• Title/Summary/Keyword: Acid and Alkali

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Dye Penetration into Xylem of Pinus koraiensis and Larix leptolepis by Transpiration Method (증산법에 의한 잣나무와 일본잎갈나무의 목부내 염료침투)

  • 전수경
    • Journal of the Korea Furniture Society
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    • v.12 no.1
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    • pp.1-9
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    • 2001
  • This study was carried out to elucidate the relationship between wood anatomy and the water flow path in P. koraiensis and L. leptolepis. through the experiment of penetration of the dye solution. The experiment was performed by permeating 1% acid, alkali and direct solution into the xylem just after being cut. The results obtained were summarized as follows : 1. In P. koraiensis and L. leptolepis, the dye solution penetrated into sapwood and annual rings adjacent to cambial zone were only dyed according to ascent of tree height. 2. The penetrability of latewood was better than that of earlywood. 3. In P. koraiensis and L. leptolepis, the main water flow path in longitudinal direction was the trachied and that in transverse direction was ray trachied and ray parenchyma. Also, the dye solution was found in resin canal. 4. P. koraiensis was more permeable than L. leptolepis. 5. Among the acid, alkali and direct dye solution, the acid dye solution was the most permeable.

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Alkali Treatment Effect of Kenaf Fibers on the Characteristics of Kenaf/PLA Biocomposites (Kenaf 섬유의 알칼리처리가 Kenaf/PLA 바이오복합재료의 특성에 미치는 영향)

  • Seo, Jeong Min;Cho, Donghwan;Park, Won Ho
    • Journal of Adhesion and Interface
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    • v.9 no.4
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    • pp.1-11
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    • 2008
  • In the present study, kenaf fibers were treated with sodium hydroxide using soaking and ultrasonic methods prior to biocomposite processing, respectively. The effect of alkali treatment on the kenaf-PLA interfacial adhesion and mechanical and thermal characteristics of kenaf/poly(lactic acid) biocomposites was investigated in terms of their interfacial shear strength, flexural properties, dynamic mechanical properties and thermal stability and also microscopic observations of kenaf fibers and the composite fracture surfaces. As a result, use of both soaking and ultrasonic methods for treating kenaf fiber surfaces played a role in increasing the fiber-matrix adhesion and the mechanical properties of the biocomposites. Their characteristics depended not only on the fiber surface treatment method but also on the treatment condition like alkali concentration and treatment time.

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Recovery of high quality external carbon sources using crystallization from pretreated excess activated sludge by alkali and ozone (알칼리-오존 동시 전처리된 잉여슬러지로부터 결정화를 이용한 고품질 외부탄 소원 회수)

  • Seo, In S.;Kim, Hong S.;Kim, Byung G.;Kim, Youn K.
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.6
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    • pp.641-646
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    • 2008
  • In this research, recovery of high quality organics from excess activated sludge and its potential as a external carbon sources for BNR process was studied. By simultaneous treatment of alkali and ozone, TSS concentration was reduced by 32%, and RBDCOD fraction was increased by 76.2%, and major constitute of produced organic were acetic acid and propionic acid. Also, nitrogen and phosphorus were greatly solubilized. However, because acid-hydrolyzable phosphorus(AHP) was major part of solubilized phosphorus, $NH_4{^+}-N$ and $PO_4{^3}-P$ concentration were insufficient for effective formation of crystal like as MAP(Magnesium Ammonium Phosphate) and hydroxyapatite. By placing BPR reactor before alkali-ozone treatment reactor, $PO_4{^3}-P$ concentration in pretreated sludge was increased by 1.8 times, and improved potential of phosphorus recovery by crystallization. In experiment of crystallization, hydroxyapatite formation was more easily applied than MAP. By hydroxyapatite formation, $SCOD/PO_4-P$ ratio was greatly increased from 32.7 at control to 141.9 at $Ca^{2+}/PO{_4}^{3-}-P$ mole ratio of 2.4. The results based on this study indicated that the proposed system configuration has potential to reduce the excess sludge production, to recover phosphorus in usable forms as well as utilize organics as a external carbon source in BNR process.

Modification of Tencel Fabric Treated with Chitosan( II ) - Change of Dyeing Properties - (키토산처리에 의한 텐셀 직물의 개질기능화(II) - 염색성의 변화 -)

  • 육은영;배현숙
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.1-10
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    • 2002
  • Tencel fabric cationized with chitosan can be effectively dyed with anionic dyes. To investigate the change of dyeing properties of cationized Tencel fabric, some experiments were performed under the several dyeing conditions with acid and reactive dyes. Whiteness index decreased with the increment of crosslinking agent concentration. The cationized Tencel fabric was dyed well by anionic dye such as acid dye, the dyeability of reactive dye was improved by addition of a little salt without alkali. The dye fixation on the cationized Tencel fabric was increased with chitosan concentration without electrolyte and alkali. The dyeability of Tencel treated with chitosan was better than controlled Tencel, especially under the acidic conditions. According to the number and the types of functional group of reactive dyes, dye affinity of the modified Tencel fabric varied and wash fastness of acid dye was better than reactive dye.

Adsorption and Molecular Sieve Properties on the Natural Zeolite with Chemical Surface treatment (화학적 표면처리에 의한 천연 제올라이트의 흡착 및 분자체 특성)

  • 조승래;심미자;김상욱
    • Journal of the Korean institute of surface engineering
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    • v.25 no.3
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    • pp.144-149
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    • 1992
  • The adsorption and molecular sieve characteristics of water, methanol, ethanol, butanol and benzene on acid-alkali treated natural zeolite from Kampo area were investigated by the Diamond·Kinter method, and it was compared with synthetic zeolite A. Adsorption amount of water increased with the treatment of acid rather than the treatment of alkali. Similar tendency was observedd in adsorption of alcohols such as methanol, ethanol and butanol, but the amount of adsorption decreased. From the views of the molecular size, adsorption amount of benzene decreased because of surface activity according to the cations species rather than chemical treatment. And it was almost same value that the amount of adsorption was compared acid treated natural zeolite with synthetic zeolite A.

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Phenolphthalein Solution Discoloration determined by alkali concentration in long-term concrete check surface (장기재령 콘크리트의 할렬면에서 알칼리농도에 의한 페놀프탈레인 용액의 변색)

  • Park, Hyun;Lee, Jong-Rok;Kim, Kwang-Ki;Kim, Woo-Jae;Kim, Jong-Sub;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.183-186
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    • 2008
  • Carbonation is measured as Phenolphthalein Solution, it is possible to confirm the scope of alkali through acid and basic reaction. Then, Concrete Basic Reaction is decided according to alkali concentration depending on Potassium Hydroxide Now that Carbonation is gradually produced toward inner side from outer side, with time going by, it doesnt work, to some adequate depth, in as fast time as compulsory facilitating test. Thus, this research thesis made a comparative analysis on concrete phenomenal discoloration borderline following Phenolphthalein Solution, as part of a bid to measure Carbonation. Also, the thesis measured Concrete Alkali Concentration. The result showed that concrete coloring is classified into red and scarlet according to alkali concentration, and into borderline breakpoint of the speckle of scarlet and carbonation reaction. The higher chroma becomes with concrete decolorizing, the higher alkali concentration becomes.

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대두발효식품의 cerebroside 조성 및 생리활성

  • Song, Seong-Gwang;Kim, Hui-Suk
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.765-766
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    • 2000
  • Cerebrosides were isolated from soybean, deunjang and chungkukjang and their constituents were investigated. The principal fatty acid of soybean cerebroside was 2-hydroxy-palmitic acid but chungkukjang cerebroside consisted palmitic acid, elaidic acid(trans 18:1), oleic acid and stearic acid. The only sugar in cerebrosides was glucose. TLC analysis of cerebroside hydrolysate elucidated soybean and chungkukjang had same sphingold bases, mainly dihydroxy bases, trans-4, trans-sphingadienine. But, alkali stable glycolipid fractions of chungkukjang and deunjang had $2{\sim}3$ different primary amines.

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Synthesis of CM-Chitin from Crab Shells (게껍질로부터 CM-Chitin의 합성)

  • Ahn, C.I.;Kim, S.H.;Yoo, Y.J.;Park, C.H.;Lim, H.S.;Park, C.K.;Park, E.K.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.41-47
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    • 1993
  • Chitin was isolated from crab shells by modified Hackman's method, which was treated again with aqueous sodium hydroxide solution to give alkali chitin(sodium alkoxide of chitin). And after, the alkali chitin is allowed to react with monochloroacetic acid to synthesize 6-O-(carboxymethyl) chitin [CM-Chitin] under diminished pressure. In order to synthesize high performance CM-Chitin as hygroscopic agent, it was measured that the yield and degree of subsititution of each CM-Chitin according to molar ratio(monochloroacetic acid equivalent mol/N-acetyl-D-glucosamine residue) and their moisture-absorption and moisture-release properties were measured and compared with those of hyaluronic acid. The moisture-absorption and moisture-release properties of CM-Chitin, especially 0.8 in degree of substitution, were found quite similar to those of hyaluronic acid. The preliminary results show that CM-Chitin might be used as hygroscopic agent instead of hyaluronic acid in field of cosmetics.

Nitric-Acid Pulping of Municipal Wastepapers and its Spent-Liquor Utilization for Fertilizers(I) -Study on the Nitric-Acid Pulping Conditions of OCC Pulp- (도시 폐휴지의 질산 펄프제조와 펄프폐액의 입상 비료화 기술개발(I) -폐골판지 상자(OCC)의 질산 펄프제조 조건-)

  • 임기표;위승곤;김창래;양정훈
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.4
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    • pp.74-80
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    • 2000
  • A series of studies on nitric-acid pulping of municipal recycled waste papers were carried out to substitute the bleached chemical pulp imported for producing printing paper as well as to use its solidified spent-liquor as fertilizer. The first experiment was carried out to find the optimum treatment conditions such as pulp consistency, nitric acid charge and temperature in $HNO_3$-alkali pulping process. The results obtained were as follows: 1. Some selective delignification of OCC pulp was conducted by $HNO_3$-alkali process. The higher the temperature and concentration of nitric acid, the lower the pulp yield and kappa number of treated pulp. while its brightness was increased. 2. The higher consistency required the stronger mixing in case of more than 5% pulp. 3. In the laboratory, the suitable $HNO_3$-treating condition seemed to be less than 6% consistency, lower than 500% $HNO_3$charge on pulp and lower than $100^{\circ}C$ in cooking temperature. 4. The spent liquor with 1.77% N-content seemed to be slow-release nitrogen fertilizer suitable for agriculture.

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Inclusion Extraction of Alkali Metals by Emulsion Liquid Membranes and Nano-baskets of p-tert-Calix[4]arene Bearing Di-[N-(X)sulfonyl Carboxamide] and Di-(1-propoxy) in ortho-cone Conformation

  • Mokhtari, Bahram;Pourabdollah, Kobra
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1509-1516
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    • 2012
  • Nano-assisted inclusion separation of alkali metals from basic solutions was reported by inclusion-facilitated emulsion liquid membrane process. The novelty of this study is application of nano-baskets of calixarene in the selective and efficient separation of alkali metals as both the carrier and the surfactant. For this aim, four derivatives of $p-tert-calix$[4]arene bearing different sulfonamide moieties were synthesized and their inclusion-extraction parameters were optimized including the calixarene scaffold $\mathbf{3}$ (4 wt %) as the carrier/demulsifier, the commercial kerosene as diluent in membrane, sulphonic acid (0.2 M) and ammonium carbonate (0.4 M) as the strip and the feed phases, the phase and the treat ratios of 0.8 and 0.3, mixing speed (300 rpm), and initial solute concentration (100 mg/L). The selectivity of membrane over more than ten interfering cations was examined and the results reveled that under the optimized operating condition, the degree of inclusion-extraction of alkali metals was as high as 98-99%.