish the optimized conditions design factors which are taking many performance as the variable valve, it shows how the standard performance and the additional element of the exhaust system effects on the engine performance.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.5
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• pp.477-485
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• 2000

The data set was collected on fifty-eight different days with a 24-h sampling period from October 27, 1995 through August 25, 1996. From the chemical mass balance (CMB) analysis of $PM_{2.5}$ in the Chongju area, the contributions from soil, gasoline, diesel, light and heavy oil combustion were 2.6%, 15.4%, 9.0%, 28.8% and 1.5%, respectively. Residual $NO_{3}^{-}$), residual $SO_{4}^{2-}$ and residual OC, possibly formed in the atmosphere. represented additional 8.0, 10.2, and 1.6% of the $PM_{2.5}$, respectively. Other unidentified sources constituted the remaining 22.9%. From the CMB analysis, the $PM_{2.5}$ source contribution for fall, winter, spring and summer were 92, 76.8, 77.5 and 59.2%, respectively.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.113-122
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• 2000

Dynamic structures of unsteady $CH_4$/Air jet diffusion flames with flame-vortex interaction were numerically investigated. A time-dependent, axisymmetric computational model was adopted for this calculation. Two step global reaction mechanism which considers 6 species, was used to calculate the reaction rates. The predicted results including gravitational effect show that the large outer vortices and the small inner vortex street can be well simulated without any additional disturbances in the downstream of nozzle tip. It was found that the temperature and species concentrations had various values for the same mixture fraction in flame-vortex interaction region. This unsteady jet flame configuration accompanying flame-vortex interaction is expected to give good implications for the structure of turbulent flames.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.3
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• pp.19-26
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• 2004

A prior fundamental study was executed using a constant volume chamber to improve the burning properties of lean pre-mixture by the injection of active radicals generated in the sub-chamber. In consequence, RI method shows remarkable progress in the aspects of burning velocity and combustible lean limit compared with SI method. In this study, the necessary additional works have been performed to be based on the former results. We changed parameters as the initial temperature and the initial pressure of mixture. And the effects of residual gas at issue in a real engine were investigated. As a result, the effects of initial temperature were significant, but on the other hand, those of initial pressure were slight. The correlation of passage hole number between overall passage hole area was grasped. And the more detailed analysis is required on residual gas.

• International Journal of Automotive Technology
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• v.8 no.6
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• pp.675-685
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• 2007

A single cylinder SI engine with a VVA system is modeled by the coupling of a commercial 1D simulation package and an additional combustion model and validated by comparison with experimental data. A number of simulations are carried out to investigate the effects of five different VVA systems on the performance and fuel efficiency of the baseline engine. Finally, the simulation model is applied to an extensive computational study to map out the strategies to operate the engines with dual CVVT and dual CVVT-2 step VVL systems in a fuel-efficient manner.