• Title/Summary/Keyword: Acrylic/boric acid

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Investigation of acrylic/boric acid composite gel for neutron attenuation

  • Ramadan, Wageeh;Sakr, Khaled;Sayed, Magda;Maziad, Nabila;El-Faramawy, Nabil
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2607-2612
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    • 2020
  • The present work was aimed to show the possibility of using hydrogel (acrylic/boric acid) for evaluation of the neutron radiation shielding. The influence of acrylic acid concentration, different gamma doses and relative contents of boric acid were studied. The physical properties and the thermomechanical stability of the studied samples were investigated. The shielding property of the composite for neutron was tested by Pu-Be neutron source (5 Ci) under room temperature. The neutron fluence rates and gamma fluxes were measured using a stilbene organic scintillator. The macroscopic effective removal cross-section ΣR (cm-1) of fast neutrons and total attenuation coefficient μ (cm-1) of gamma rays has been studied experimentally. The transmission parameters, the relaxation length (??) and the half-value layer (HVL) were obtained. The obtained results indicated that the addition of boric acid to acrylic acid tends to increase the macroscopic effective removal cross-section ΣR (cm-1) to 0.141 compared to 0.094 of ordinary concrete.

Synthesis and Characteristics of Acrylol Borate as New Acrylic Gelator for Lithium Secondary Battery

  • Shin, Hyun-Min;Nguyen, Congtranh;Kim, Byeong-Yeol;Han, Myong-Hee;Kim, Ju-Sung;Kim, Jin-Hwan
    • Macromolecular Research
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    • v.16 no.2
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    • pp.134-138
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    • 2008
  • A novel acrylol borate was designed and synthesized by reacting acrylate monomer and boric acid. The obtained acrylol borate was used as both gelator and anion receptor for the liquid electrolyte in a lithium secondary battery. It was found that the ionic conductivity of the gel polymer electrolyte (GPE) was as high as that of the liquid electrolyte, and the thermal stability of GPE was increased when only 2 wt% acrylol borate was incorporated into the liquid electrolyte. These results suggest that acrylol borate can be used as an effective additive to enhance the thermal stability of the electrolyte without adversely affecting its conductivity. It is believed that the strong complex formation between boron in the gelator and the anion of the salt is responsible for the enhanced thermal stability of the electrolyte solution and the increased ionic conductivity.