• 제목/요약/키워드: Acidic solution

검색결과 743건 처리시간 0.021초

인산염을 이용한 납오염 토양 고정화 반응의 가속화

  • 이의상;이상봉;이인원
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.201-204
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    • 2004
  • Immobilization is seen as a promising technology for lead remediation. In a laboratory experiment, immobilization of lead with soluble P was tested as a function of reaction time and P concentration. The P treated with an acidic solution to enhance heavy metal immobilization was worked into the soil, and within 7 days, lead was stabilized. Different molar ratios of soluble phosphates (super-phosphate and KH$_2$PO$_4$) would be considerably effective to accelerate the formation of highly insoluble minerals due to the lack of leachable Pb in the contaminated soil. Although it was demonstrated that the addition of soluble phosphates with an acidic solution significantly reduced available lead in soil up to over 95%, remaining phosphorus in soil matrix might cause a possible groundwater eutrophication in the near future.

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强酸溶液中에서의 Azoxybenzene 系化合物들의 轉移反應. Wallach 轉移反應 (The Wallach Rearrangement The Behaviour of Monosubstituted Azoxybenzenes in Strongly Acidic Solution)

  • 한치선
    • 대한화학회지
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    • 제6권2호
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    • pp.162-170
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    • 1962
  • The rearrangement reaction of azoxybenzenes into hydroxyazobenzenes in strongly acidic solution has been studied by an U. V. spectrophotometric method and by isolation of the rearranged compound. In all cases under investigation, it appeared that the oxygen atom in the azoxy group migrated to the unsubstituted ring, depending neither on the substituent already present in the other ring, nor on the distance between the oxygen atom and the eligible position; whereas, the position in the open ring, ortho or para, to which the oxygen migrates depends on the substituent already present in the other ring. In all compounds besides ${\alpha}$-and ${\beta}$-4-methyl azoxybenzene, the oxygen atom migrates to the para position. In the case of ${\alpha}$ and ${\beta}$-4-methylazoxybenzene, the oxygen atom migrates to the ortho position of the unsubstituted ring.

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Hydrophobic Core Variant Ubiquitin Forms a Molten Globule Conformation at Acidic pH

  • Park, Soon-Ho
    • BMB Reports
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    • 제37권6호
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    • pp.676-683
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    • 2004
  • The conformational properties of hydrophobic core variant ubiquitin (Val26 to Ala mutation) in an acidic solution were studied. The intrinsic tryptophan fluorescence emission spectrum, far-UV and near-UV circular dichroic spectra, the fluorescence emission spectrum of 8-anilinonaphthalene-1-sulfonic acid in the presence of V26A ubiquitin, and urea-induced unfolding measurements indicate this variant ubiquitin to be in the partially folded molten globule conformation in solution at pH 2. The folding kinetics from molten globule to the native state was nearly identical to those from the unfolded state to the native state. This observation suggests that the equilibrium molten globule state of hydrophobic core variant ubiquitin is an on-pathway folding intermediate.

Probenecid와 Nalidixic Acid의 약물상호작용(藥物相互作用) ( II ) (Drug Interaction of Probenecid and Nolidixic Acid( II ))

  • 최준식;이진환;김용현;이민화
    • Journal of Pharmaceutical Investigation
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    • 제13권4호
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    • pp.183-190
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    • 1983
  • The interaction between probencid and nalidixic acid was studied pharmacokinetically in rabbits infused with or without acidic soiution (5% $NH_4Cl$). The results were as fellows. The blood level and the area under the blood concentration curve of nalidixic acid administered intravenously was elevated by coadministration of probenecid and more elevated in rabbits infused with acidic solution. Probenecid inhibited the urinary excretion of nalidixic acid in rabbits infused with adidic solution. Therefore, biolgcal half-life of nalidixic acid was prolonged by coadministration of probencid.

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프르브유닛 소자용 블레이드형 팁 제조방법 (A Fabrication Method of Blade Type Tip for Probe Unit Device)

  • 이근우;이재홍;김창교
    • 전기학회논문지
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    • 제56권8호
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    • pp.1436-1440
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    • 2007
  • Beryllium copper has been known to be an important material for the various fields of industry because it can be used for mechanical and electrical/electronic components that are subjected to elevated temperatures (up to $400^{\circ}C$ for short times). Blade type tip for probing the cells of liquid crystal display(LCD) was fabricated using beryllium copper foil. The dry film resist was employed as a mask for patterning of the blade type tip. The beryllium copper foil was etched using hydrochloric acidic iron-chloride solution. The concentration, temperature, and composition ratio of hydrochloric acidic iron-chloride solution affect the etching characteristics of beryllium copper foil. Nickel with the thickness of $3{\mu}m$ was electroplated on the patterned copper beryllium foil for enhancing its hardness, followed by electroplating gold for increasing its electrical conductivity. Finally, the dry film resist on the bridge was removed and half of the nickel was etched to complete the blade type tip.

Kinetic Studies on the Reaction of Iron (Ⅲ) with D-penicillamine in Acidic Solution$^1$

  • Hyun-Jae Park;Yung-Hee Oh Kim;Jung-Ae Shim;Sung-Nak Choi
    • Bulletin of the Korean Chemical Society
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    • 제14권4호
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    • pp.444-449
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    • 1993
  • Anaerobic oxidation of D-penicillamine by Fe(III) in acidic solution has been studied kinetically by the use of stopped-flow system. The reaction is biphasic with a rapid complexation of 1: 1 complex, $Fepen^+$ (pen= D-penicillamine dianion) which is then internally reduced to Fe(II) and disulfide. Rates of both the complexation and the redox process are pH dependent and also are affected by the presence of chloride ion. Different from the reaction of Cu(II) with D-penicillamine, partially oxidized mixed-valence complex is not formed even transiently in this reaction.

Environmentally benign. Background-free protein staining in SDS-polyacrylamide gels using an counter ion-dye complex solution.

  • Jin , Li-Tai;Hwang, Sun-Young;Yoo, Gyurng-Soo;Choi, Jung-Kap
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.313.2-313.2
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    • 2002
  • Environmentally benign protein staining method in sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) using both an acidic dye, zincon (ZC) and a basic dye. ethyl violet (EV) is described. It is based on a counter ion-dye staining technique that employs oppositely charged two dyes to form an ion-pair complex. The selective binding of the free dye molecules to proteins in an acidic solution produces bluish violet colored bands. It is a rapid procedure, involving only fixin and staining steps that are completed in 45 min. (omitted)

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排氣가스로 만든 人工酸性雨에 의한 植物의 形態的 症狀 (Plant morphological symptom caused by simulated acidic rain made by fuel gases)

  • Chang, Nam-Kee;Yun-Sang Lee;Soo-Jin Yi
    • The Korean Journal of Ecology
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    • 제16권1호
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    • pp.17-26
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    • 1993
  • We investigated the ph change of water caused by several fuel gases regarded as the main cause of the air pollution, To find out the main cause of increase of the acidity of the rain. We measured it while injrcting each fuel gas directiy to the distilled water. It was observed that bunker-c oil gas and anthracite coal gas were the main cause to make the ph of the solution lowest. We examined the effects of simulated acidic water solutions on several plant species. Simulated acidic rain made by bunker-c oil gas has significant symptom on the saxifraga stolonifera and commelina communis, while no injury was observed on plants exposed to simulated rainfall made by anthracite coal gas.

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왕겨초액 처리지의 항균 특성 (Antimicrobial Properties of Paper Treated with Acidic Liquid from Carbonized Rice Hull)

  • 민춘기;조중연;신준섭;이세은
    • 펄프종이기술
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    • 제43권2호
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    • pp.72-76
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    • 2011
  • Antimicrobial activities of the Acidic Liquid originated from Carbonized Rice Hull(ALCRH) and the paper treated with ALCRH were investigated to apply ALCRH to functional paper products as a natural antimicrobial agent. ALCRH showed antimicrobial activity for bacteria and yeast, with higher performance for bacteria than for yeast. Antimicrobial activity was not developed on paper coated with ALCRH by bar coater probably due to the evaporation of antimicrobial compounds of ALCRH from the paper surface with time. Saturation of paper with ALCRH was essential to develop antimicrobial activity on the paper. Dipping paper in ALCRH solution was recommended as one of the effective ways to make antimicrobial paper.

Reaction Conditions and Mechanism of Electrolytic Reduction of Dibenzoylmethane$^\dag$

  • Kang, Sung-Chul;Chon, Jung-Kyoon
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.414-418
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    • 1987
  • Electrochemical reduction of dibenzoylmethane was studied on mercury electrode by means of cyclic voltammetry, polarography and potentiostatic measurements in ethanol-water system. In acidic solutions monomeric pinacol was produced by irreversible two-electron process while monomeric and dimeric pinacol were competitively produced by the same process in neutral solution. However, in basic solution the dimeric pinacol was mostly produced through radical by irreversible one-electron transfer process. Mechanisms of the reduction of dibenzoylmethane are deduced from Tafel slope, pH dependance and reaction order with respect to the concentration of dibenzoylmethane in the solution of various pH.