• Title/Summary/Keyword: Acid and Alkali

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Quality Change in Precooked Sardine during Frozen Storage (자숙 정어리육의 동결저장중의 품질변화)

  • SUH Jae-Soo;LEE Kang-HO;JO Jin-HO
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.16 no.2
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    • pp.117-124
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    • 1983
  • Qualify changes of the precooked frozen sardine (Sardinops melanosticta) during frozen storage were investigated by measuring extractable protein, expressible drip, available lysine and lipid oxidation as peroxide value. Fresh sardine was dressed, washed in chilled water, cooked in boiling water to have $55^{\circ}C\;and\;70^{\circ}$ at the center of the body, frozen at $-40^{\circ}C$, and finally stored at $-20^{\circ}C$ for 84 days. The quality factor mentioned above were determined in both ordinary and dark muscle at 14 day intervals through the period of storage. When cooked at $70^{\circ}C$, the changes in expressible drip were less than that of raw and the one cooked at $55^{\circ}C$. In observation of the extractability of muscle protein, no great change in extractable sarcoplasmic protein was observed, the extractable myofibrillar protein, however, showed a tendency to decrease during the period of frozen storage, accompanying the increase of the alkali-soluble protein. That was more excessive in ordinary muscle than dark muscle. Lipid oxidation of dark muscle was faster than that of ordinary muscle. Acid value was not changed, and peroxide value of the samples cooked at $70^{\circ}C\;and\;55^{\circ}$ was higher than that of raw at the early stage of the storage, after 40-50 day storage, it became lower than that of raw muscle.

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The Study On the dye fastness of the Rayon & Tencel Fiber (Rayon과 Tencel 섬유의 염색 견뢰도 고찰)

  • 안찬희
    • Journal of the Korean Home Economics Association
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    • v.34 no.5
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    • pp.283-292
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    • 1996
  • This study examines the character of "Tencel" named as Ecology Fiber and investigates the fitness of it as the textile and the satisfaction in dress when its fastness is compared with that of Rayon classified into Celulose textile. Dye experiment selected 100% Tencel, Rayon for the samples, which were dyed into the direct dye and Turky Blue and Blue of the rective dye and were washed twelve times by the automatic washer. After that, the dye experiment examines the light, laundering, perspiration, rubbing and the composite fastness of the perspiration and hight in the lists of the dye fastness. The results are as follows: 1. The experiment of the color fastness, especially in T-blue of the direct dyestuff, requiring the twelve times-repeatedly-washing by the detergent says that the color fastness of Tencel is superior to that of the cellulose textile ; Rayon. 2. The experiment of the light fastness says that the fastness of Tencel is superior to that of Rayon. 3. The experiment of the laundering fastness says that all of Tencel, Rayon shows the excellent result in the direct dye than in the reactive dye. 4. The experiment of the rubbing fastness says that although Tencel, Rayon show the remarkable result in the desiccant experiment than in the humid one, the rubbing fastness of Tencel is superior to that of others. 5. The experiment of perspiration fastness says that Tencel, Rayon have the closely tightened tendency not to be altered through the acid and alkali perspirations. 6. The experiment of the composite fastness of perspiration and light indicates that the artifical perspirations, though the light lets the fastness of textiles weeken, do very slightly make them loosen, which does not offer the outstanding result. This whole result show that the fastness of Tencel is superior to that of Rayon. The Korean Fiber Enterprise in clothing should make the new and ecological fiber "Tencel" by means of the large amount of investment, and the technique of handing and controlling about it, considering that the dangerous needle of environmental pollution has been slackening the close-related ecological knots of the global environment. global environment.

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A Study on the Property of Hair Dyed with Fermented Indigo (천연염료 발효(天然染料 醱酵) 쪽으로 염색(染色)한 모발(毛髮)의 특성 연구(特性 硏究))

  • Kim, Kyung-Sun;Lee, In-Sook;Jeon, Dong-Won;Ha, Byung-Jo
    • Journal of Fashion Business
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    • v.10 no.1
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    • pp.120-131
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    • 2006
  • Recently, it has been reported that chemical hair coloring can cause allergic reactions, the toxicity issue of chemical hair color was issued. Therefore, there is an increasing interest in the hair coloration technique using non-toxic and bio-compatible hair color gotten from natural resource. In this study, the possibility using fermented Indigo as natural hair coloring agent was investigated. Bleached hair samples were dyed using Indigo, and the effect of dyeing frequency, the physical change after dyeing, color, surface and cross-section characteristics, and tensile property were also studied. In addition, the protection property of cationic detergent finishing on damaged hair samples were also studied. The following conclusions are made; 1. While bleached hair samples with low value showed the negligible effect of repeated dyeing, bleached hair samples with high value showed the good effect of repeated dyeing. 2. Hair sample dyed with Indigo showed a high light-fastness, however, tensile strength and elongation showed very low values (high damage on hair sample). 3. Cationic detergent finishing did not affect on the colorfastness because of decoloration after dyeing, however, it increased the smoothness of hair sample, and therefore, can use as protectant of damaged hair. 4. Hair scale was damaged after dyeing. It seemed that the alkali, potassium carbonate, increased pH of dyeing bath to 11, as a result, the hair was swollen, weaken, and dissolved on the prolonged dyeing time. Dyed hair sample became stiff and fine. 5. The color difference was 4.62 (a high fastness value) in the test of sunlight exposure, shampoo, cationic detergent finishing, and acid perspiration fastness.

Production and Rheological Properties of the Polysaccharide from Bacillus sp. A29 (Bacillus sp. A29에 의한 다당류의 생산과 물성)

  • Ahn, Sung-Ku;Suh, Hyun-Hyo;Lee, Chang-Ho;Oh, Hee-Mock;Kwon, Gi-Seok;Yi, Dong-Heui;Yoon, Byung-Dae
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.175-181
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    • 1994
  • A bacterial strain producing highly viscous polysaccharide(A29 POL) was isolated from soil and identified sa Bacillus sp. A29. The cultural conditions of the Bacillus sp. A29 for the polysaccharide prouction were dextrin 12%, soytone 0.2%, SnCl$_{2}$ $\cdot $2H$_{2}$O 0.02%, Na$_{2}$HPO$_{4}$ $\CDOT $12H$_{2}$O 0.36%, L-alanine 0.01%, initial pH6.8, and 30$\circ $C at pH 3 FOR 4 days. Final viscosity of the culture broth was 65, 000 cp and then the amount of produced polysaccharide was 8.3 g/l. A29 POL was composed of glucose and xylose. A29 POL showed high viscosity at low concentration(0.1%) and in the presence of the salts such as NaCl or CaCl$_{2}$. A29 POL showed high viscosity acid condition and at alkali condition and high pseudoplasticity in the presence of a NaCl or CaCl$_{2}$. It was shown that the viscosity at high temperature(80$\circ $C) was decreased but it was recovered at low temperature (20$\circ $C. A29 POL was able to from film and gel in the presence of MgSO$_{4}$ $\CDOT $7H$_{2}$O, Na$_{2}$CO$_{3}$ \CDOT $H$_{2}$O, MnSO$_{4}$ $\CDOT $ 7H$_{2}$O. A29 POL had anionic charge.

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A Study on the Preparation of Wood-Plastic Combinations (IV)

  • Kim, Jaerok;Lee, Kyung-Hee;Pyun, Hyung-Chick
    • Nuclear Engineering and Technology
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    • v.5 no.1
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    • pp.3-12
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    • 1973
  • Some physical and chemical properties of wood-plastic combinations(W.P.C.) made of domestic soft woods such as pinus densiflora, pinus rigida and poplus deltoides were measured. The rates of improvement in properties were roughly proportional to the contents of polymer or polymer mixtures in W.P.C. For the W.P.C. obtained by means radiation curing and containing 80% of polymer or polymer mixture, the hardness and water absorptirity were improved 2.2 times and 4 times those of the original wood, respectively. The improvement of hardness was especially remarkable in the W.P.C. made of pinus densiflora and polystyrene(120%) to show 7 times increased hardness. For the W.P.C. obtained by means of thermal curing and containing 80% of polymer or polymer mixture, the hardness and water absorptivity were improved 2.4 times and 3.4 times those of the non-treated woods, respectively. These data indicate that the properties of W.P.C. prepared by means of radiation curing are not much different from those of W. p. C. prepared by means of thermal curing. Both of acid resistancy and alkali resistancy of the W.P.C. were also improved remarkably in comparison with the non-treated wood.

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Improvement of Hardwood Pulp Yield in Continuous Kraft Cooking and Estimation of Pulp Yields Pulp yields of isothermal cooking with polysulfide and anthraquinone

  • Ohi, Hiroshi;Yokoyama, Tomoya
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.295-303
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    • 2006
  • The pulp yield was improved by about 4.5-5% when polysulfide (PS) and anthraquinone (AQ) were added to the kraft cooking liquor (white liquor). The exchange of the black liquor with fresh white liquor further increased the yield. The highest pulp yield was obtained when the PS cooking liquor containing 70% of total active alkali (AA) and 100% of AQ was used from the beginning of the reaction and the black liquor was exchanged with fresh white liquor containing the residual 30% of AA just after temperature reached $135^{\circ}C$. There was a good correlation between kraft pulp yields of a hardwood species and the ratios of the amount of xylose to glucose (X/G ratio), liberated by an acid hydrolysis of the pulps. However, the correlation was dependent on raw material wood species. Therefore, it is required in advance to establish a correlation between the yields and X/G ratios for raw material wood species of a target pulp in order to estimate pulp yield using X/G ratio. The X/G ratios of relatively high yield pulps showed higher values than those expected from the correlation. In a mill trial, the superiority of the PS-AQ isothermal cooking (ITC) process over the kraft ITC process was confirmed by examining X/G ratio of pulps obtained. The pulp yield in the PS-AQ ITC process was estimated at about 57.0%. This yield is very high, which indicates that reaction conditions of the PS-AQ ITC process are optimal.

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Synthesis of Azo Based Disperse Dyes for Dyeing Polyester Fiber in Supercritical Carbon Dioxide (초임계 유체 염색용 아조계 분산염료 합성 및 PET 섬유에 대한 염색 특성 연구)

  • Shin, Seung-Rim;An, Kyoung-Lyong;Lee, Sunhye;Ko, Eunhee;Lee, In-Yeol;Kim, Changil;Jun, Kun
    • Textile Coloration and Finishing
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    • v.33 no.1
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    • pp.10-23
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    • 2021
  • In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

Removal of Malodorous Gases Emitted from a Wastewater Pumping Stations by Biological Methods (생물학적 방법에 의한 하수 중계펌프장의 악취제거)

  • 류희욱
    • Microbiology and Biotechnology Letters
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    • v.32 no.3
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    • pp.265-270
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    • 2004
  • To select a promising technologies for removal of odorous gases emitted from a wastewater pump station, four methods such as activated carbon (A/C) adsorption, chemical absorption (acid and alkali scrubber), and two biofilters (polyurethane (PU) and worm cast) were investigated. The average odor removal efficiencies in the PU biofilter and A/C column was over 98%, but in a worm cast biofilter and chemical absorption were below 60-80%. The removal efficiency of PU biofilter was very stable (about 98-99%) in the range of retention times of 4-36s, and a maximum elimination capacity was $1.6${\times}$10^{ 7}$ $OUm^{-3}$$h^{-1}$ Deodorization costs for an activated carbon adsorption and a biofiltration method were investigated. With increasing odor intensity, the operating cost of the A/C column increased linearly, but the operating cost of the biofilteration increased slightly. The capital cost in a biofilter is about two times higher than that in an A/C column, but the operating cost is very lower than that of in A/C column. In conclusion, the biofiltration was evaluated one of the most promising technologies to control odor in a wastewater pump station.

The Study of Polar Effects of Aluminium Sulfate on the Reduction of Phenolic Resin Spreading Content for the Manufacture of Plywood (황산(黃酸)알루미늄의 극성효과(極性效果)로 인(因)한 합판용(合板用) 페놀 수지(樹脂) 도포량(塗布量)의 감소(減少)에 관(關)한 연구(硏究))

  • Lee, Joung-Sin;Lee, Hwa-Hyoung
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.2
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    • pp.29-35
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    • 1986
  • This study was carried out to examine the effect of aluminium sulfate addition to the alkali-acid catalyst phenolic resin for the manufacture of the kapur (Dryobalanops spp.) plywood on the reduction of phenolic resin spreading. On the manufacture of plywood, Adhesive Contents such as 50g/$m^2$, 75g/$m^2$ and 150g/$m^2$ were treated. The spreading adhesive content of 50g/$m^2$ and 75g/$m^2$ had been controlled to about 150g/$m^2$ added with the water in order to get sufficient spreading and controlled to pH 4.5 with aluminium sulfate [$Al_2(SO_4)_3$]. The results are summarized as follows: 1. Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.77 to 0.86 and their moisture contents met the KS requirements. 2. In dry and wet shear strengths, 150 $P_{Al{\cdot}Ac}$ adhesive showed the highest and 75 $P_{Al{\cdot}Ac{\cdot}Am}$ adhesive indicated higher value than 150 $P_{Al{\cdot}Ac}$ adhesive. 3. In case of glue shear strength after boiling test, 150 $P_{Al{\cdot}Ac}$ adhesive was the best and adding of aluminium sulfate was not effective on reinforcement of boiling water resistance of phenolic resin, but met KS requirements. 4. 75 $P_{Al{\cdot}Ac{\cdot}Am}$ adhesive showed the good shear strength and met KS requirements. Therefore, adding of aluminium sulfate was very efficient for economical plywood manufacture.

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Synthesis of Biodiesel Using Supercritical Fluid (초임계유체를 이용한 바이오디젤연료의 제조기술)

  • Lee, Youn-Woo;Song, Eun-Seok;Kim, Hwayong
    • Clean Technology
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    • v.11 no.4
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    • pp.171-179
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    • 2005
  • Biodiesel is synthesized by transesterification of vegetable or animal oils with alcohols. Since it has similar characteristic with diesel fuel, it can be used as a fuel by mixing with diesel fuel. Moreover, it is advantageous that biodiesel can reduce air pollution emitted from fuel combustion and is produced from sustainable energy, biomass. Recently, many researchers have investigated biodiesel synthesis using supercritical methanol since it is economical due to shorter reaction time and simple separation/purification process, compared with conventional alkali- or acid-catalyzed process. By the development of biodiesel production process from waste edible oil using supercritical methanol, it can be expected to utilize potential energy resources, reduce carbon dioxide emission, and improve environmental conditions.

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