• Title/Summary/Keyword: Acidic environment

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EFFECTS OF REACTION TIME AND pH ON FENTON'S BATCH PROCESS FOR THE TREATMENT OF LEACHATE

  • Choi, Heung-Jin;Kim, Il-Kyu
    • Journal of Korean Society on Water Environment
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    • v.18 no.2
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    • pp.169-187
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    • 2002
  • The effects of important parameters such as reaction time and pH on the Fenton's process were evaluated using a batch reactor. It was proven that organic materials and heavy metals in leachate could be successfully removed by Fenton's reagent. Favorable operation conditions were investigated. It was observed that the reaction between ferrous iron and hydrogen peroxide with the production of hydroxyl radical was almost complete in 10 minutes. That is, the oxidation of organic materials by Fenton's reagent was so fast that it was complete in 30 minutes with batch experiments. With the formation of carbonic acid, pH of the batch reactor decreased to favorable acidic conditions without acid addition. The oxidation of organic materials in the leachate showed a pH dependence and was most efficient in the pH range of 2-3.

Visibility Impairment by Acidic Aerosol & Carbonaceous Particles in Urban Atmosphere (산성 에어로졸과 미세탄소 입자에 의한 도시지역 시정감쇄)

  • 김경원;오승진;김영준;김문옥
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.65-66
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    • 1999
  • 도시지역의 시정변화는 일정한 경향성을 지니는 일부 오염물질들의 배출에 의해 지배적인 영향을 받는 것으로 보고되고 있다. Sulfate, nitrate는 대기중의 상대습도와 밀접한 관계를 지니고 있어서, 일일주기로 증감하는 수증기와의 반응에 의하여 입자의 크기가 성장ㆍ감소하여 대상물체의 이미지 형성광(image forming light)을 산란시킴으로써 관측자의 시야 경로부터 빛을 이탈시키는 현상을 나타낸다.(중략)

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Chemical Characteristics of Fine Particulate and Acidic Air Pollutants during Worldcup Game in Korea (월드컵기간 중 산성오염물질과 미세먼지의 화학적 특성에 관한 연구)

  • 장기석;김윤신;이종태;조용성;엽무종
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.308-309
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    • 2002
  • 대기오염의 주요발생원은 자동차 배기가스, 산업시설 발전소, 배경오염물질이다. 비차량 발생원, 질산화물, 일산화탄소, 차량으로부터 배출되는 일부 미세먼지들의 비교는 과거 30년에 걸쳐 사용되고 있는 전세계 차량의 증가 때문에 불균형하게 증가하였다. 대기질에 있어 인위적인 개선의 건강상 영향을 연구할 기회는 드물다. 월드컵기간동안 서울에서의 대기질 개선을 위한 노력의 일환으로 차량 2부제를 시행은 대도시 교통수단 변화의 영향을 연구할 기회를 제공하였다. (중략)

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Assessment of Environmental Contamination caused by the Stone-dust using Leaching Tests (용출실험에 의한 석분토의 지표환경 오염 평가)

  • Kang, Min-Ju;Lee, Pyeong-Koo;Youm, Seung-Jun
    • Journal of Soil and Groundwater Environment
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    • v.15 no.3
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    • pp.52-60
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    • 2010
  • The stone-dust is an unavoidable by-product of aggregate production, which is produced about 0.8~1.0 million $m^3$ annually. The stone-dust is currently regarded as a hazard material on environment because it is classified as an industrial waste in the Waste Management Law of Korea. At present, the stone-dust is considered as a environmentally hazardous material, and is classified as an industrial waste according to the Waste Management Law of Korea. In this study, we assessed the heavy-metal contamination of the stone-dust on surrounding environments by various leaching tests. Leaching experiments (such as Korea Standard Leaching Procedure (KSLP), Soil Environment Preservation Act of Korea (SEPAK), Toxicity Characteristic Leaching Procedure (TCLP), and Synthetic Precipitation Leaching Procedure (SPLP)) show that very low heavy metals (As, Cd, Cu, Pb, Zn, Hg) and CN are leached out, or much less than each regulatory thresholds. The resuts of the leaching test with time in acidic solution (initial pH 5 and 3) indicate that pH-buffering minerals are present in the stone-dust. These results suggest that the stone-dust can not potentially affect adverse impact on surrounding environments such as surface water, groundwater and soil etc..

Removal Characteristics of Arsenic from Abandoned Metal Mining Tailings by Electrokinetic Technique (동전기법에 의한 폐 중금속광산 퇴적토 내의 비소제거 특성)

  • Shin Hyun-Moo;Yoon Sam-Seok
    • Journal of Environmental Science International
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    • v.15 no.3
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    • pp.279-286
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    • 2006
  • Electrokinetic technique was considered in removing arsenic from the abandoned mining tails. In order to estimate the removal characteristics of arsenic, the sequential extraction analysis and desorption experiment were carried out prior to the application of electrokientic process. The result of sequential extraction analysis indicated that the water soluble and exchangeable fraction, easily leachable to ground water, were very low as much as about 2.5% and the fraction except residual (38.3%), possibly extractable under very acidic or alkalic environment, was about 59%. In the result of desorption test using four different kinds of electrolytes, the mixture of citric acid and sodium dodecyl sulfate (SDS) showed the highest desorption efficiency as much as 77.3%. The removal efficiencies of arsenic from mining tailings by electrokinetic process under the different electrolyte environments were slightly low and resulted in the following order: citric acid + SDS (18.6%) > 0.1 $NHNO_3$ (8.1%) > HAc (7.4%) > Distilled water(6.6%). Also, arsenic in soil matrix was moved favorably in the direction of anodic rather than cathodic region, which is opposite trend with cationic metal ions generally existing in soil, because anionic form of arsenic is dominated in acidic soil caused by the movement of acid front form anode.

Study on Growth Characteristics of Lactobacillus Isolated from Broiler Cecum (육계 맹장 유산균의 성장특성에 관한 연구)

  • 김상호;박수영;유동조;장병귀;최철환;박용윤;이상진;류경선
    • Korean Journal of Poultry Science
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    • v.27 no.1
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    • pp.31-35
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    • 2000
  • This study was investigated to observe Lactobacillus spp. population of poultry digestive organ, duodenum, ilium, cecum and colon by growing steps and to select of valuable lactobacilli as probiotics. Two strains of male broiler commercial chickens, Hybrid and Ross, were used to evaluate population of Lactobacillus spp. in intestinal tracts. Three strains of Lactobacillus were identified, and bile salts environment. The number of lactovacilli was the lowest in duodenum compared to other intestinal tracts which had similar population. Population of Lactobacillus was maintained constantly regardless growing steps after one week of age. Identification of Lactobacillus from cecum resulted in L.reuteri BC5, L. crispatus BC7, L.reuteri BC9. All strains was depressed in pH 1 and 2, although two strains could survive for one hour at pH 2. And they could survive at pH 4 for 4hours. In bile salts tolerance, L.reuteri BC5, L.crispatus BC7 were maintained for 2 hours, but the growth reduced from 2hours. Growth of L.reuteri BC9 was increased continuously. In conclusion, Lactobacillus of intestinal tracts were established at first week, and maintained constant population. They were influenced on severe acidic condition and bile salts. Cecal Lactobacillus has different growth charcteristics by strains.

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Acidic Properties and Catalytic Activity of Titanium Sulfate Supported on TiO2

  • Sohn, Jong-Rack;Lee, Si-Hoon;Cheon, Park-Won;Kim, Hea-Won
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.657-664
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    • 2004
  • Titanium sulfate supported on $TiO_2$was prepared by impregnation of powdered $TiO_2$with an aqueous solution of titanium sulfate followed by calcining in air at high temperature. For Ti$(SO_4)_2/TiO_2$ samples calcined at 300 $^{\circ}C$, no diffraction lines of titanium sulfate are observed at $Ti(SO_4)_2$loading up to 30 wt%, indicating good dispersion of $Ti(SO_4)_2$ on the surface of $TiO_2$. The acidity of the catalysts increased in proportion to the titanium sulfate content up to 20 wt% of $Ti(SO_4)_2$. 20 wt% $Ti(SO_4)_2/TiO_2$ calcined at 300 $^{\circ}C$ exhibited maximum catalytic activities for 2-propanol dehydration and cumene dealkylation. The catalytic activities for these reactions, were correlated with the acidity of catalysts measured by ammonia chemisorption method.

Electrochemical Corrosion Failure of ITO-Coated PET Film for Display Application

  • Farooq, Hina;Kim, Hye-young;Byeon, Jai-Won
    • Journal of Applied Reliability
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    • v.17 no.1
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    • pp.72-77
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    • 2017
  • Purpose: The electrochemical corrosion behavior of tin oxide film coated on PET substrates has been studied under varying concentrations of acrylic acid to investigate possible corrosion in contact with the acidic environment. Method: Potentiodynamic test was performed for a commercial ITO/PET film in 0.1, 0.3, and 0.5 M of acrylic acid. The surface morphology was analyzed by scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). Results: Potentiodynamic test results showed an increase in Icorr and decrease in Ecorr value with increasing concentration of acid. Microscopic evaluation suggested the presence of certain deep cracks on the surface of the film in addition with a severe acidic attack. Conclusion: Exposure of ITO to acrylic acid resulted in the stress corrosion cracking of ITO film due to the mechanical mismatch between brittle inorganic ITO fim and a compliant organic PET substrate leading to the subsequent failure of the film.

Interannual Variations of Limnological and Ecological Characteristics in Acidic Lake Katanuma

  • Kikuchi, Eisuke;Takagi, Shigeto;Doi, Hideyuki;Shuichi, Shikano
    • Korean Journal of Ecology and Environment
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    • v.38 no.4 s.114
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    • pp.435-438
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    • 2005
  • We observed the physical, chemical, and biological characteristics of an acidic lake, Lake Katanuma, from 1998 to 2002 at weekly or biweekly intervals, except during the winter. This volcanic lake has a dimictic thermal pattern. In summer, the volcanic heat supply at the lake bottom results in weak thermal stratification. In 1998, 1999, and 2002, short-term holomixis was observed during the stratification period, when the anoxic, hydrogen sulfide-rich water from the hypolimnion spread across the entire lake. In contrast, distinct short-term holomixis did not occur during the stratificatlon period in 2000 and 2001. However, the early onset of the autumn turnover in August 2000 and 2001 caused anoxic conditions to persist throughout the entire water column for more than 2 weeks. The anoxic and hydrogen sulfide-rich conditions affected population densities of chironomid larvae (Chironomus acerbiphilus) and planktonic algae (Chlamydomonas acidophila), both dominant species in Lake Katanuma. Thus, the interannual variations of limnological characteristics influenced the seasonal population changes of these species.