• 한국염색가공학회지
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• 제11권2호
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• pp.38-45
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• 1999

Natural red colorants were extracted from Phytolacca americana Linne by using 50% ethanol solution at room temperature for 12 hours. The colorant components were partially purified as yellow and deep red colorants by thin layer chromatography. Natural red colorants were consisted of major water-soluble red colorant, having maximum absorbance at 538nm and alcohol-soluble yellow colorant, having maximum absorbance at 664nm. Concentration of red colorants were calibrated by the equation of dye(mg/ml) $A_{538nm}\times{1.284}$. Red colorants were changed to yellow at extreme alkali pH and repaired 55% color intensity by neutralization of pH and stabled below $55^\circ{C}$. Dyeability of red colorants against wool fabrics was mainly operated by red pigment having 538nm absorbance without big color differences. Below $55^\circ{C}$, color differences $(\Delta{E}^*_{ab})$ were not changed in spite of big difference of chroma$(c^*)$, having higher scores at higher temperature. The effect of mordants were not drastically changed parameters of color difference without copper ion. Citric acid was big changes of color difference$(\Delta{E}^*_{ab})$ in spite of similar chroma$(c^*)$ values. From these experimental results, red colorants from Phytolacca americana Linne is available for wool fabric dyeing.

• 한국염색가공학회지
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• 제27권3호
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• pp.194-201
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• 2015

Cotton and silk fabrics were dyed with Houttuynia cordata extract using aqueous ethanol solution and the dyeing and post-treatment conditions were optimized to impart antimicrobial activity to the fabrics. The dried Houttuynia cordata can be extracted at $80^{\circ}C$ for 3 hours using an aqueous ethanol solution containing 70%(w/w) ethanol. For the highest color yields. Both cotton and silk fabrics can be dyed at $100^{\circ}C$ for 60min with 10g/L of NaCl under pH 4. Silk fabrics can be dyed to higher K/S than cotton fabrics. The color fastness properties of the dyed fabrics were good when either citric acid crosslinking or aluminum alum mordanting was carried out as a post treatment. The dyed silk and cotton fabrics with the post treatments showed excellent antimicrobial activity against both Staphylococcus aureus and Klebsiella pneumoniae.

• 한국잠사곤충학회지
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• 제41권2호
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• pp.116-121
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• 1999

This study was aimed to explain the essence of Hydroxylammonium hydrochloride(H.A.) effect on degummed silk fiber increasing the colour sites due to oxime generating reaction. H.A. in aqueous solution caues to increase the amount of [H+] and reduce pH values as the concentration of H.A. increases. The rate of [H+] absorption of silk fiker in acidic solution differs on the basic of solution pH and shows a specific uptake in each pH, the lower the pH of solution, the higher the amount [H+] absorption. The pH of solution after treating of silk fiber in H.A. and HCl, showed more remaining [H+] in H.A. solution due to [H+] releasing under the procedure of oxime production. Also it was revealed that in higher concentration of H.A. the reaction for oxime fixation in silk fiber carried out stonger and as a result the bigger gap with acid uptake curve appeared. FT-IR analysis of silk fiber treated with H.A. revealed the creating of intermolecular H-bond at the 2,981-2.930 cm-1, which was not appeared for nontraeted silk fibers and shows H-bond between N-OH group in oue chain and C=) group in another chain of silk protein. Colourimetry of dyed silk fiber after H.A. tratment showed that the silk fiber treated with the high concentration of H.A. compare to low concentration, absorbed more dyeing molecules and so Showed less percontage of Whiteness.

• 패션비즈니스
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• 제22권1호
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• pp.124-134
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• 2018

This study examined the dyeing characteristics and spectrum of cotton and silk by using dyeing solution extracted from aronia. The value $L^{\ast}$ which indicates the brightness of cotton regardless of mordant increases with increasing pH from pH 3.5 to pH 10.5. The color difference value(${\Delta}E$) of the cotton was generally high in pH 3.5 regardless of mordant existence. The silk showed the highest ${\Delta}E$ value in pH 3.5 dye solution as cotton did. On the other hand, the silk with mordant dyed showed the highest ${\Delta}E$ value in pH 7. Silk fabrics dyed with Aronia solution turns out red in pH 3.5, blue in pH 7 and yellow in pH 10.5. This is because of the amino acid, one of the silk ingredients, combines with a part of anthocyanin to show blue. As the result of the spectrum measurement, the maximum absorption wavelength of Aronia solution was increased in the order of pH 10.5, pH 3.5 and pH 7, regardless of extraction temperature and mordant. The measurement results of color fastness to washing and color fastness to light are generally low. Therefore, there is a need for further study to improve color fatness in the future.

• 한국의류학회지
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• 제37권8호
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• pp.1130-1138
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• 2013

We examined dyeing properties using cotton, Tencel, general nylon 66 and hollow nylon 66 treated with aqueous and ethanol extracts without mordant. The antimicrobial properties of fabrics treated with Artemisia extracts against gram positive Staphylococcus aureus (S. aureus) and gram negative Klebsiella pneumonia (K. pneumonia) were also examined. The dying solution concentrations were determined from a calibration curve of the concentration and absorbance of Artemisia extracts. FTIR spectra confirmed that antimicrobial components and colorants (such as 1,8-cineol, thujone, caffeoylquinic acid and chlorophyll) were more present in ethanol extract than in aqueous extract. Nylons had higher $a^*$ and $b^*$, and lower $L^*$ values than cellulose fabrics dyed with aqueous solutions of Artemisia extracts; however, the dyed nylon fabrics were brown. Fabrics dyed with ethanol-extract added solutions were greener and had higher antimicrobial properties than those dyed with aqueous solutions; however, they faded and lost their antimicrobial properties after laundering. Fabrics regained their antimicrobial properties (especially against S. aureus) by the spraying of Artemisia ethanol extract; therefore, the application of Artemisia ethanol extract onto underwear is expected to relieve atopic dermatitis.

• 한국염색가공학회지
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• 제12권6호
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• pp.389-395
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• 2000

A natural colorants was extracted from cherry by 10wt% aqueous acetic acid solution as an extractant. Silk and cotton fabrics were dyed with the cherry extract in the temperature range of $40-80^\circ{C}$ and for the time range of 30-60min. by pre- and post-mordanting with various mordants, their dyeability and fastness were investigated. The natural cherry extract prepared in this study has a maximum absorbance at 520nm. It was found that the optimum dyeing temperature and time were $40^\circ{C}$ and 50min, respectively. The pre-mordanting method was more effective than post-mordanting. All mordants except $SnCl_2\cdot{2H}_2O\;and\;FeSO_4\cdot{7H}_2O$ were effective for silk fabrics. However, the dyeability on cotton fabrics increased in the order of $CrK(SO_4)_2\cdot{12H_2O>(CH_3COO)_2Cu\cdot{H}_2O>CuSO_4\cdot{5H}_2O>AlK(SO_4)_2\cdot{12H}_2O>FeSO_4\cdot{7H}_2O>SnCl_2\cdot{2H}_2O$ among the mordants used in this study Fastness(light, water, washing, perpspiration fastness) on the silk and cotton fabrics increased with using mordants. The post-mordanting using mordant$(CH_3COO)_2Cu\cdot{H}_2O$ among the various mordants in this study gave the best fastness.

• 한국염색가공학회지
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• 제32권1호
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• pp.44-50
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• 2020

In this study, pre-treatment was performed on kapok, a hydrophobic fiber, to compare dyeability by hydrophilization. The pretreatment conditions of kapok fiber were used with different amounts of sodium oleate(NaO), a fatty acid-based anionic surfactant, and xanthan gum(XG) as a natural thickener. At this time, NaO and XG were separately or mixed treated with 0.01%, 0.1%, 1% aqueous solution at 80℃ for 30 min. Hydrophilicity through dyeing was confirmed using Sappan wood extract. Therefore, SEM observation was performed to investigate the surface change of kapok fiber according to the conditions. The surface color difference was also analyzed. Pretreated kapok fibers were made from nonwoven fabrics and the contact angles were measured to determine their hydrophilization. The surface of the fiber after pretreatment was found to be cracked when NaO and NaO were mixed with XG. The surface color was the highest in a^⁎ and K/S values after the simultaneous treatment of NaO and XG, followed by NaO pretreatment and XG pretreatment. The contact angle of kapok fiber made of nonwoven fabric was slightly lower at 300g/㎡ than the fabric weight of 150g/㎡. Such hydrophilized nonwoven kapok fiber are expected to be used in various fields.

• 한국지역사회생활과학회지
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• 제21권1호
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• pp.71-79
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• 2010

This study was conducted to develop fresh-cut and processed pears. After treatment of citric acid (1%) or N-acetylcysteine (0.2 M), and co-treatment of citric acid (1%) and N-acetylcysteine (0.2 M) into the pears c.v. 'Wonhwang', the quality changes of pears during cold storage ($1^{\circ}C$) for 10 days were investigated respectively. Pear quality and the taste of pears increased much more in those treated with anti-browning agents than those in the control group at 10 days after anti-browning treatment and cold storage. Changes in Hunter b values of pears treated with 0.2 M N-acetylcysteine were insignificant. Those with Polyphenol oxidase (PPO) activity and ethylene production were had the most decreased effects and those with the phenolics compound contents were the most lowered. Firmness of fruits increased in treatment of 0.2 M N-acetylcysteine + 1% citric acid solution. The amount of respiration decreased in the application of 1% citric acid solution. Consequently, fruit freshness can be maintained more effectively by the treatment of the anti-browning agent compared to non-treatment, even if the effectiveness were different among different kinds of anti-browning agents.

• 한국의류산업학회지
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• 제7권5호
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• pp.547-552
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• 2005

The study has objective in raising value of the gray color as a meaningful color suiting sentiments of modern people by expressing the gray color in various perspective utilizing natural dyes that is natural at the same time having aesthetic color tones. For example, the main ingredient used for coloring black and gray color is the pyrogallol tannin and the gray tone dye can be acquired by combining the tannin with iron. In order to find the suitable condition for processing tannin, UV-Vis part absorption spectrum of Gallapple pyrogallol tannin, dye ability based on temperature and time, reflection rate based on concentration, color changes based on acid treatment and alkali treatment, changes on surface based on concentration or metal mordant condition, and lightfastness were measured. Maximum absorption wavelength (${\lambda}_{max}$) of Gallapple tannin was at around 273 nm, while strong absorption was also observed at below 350 nm. Dye ability of Gallapple tannin is done more easily on silk rather than cellulose fibers such as cotton, while the optimum condition for dyeing was observed to be at $60^{\circ}C$, for 20 minutes. As a result of acid treatment, the color of dye material consist highly of gray tones and showed red tone after the alkali treatment. While it was observed that as dye concentration and metal mordant concentration increased the color changed at counter-clockwise direction on the Y-scale of Munsell's scale of colors. Lightfastness was more on a normal fading. I hope this study opens up possibilities towards presenting gray color expressed from tannin as color with diversity and aesthetic value. In future, comparative study between dye expressed from catechol tannin dye materials will be helpful.

• 한국염색가공학회지
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• 제34권3호
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• pp.135-145
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• 2022

In this study, the dyeability of 0.06-denier-per-filament (dpf) ultrafine sea-island-type nylon knitted fabric was investigated and compared with that of 1.0-dpf general nylon with respect to four types of dyes. In particular, leveling, milling, half-milling, and metal-complex dyes were compared at concentrations of 0.5%, 1.0%, 2.0%, 4.0%, and 8.0% on-weight-fabric (o.w.f). In each case, staining was performed at 100 ℃. The dyeabilities of the materials were compared in terms of the depth of color as defined by the ratio of the absorption coefficient (K) to the scattering coefficient (S). Results indicated generally low K/S values for both the 0.06-dpf ultrafine sea-island-type nylon and 1.0-dpf general nylon. In terms of the dye type, the milling and half-milling dyes exhibited K/S values of ≥20 for all colors of yellow, red, and blue for the 0.06-dpf ultrafine yarn sea-island-type nylon, which were superior to those of the other dye types. Hence, the milling and half-milling dyes are considered more suitable than the other dyes. Further, a comparison of dye fastness and compatibility revealed that the half-milling dye was the most suitable dye for the 0.06-dpf ultrafine sea-island-type nylon.