• 제목/요약/키워드: Acid soil

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아세트산의 농도에 따른 Ferrous Soil의 동전기 정화 거동

  • 이정철;김병일;조대호;김수삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.306-309
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    • 2003
  • The natural soil containing organic matter and ferrous is used in the Electrokinetic-Flushing Remediation(EFR) tests. A series of tests are carried out through controlling the concentration of acetic acid in the EFR cell. The test results showed that the electrical potential in X/L=0.9 is increased with the increasing of the concentration, and pH in the sample is the similar at all of the region because of the buffer capacity of natural soil. Finally, the efficiency of EFR is enhanced at acetic acid of 1mM. But it may not be not strongly affected by the concentration of acetic acid.

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Biodegradability of Polylactic Acid Fabrics by Enzyme Hydrolysis and Soil Degradation

  • Lee, So Hee
    • 한국염색가공학회지
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    • 제29권4호
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    • pp.181-194
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    • 2017
  • The biodegradability of polylactic acid(PLA) fabrics was evaluated by two methods: enzyme and soil degradation. Three different enzymes were selected to evaluate. Degradation times were measured at optimal enzyme treatment conditions. Biodegradation by enzymatic hydrolysis was compared with soil degradation. As a result, biodegradation created cracks on the fiber surface, which led to fiber thickening and shortening. In addition, new peak was observed at $18.5^{\circ}$ by degradation. Moreover, cracks indicating biofragmentation were confirmed by enzyme and soil degradation. By enzyme and soil degradation, the weight loss of PLA fabrics was occurred, there through, the tensile strength decreased about 25% by enzyme hydrolysis when 21 days after, and 21.67% by soil degradation when 60 days after. Furthermore, the biodegradability of PLA fabrics by enzymatic and soil degradation was investigated and enzymatic degradation was found to be superior to soil degradation of PLA fabrics. Among the three enzymes evaluated for enzymatic degradation, alcalase was the most efficient enzymes. This study established the mechanism of biodegradation of PLA nonwovens, which might prove useful in the textile industry.

화전토양(火田土壤)의 부식(腐植)에 관(關)한 연구(硏究) (Studies on the humus soil reclaimed by farming for cultivation)

  • 곽판주
    • Applied Biological Chemistry
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    • 제9권
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    • pp.153-159
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    • 1968
  • 강원도(江原道) 춘성군(春城郡) 동산면(東山面) 원창이리(元倉二里) 면내리(面內里)의 화전토양수점(火田土壤數點)을 공시(供試)하여 토양(土壤)의 일반적(一般的) 성질(性質)과 홍법(弘法), 대우(大羽)에 의한 Simon의 수정법(修正法)으로 부식(腐植)의 형태(形態)를 분석검토(分析檢討)하였든바 그 결과(結果)를 요약(要約)하면 다음과 같다. 1) 본화전토양(本火田土壤)은 일반화학성분(一般化學成分)이 보통(普通) 토양(土壤)과 근사(近似)하나 C.E.C.는 크며 유기물(有機物)이 특(特)히 많이 함유(含有)되어 있다. 2) 추출제(抽出劑)에 따른 추출부식(抽出腐植)은 NaOH의 Na-pyrophosphate, NaF.의 순(順)이며 토층(土層)에 따른 추출량(抽出量)은 상층(上層)일수록 많으며 PQ% 역시(亦是) 상층(上層)일수록 크다. 3) 부식화도(腐植化度)는 NaOH. Na-pyrophosphate 추출부식(抽出腐植)은 근사(近似)하나 NaF 추출부식(抽出腐植)은 낮다. 층위별(層位別)로 보면 하층(下層)일수록 높으며 토양(土壤)의 부식화도(腐植化度)의 순위(順位)는 약간 B 토양(土壤)이 높은것 같다. 4) $Mg^{++}$에 의하여 부식산(腐植酸)을 ${\alpha}$ 형(形), ${\beta}$ 형(形)으로 분할(分割)하였으며 NaOH 추출부식산(抽出腐植酸)의 ${\alpha}$ 형(形), ${\beta}$ 형(形) 부식산(腐植酸)이 부식화도(腐植化度)가 높으며 Na-pyrophosphate 추출부식산(抽出腐植酸)의 부식화도(腐植化度)는 낮다. 경작기간(耕作期間)에 따른 부식화도(腐植化度)의 변화(變化)는 별(別)로 찾아 볼 수 없다. 5) ${\alpha}$, ${\beta}$ 형(形) 부식산(腐植酸)의 흡광곡선(吸光曲線)을 보면 추출제(抽出劑)에 따른 변화(變化)는 없고 동일(同一)한 곡선(曲線)이 나타났다.

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CHEMICAL DECONTAMINATION OF SOIL CONTAMINATED WITH Cs-137

  • H. J. Won;Kim, G. N.;C. H. Jung;Park, W. K.;Kim, M. G.;W. Z. Oh;Park, J. H.
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 Proceedings of the 4th Korea-China Joint Workshop on Nuclear Waste Management
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    • pp.83-95
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    • 2004
  • The removal efficiency of several washing agents on the $Cs^+$ ion was investigated. Leaching of $Cs^+$ ion from the soil surface by washing agents is affected by the exchange capability of the washing solution. Reuse tests of the effective soil washing agents such as $BaCl_2$, NaOH, citric acid+ $HNO_3$ and oxalic acid were performed. NaOH, citric acid + $HNO_3$ and oxalic acid solutions can be reused after passing through the ion exchange column. Among the tested solutions, both of citric acid+ $HNO_3$ and oxalic acid were effective for the decontamination of TRIGA research reactor soil. The radioactivity of soils can be reduced to a release level by the successive application.

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Chloronicotinyl계 살충제 Acetamiprid의 토양 환경중 동태 (Behaviors of Chloronicotinyl Insecticide Acetamiprid in Soil)

  • 홍민기;박종우;김장억
    • 한국환경농학회지
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    • 제20권3호
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    • pp.162-168
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    • 2001
  • Chloronicotinyl계 살충제인 acetamiprid의 토양중 분해, 흡${\cdot}$탈착양상 및 용탈정도를 토양의 유기물함량과 관련시켜 규명하였다. Acetamiprid의 토양 중 잔류양상은 포장실험에서 권장량 (0.08 kg a.i./10 a) 처리구의 경우 분해반감기가 1.7일, 배량처리구 (0.16 kg a.i./10 a)에서는 3.1일로 나타났으며 실험실 조건에서는 15.5 일이었다. Acetamiprid의 토양중 흡착량은 유기물함량이 높은 토양에서 높았으며 특히 humic acid보다는 fulvic acid를 처리한 토양에서 더 높았다. 탈착실험에서 토양내 유기물을 첨가한 실험구의 총 탈착률이 $48{\sim}61%$로 나타나 유기물 제거토양의 총 탈착률 81%보다 매우 낮게 나타났다. 특히 fulvic acid 첨가구의 총 탈착률은 44%로 나타나 humic acid 첨가구의 총 탈착률 62%보다 낮게 나타났다. 포장실험에서 얻은 분해반감기 실험결과와 흡착실험에서 얻은 결과를 GUS (Groundwater Ubiquity Score)에 대입한 결과 acetamiprid는 토양환경 중에서 non-leacher로 분류될 수 있었으며, 이러한 이론적 결과는 실제 토양 중 acetamiprid 용탈 실험의 결과와 일치하였다. Acetamiprid의 용탈실험 결과 soil column의 표층으로부터 15 cm까지 잔류량의 82%가 존재하였으며 그 이하 30 cm 까지에서도 아주 미량이 검출되었으나 30 cm 이상과 용출수에서는 검출되지 않았다.

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폐자원(폐석회, 굴패각, 바닥재)을 이용한 토양 중화제 개발 연구 (A Study on the Development of Soil Neutrailizing-agent using Waste Materials (Waste-lime, Oyster, Bottom-ash))

  • 오승진;조미현;박찬오;정문호;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제17권6호
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    • pp.92-101
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    • 2012
  • Korea shows the soil pH is 5.8 ~ 6.2 by many factors including the geological structure and climate condition. There is known as the cause for soil acidification by weathering of the mineral, excessive use of the chemical fertilizer, and extensively diffused acid rain. The purpose of research is environmentally-friendly material neutralization technology development utilizing the waste resources against by acid soil. The experiment analyze the physico-chemical property of the acid soil and waste resource materials (waste lime, oyster shell, bottom ash). The Batch-Test was performed under 3 stage. As a result, the acid soil showed up acid soil about 3.19. And waste lime, oyster, bottom ash showed the alkalinity with 9.62, 10.08, 9.17. In case of 1 batch-test experimental result, waste lime and oyster shell, the alkalinity was shown over 7.5 and the good efficiency was showed, on the other hands, the bottom ash showed the pH 4 the neutralization efficiency which is low. waste resource materials to be applied to 2 steps was chosen as the waste lime except the bottom ash and oyster. In 2 step batch-test experiment, it was exposed to be the most appropriate in case of doing the combination ratio of the waste lime and oyster shell with 9 : 1. It was exposed to be efficient most in the effeciency and aspect of economical efficiency combination ratio of the soil and materials was 9.6 : 0.6 with 3 step batch-test experimental result.

하수슬러지와 굴껍질의 혼합첨가에 의한 산성토양 교정효과 (A Study on Acid soil amendment by Addition of Sewage Treatment Sludge mixed Oyster Shell)

  • 문종익;최성문;성낙창;허목;김부길;김철
    • 유기물자원화
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    • 제9권2호
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    • pp.66-70
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    • 2001
  • 본 연구에서 밭토양은 부산시의 평균 pH인 인공 산성우(pH=5.34) 조건에서 실험되어졌다. 그리고 산성토양 중 화능을 확인하기 위해 토양산도, CEC(양이온 치환능력)와 K, Ca, Na와 같은 알칼리 금속에 대해 분석하였다. 굴껍질은 치환성 양이온을 다량 함유하고 있기 때문에 산성 토양 개선제로의 역할을 할 수 있을 것이고 하수슬러지의 토양 첨가는 슬러지 처분의 대체 방안으로 기대된다. 본 연구의 목적은 하수슬러지 및 굴껍질의 적정처리방법으로 산성토양에 주입시 그 개선효과를 검토하고자 하였다. 토양과 하수슬러지의 비율을 각각 10:0, 9:1, 8:2, 7:3으로 한 것과 토양 : 하수슬러지와 굴껍질 혼합물의 비율을 각각 9:1, 8:2, 7:3으로 한것을 대상토양에 첨가하였다. 실험 결과, 토양산도는 약간 감소하였고 CEC는 약간 증가하는 경향을 나타내었다. 알칼리 금속의 경우는 실험기간동안 지속적으로 감소되어져 토양산도, CEC와는 다른 농도경향을 나타내었다. 결과적으로 굴껍질이 혼합된 하수슬러지는 산성토양 개선제로서 역할을 할 수 있음을 확인하였다.

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LAND FARMING OF WATER PLANT ALUM SLUDGE ON ACID MINERAL SOIL AFFECTED BY ACID WATER

  • Lee, Seung-Sin;Kim, Jae-Gon;Moon, Hi-Soo;Kang, Il-Mo
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.182-186
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    • 2001
  • An acid forest surface soil as a land farming medium was treated with a water plant alum sludge at 0 to 18%. Indian mustard was grown in the treated soil in a greenhouse for 5 weeks and watered with pH 4 tap water adjusted with a mixed acid (1HNO$_3$: 2H$_2$SO$_4$) during plant growth. Changes in soil property, leachate chemistry, plant growth, and plant uptake of elements by the sludge treatment were determined. The alum sludge treatment increased buffer capacity to acidity, hydraulic conductivity, water holding capacity, and phosphate adsorption of the soil and decreased bulk density and mobility of small particles. The sludge treatment reduced leaching of Al, Mg, K, Na, and root elongation. Plant did uptake less amount of the cations and P but more Ca with the sludge treatment.

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Responses of Low-Quality Soil Microbial Community Structure and Activities to Application of a Mixed Material of Humic Acid, Biochar, and Super Absorbent Polymer

  • Li, Fangze;Men, Shuhui;Zhang, Shiwei;Huang, Juan;Puyang, Xuehua;Wu, Zhenqing;Huang, Zhanbin
    • Journal of Microbiology and Biotechnology
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    • 제30권9호
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    • pp.1310-1320
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    • 2020
  • Low-quality soil for land reuse is a crucial problem in vegetation quality and especially to waste disposal sites in mining areas. It is necessary to find suitable materials to improve the soil quality and especially to increase soil microbial diversity and activity. In this study, pot experiments were conducted to investigate the effect of a mixed material of humic acid, super absorbent polymer and biochar on low-quality soil indexes and the microbial community response. The indexes included soil physicochemical properties and the corresponding plant growth. The results showed that the mixed material could improve chemical properties and physical structure of soil by increasing the bulk density, porosity, macro aggregate, and promote the mineralization of nutrient elements in soil. The best performance was achieved by adding 3 g·kg-1 super absorbent polymer, 3 g·kg-1 humic acid, and 10 g·kg-1 biochar to soil with plant total nitrogen, dry weight and height increased by 85.18%, 266.41% and 74.06%, respectively. Physicochemical properties caused changes in soil microbial diversity. Acidobacteria, Bacteroidetes, Chloroflexi, Cyanobacteria, Firmicutes, Nitrospirae, Planctomycetes, and Proteobacteria were significantly positively correlated with most of the physical, chemical and plant indicators. Actinobacteria and Armatimonadetes were significantly negatively correlated with most measurement factors. Therefore, this study can contribute to improving the understanding of low-quality soil and how it affects soil microbial functions and sustainability.

오염중의 유리지방산이 세척성에 미치는 영향 제2보 고형오염의 세척성 (Studies on the Detergency Characteristics of Free Fatty Acid in Oily Soil (Part II. Detergency of Particulate Soil))

  • 김은옥;김성련
    • 한국의류학회지
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    • 제4권1_2호
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    • pp.43-48
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    • 1980
  • The effect of free fatty acid in fatty soil on the detergency of particulate soil was investigated. Cotton lawn fabric was soiled with the mixture of polmitic acid, hydrogenated fat, paraffin oil and iron oxide black altering the contents of palmitic acid and was laundered with different sur-fastants under various temperature and alkalinity. The rate of soil removal was estimated by means of the spectoometic analysis of iron on the fabric before and after washing. The results of dergency were compared those obtained by reflactance and K/S value from Kubelka-Munk equation which were derived from reflactance measurements.

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