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Asymmetric Synthesis of 12-epi-$PGF_{2α}$ by a Palladium-Mediated, Three-Component Coupling Reaction

  • 이남호;Richard C. Larock
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.859-863
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    • 1995

  • The prostaglandin analogue 12-epi-PGF2α (2) has been synthesized from optically active cis-4-t-butyldimethylsilyloxy-2-cyclopenten-1-ol (4b) in 4 steps in an overall yield of 21%. An extremely efficient Pd(Ⅱ)-mediated, three-component coupling reaction is employed to obtain the key intermediate 9.

  • https://doi.org/10.5012/bkcs.1995.16.9.859 인용 PDF

On the Critical Scattering Phenomena of a Nonpolar Binary Liquid Mixture

  • Dong J. Lee;Shoon K. Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.403-406
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    • 1991

  • Light scattering phenomena are discussed for a nonpolar binary liquid mixture composed of an optically active solute and an optically nonactive solvent in the critical region, using the Fisher theory. Comparing them with those in the case that the Ornstein-Zernike theory is satisfied, the appropriate analytic results are obtained and discussed.

  • https://doi.org/10.5012/bkcs.1991.12.4.403 인용 PDF