• Title/Summary/Keyword: Acid and base

Search Result 1,241, Processing Time 0.024 seconds

Polyethyleneimine Derivative for Nucleic Acid Model

  • Lee, Chan-Woo;Chae, Hee-Jeong;Kwon, Young-Jin
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • v.10 no.3
    • /
    • pp.205-211
    • /
    • 2005
  • Water-soluble polyethyleneimine (PE) derivatives containing nucleic acid bases and hydrophilic amino acids such as homoserine (Hse) and serine were prepared by the activated ester method as nucleic acid models. From spectroscopic measurements, the polymers were found to interact with DNA accompanied by an induction of conformational change. Hypochromicity in UV spectra indicated that a stable polymer complex was formed between poly (A) with PEI­Hse-Ura by complementary hydrogen bonding with equimolar nucleic base units (adenine:uracil=1:1). The induced conformation of DNA by the interaction with the polymer containing uracil and homoserine (PEI-Hse-Ura) was concluded to be a super triple helical structure. The formation of the polymer complex, DNA: PEI-Hse-Ura, was found to be affected by the presence of metal ions such as $Ca^{2+}\;and\;Cu^{2+}$.

Development of Computer Program for Menu Based on Nutrients and Food Preference (영양소와 식품기호도를 고려한 식단 작성 Computer Program의 개발)

  • 김은미
    • Journal of Nutrition and Health
    • /
    • v.30 no.5
    • /
    • pp.529-539
    • /
    • 1997
  • The present study was to formulate a computer program to provide a menu based on a food preference survey of families in urban areas. A food preference survey was conducted by individual direct interviews of infants, children and old people in this study. In case other's food preferences were available, food menus considering all age groups could be made. Database III PLUS package was utilized for this study. The dBASE was loaded with a food compostion table of 339 different food items, along with data for amino acids and fatty acids for 171 and 43 food items respectively. Food preference, unit of food, and recommended dietary allowances were also incloded. This meun program system calculates nutrients in selected foods, and menu assessment was composed of several factors inculding energy ratio of carbohydrate : protein : fat, amino acid score, limiting amino acid, polyunsaturated fatty acid/saturated fatty acid(JP/S) ratio and Ca/P ratio.

  • PDF

The Effect on the Strength According to Carbon Content of Kovar Steel (코바강의 탄소첨가량에 따른 강도에 미치는 영향)

  • Choi, Byung-Hui;Choi, Byung-Ky
    • Journal of the Korean Society of Safety
    • /
    • v.25 no.3
    • /
    • pp.28-33
    • /
    • 2010
  • Ni alloy steel is able to use during long time because of good acid and corrosion resistance. So, it's research has focused on developing the alternative alloy which is economically feasible. Recently, consumption of Kovar steel is gradually increased in field of the jet engine and the gas turbine because of its low thermal expansive characteristics. The specimens of Kovar steel(29%Ni-17%Co) contain 0.00%C, 0.03%C, 0.06%C, 0.10%C and 0.20%C, respectively. Ingots are manufactured by VIM(vacuum induction melting furnace) and then specimens are made by automatic hot rolling after heat treatment. Strength of Kovar steel according to carbon contents is estimated by hardness, tensile and impact test. Hardness of the 0.20%C specimen is more improved approximately 14.4% than one of base metal. Its strength increases 32.4% of a base metal, and its impact energy is also enhance 11.5%.

Studies on the Coated Broke Recycling in the Papermaking(II)-Effect of Sulfuric acid Treatment on Coated Broke Recycling - (도공파지의 재생에 관한 연구(제 2보)-황산처리가 도공파지 재생공정에 미치는 영향)

  • 이용규;김창근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.31 no.4
    • /
    • pp.23-29
    • /
    • 1999
  • The effect of dilute sulfuric acid treatment was examined to improve recyclability of coated brokes. Turbidity , electric conductivity , and cationic demand of the white water from coated broke prepared from an alkaline base paper was determined. Sulfuric acid treatment was found to be effective in dissolving undisintegrated substances such as binders, pigments, and fibers. The properties of papers prepared by adding the broke to pulp stock up to 30% dry weight were examined . With the increase of broke addition, retention, sizing degree and smoothness were improved ; on the other hand, formation uniformness, air permeability and internal bonding strength were decreased. The extent of improvement by broke addition was greater for the surfuric acid-treated broke than the control broke. It was concluded that the use of coated broke should be limited within 10-15% weight of the product for either type of broke.

  • PDF

Identification of a Regulatory Region within the luxR Structural Gene in a Marine Symbiotic Bacterium, Vibrio fischeri

  • Choi, Sang-Ho
    • Journal of Microbiology and Biotechnology
    • /
    • v.4 no.3
    • /
    • pp.176-182
    • /
    • 1994
  • The light-organ symbiont of pine cone fish, Vibrio fischeri, senses its presence in the host and responds to environmental changes by differentially expressing its symbiosis-related luminescence genes. The V. fischeri luminescence genes are activated by LuxR protein in the presence of an autoinducer. In an effort to elucidate the mechanism of regulation of luxR, a plasmid containing luxR was mutagenized in vitro with hydroxylamine and a luxR mutant plasmid was isolated by its ability to activate luminescence genes cloned in E. coli in the absence of the autoinducer. The specific base change identified by DNA sequencing was only single base transition at +78 from the transcriptional start of luxR. Based on a Western immunoblot analysis, the nucleotide change directed the synthesis of much higher level of LuxR protein without any amino acid substitutions. The results suggest that the region including the +78th base is presumably internal operator required for autorepression of luxR, and the increased cellular level of LuxR results in activation of luminescence genes by autoinducer independent fashion.

  • PDF

Histopathological effect of experimental feeding of melamine and cyanuric acid in kidney of crucian carp (Carassius carassius) (Melamine과 cyanuric acid의 혼합투여가 붕어(Carassius carassius)의 신장에 미치는 조직병리학적 영향)

  • Wang, Seong-Jin;Heo, Gang-Joon
    • Korean Journal of Veterinary Research
    • /
    • v.50 no.4
    • /
    • pp.259-264
    • /
    • 2010
  • Melamine is an organic base and a trimer of cyanamide which contains 66% nitrogen by mass, but it was sometimes illegally added to food products in order to enhance the apparent protein content for the bigger profit. Many Chinese infants and pet animals fed melamine-containing formulas suffered acute kidney failure with renal crystal formation. Fish feeds were also recently found to be contaminated with melamine. This experiment has been designed to determine whether renal crystals can be experimentally induced in crucian carp (Carassius carassius) fed melamine and cyanuric acid (each at 400 mg/kg/day for 3 days) in combination, and to compare experimentally induced crystals with those from pet animals with triazine related renal failure. The results showed that all fish developed gold brown renal crystals arranged in radial spherulites in the renal tubules, similar to those detected in the pet animals.

Electrical Properties of Coatings of Polyaniline (Polyaniline을 이용한 코팅막의 전기적 특성)

  • 김언령;김종은;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.310-313
    • /
    • 2000
  • Polyaniline Emeraldine Base (PANI EB) polymerized by chemical oxidative polymerization was doped with Camphorsulfonic Acid(CSA). Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) solutions were solved in organic solvents and sonificated at the room temperature for different solvents in PANI-CSA ES solution and sonification time. PANI-CSA ES solutions was coated on PET films using bar coater. 1-Step oxidatively-polymerized Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was solved in m-cresol:chloroform 1:1 co-solvents and their solution was bar-coated on PET film. The surface resistivities of these coated films were measured, The surface resistivity of PANI-CSA ES solution in m-cresol:chloroform 1:1 co-solvent system was 5${\times}$10$^2$$\Omega$/$\square$.

  • PDF

Basic Physiological Activities of Bifidobacterium infantis Maeil-K9 and Lactobacillus plantarum KCTC3099 Selected by Anticarcinogenic Activities. (항암 활성능이 우수한 Bifidobacterium infantis Mneil-K9과 Lactobacillus plantarum KCTC3099의 기초 생리활성)

  • 김응률;정병문;김지연;김서영;정후길;이형주;전호남
    • Microbiology and Biotechnology Letters
    • /
    • v.31 no.4
    • /
    • pp.348-354
    • /
    • 2003
  • This study was conducted to confirm the availability of lactic acid bacteria as probiotics haying inhibitory effects to cancer cell line. Five lactic acid bacteria showing anti-cancer activity were compared by acid tolerance, bile tolerance, antibiotics resistance, milk fermentation, stability, and cell adherence activity to colon epithelial cell. The results obtained are as follows : In acid tolerance, all strains did not have a resistance below pH 3.0 and 3.5 except Lactobacillus plantarum KCTC3099. In antibiotics resistance, Lactococcus lactis and L. plantarum KCTC3099 were resistant to cotrimoxazol (128 mg/1), and Bifidobacterium adolescentis Maeil-K8 and B. infantis Maeil-K9 were resistant to doxycylin and gentamycin (4 mg/1). In case of cell adherence ability to Caco-2 cell, B. infantis Maeil-K9 was found to be superior to others as 3.1%, while the others were less than 0.5%. When the strains were cultured to milk base, viable counts of the strains tested increased more 1 log cycle than inoculation, but acid production was very low except L. plantarum KCTC3099. Also, L. plantarum KCTC3099, B. adolescentis Maeil-K8, and B. infantis Maeil-K9 were stable in fermented milk base during storage. In conclusion, L. plantarum KCTC3099 and B. infantis Maeil-K9 were confirmed to be superior for the availability as probiotics.

Synthesis and Lubricant Properties of Estolides based on Fatty Acid (지방산 기반 에스토라이드 합성 및 윤활특성)

  • Son, Jeong-Mae;Yoo, Seunghyun;Lee, Sangjun;Shin, Jihoon;Chung, Kunwo;Yang, Youngdo;Kim, Young-Wun
    • Tribology and Lubricants
    • /
    • v.30 no.5
    • /
    • pp.256-264
    • /
    • 2014
  • Enhancing the value of fine chemicals based on biomass resources is an important objective for addressing environmental and other concerns such as demand for renewable or green products, as well as from the political perspective to reduce dependence on fossil feedstock associated with the use of petroleum-based products. Based on these considerations, we studied the synthesis of estolide using waste plant-based oil materials and their application as lubricants and pour point depressants. Five estolides were prepared by varying molar ratio of palmitic acid (PA) to oleic acid (OA) using a reaction time of 48 h. The estolides were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR). The isolated yields were in the range of 57-78 % and purity was 93-97%, showing iodine values of 18.2-37.8, total acid numbers (TANs) of 75.6-94.2 mg KOH/g and estolide numbers (ENs) of 1.2-1.8. Increasing the ratio of OA to PA in the synthesis decreased the kinematic viscosity and clouding point of the estolides. Four ball wear test of the estolides as a base oil demonstrated that the wear scar diameter (WSD) of the estolides was significantly lower (0.320-0.495 mm) than the WSD of general base oils such as 150N and Yubase (0.735 and 0.810 mm, respectively), indicating better wear resistance of the estolides. However, the lubricant property was found to be independent of the amount of OA in the estolides. These new materials are prospective candidates for application as a lubricant base oil.

Poly[(1-methacryloyloxy-4-tosyloxycyclohexane)-co-(tert-butyl methacrylate)] as an acid amplifying photoresist (산 증식형 포토레지스트로 Poly($MTC_{10}-co-tBMA_{90}$)의 합성 및 특성 연구)

  • Kuen, Kyoung-A;Lee, Eun-Ju;Lim, Kwon-Taek;Jeong, Yong-Seok;Jeong, Yeon-Tae
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.20 no.2
    • /
    • pp.131-140
    • /
    • 2002
  • Chemically amplified deep UV(CA-DUV) resists are typically based on a combination of an acid labile polymer and a photoacid generator(PAG) but acid amplification type photoresist is formulated by addition of the acid amplifiers to chemically amplified resist system(CAPs). We developed acid amplifiers base on cyclohexanediol such as 1-methacryloyloxy-4-tosyloxy cyclohexane(MTC) and poly(MTC$_{10}$-co-tBMA$_{90}$)(P-1) to enhance photosensitivity. P-1 is a copolymer of tert-butyl methacrylate and MTC as a positive working photoresist based on polymeric acid amplifier in order to enhance photosensitivity and simplify the process of fomulating a photoresist. P-1 exhibited 2X higher photosensitivity compared with PtBMA. The acid amplifiers showed reasonable thermal stability for resist processing temperature and higher photosensitivity compared with chemically amplified resist.

  • PDF