• Title/Summary/Keyword: Acid and Alkali

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Nondestructive Evaluation of Free Acid Content in Apples using Near-infrared Spectroscopy (근적외 분광분석법을 응용한 사과의 유리산 함량 측정)

  • Sohn, Mi-Ryeong;Cho, Rae-Kwang
    • Applied Biological Chemistry
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    • v.41 no.3
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    • pp.234-239
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    • 1998
  • In non-destructive evaluation of free acid content in apples by near- infrared spectroscopy(NIRS), browning and heat treatment of squeezed apple juice affected to the accuracy but titrable alkali concentration did not. The free acid content in apples after harvest was able to determine using different apples in harvest time for calibration making. The result of MLR, multiple correlation coefficient(R) was 0.77 and standard error of prediction(SEP) was 0.03%. The free acid content in apples during storage was able to determine using calibration equation established with stored apples, R was 0.90 and SEP was ca. 0.04%. The prediction accuracy by LAIR was not sufficient for use of quantitative analysis of free acid content in apple, but classification of law and high level in acid content was supposed to be applicable.

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Studies on the Utilization of Acorn Starch -Part I. Properties of Acorn Starch- (도토리 녹말의 이용에 관한 연구 -제 1 보 도토리 녹말의특성-)

  • Chung, Dong-Hyo;Yu, Tai-Jong;Choi, Byeng-Kyu
    • Applied Biological Chemistry
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    • v.18 no.2
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    • pp.102-108
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    • 1975
  • Acorn starch preparation and some of its characteric study were made. The results obtained were as follows. 1) Yearly production of acorn in Korea is amounted to be 1,200,000 l approximately. The content of its carbohydrate was found to be 72.8%, so that this would be considered as one of good resources of starch in our country. 2) The major moieties of tannin constituents of acorn were found to be the gallic acid, catechin and chlorogenic acid. 3) The type of acorn starch granules were short oval shaped having the diameters of that were in the range of $3.5{\sim}5.2{\mu}$ and $8.0{\sim}19.5{\mu}$, respectively. 4) Initial gelatinifalion teniperaiure of acorn starch was $62{\sim}64^{\circ}C$, similar to those of corn and wheat starch. 5) Alnylose content of acorn starch were 27.1%, which is lower than that of barley but higher than that of potato starch. 6) The raising power of the acorn starch was 12.4, which is higher than that of the potato starch but lower than those of common cereal starches. 7) The blue value of acorn starch was 0.43, similar to that of wheat starch and higher than those of wheat potato and rice starch but lower than that of barley starch. 8) The alkali number of the acorn starch was 11.03, similar to that of corn starch but higher than those of barley and rice starch.

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Negative Pressure Wound Therapy of Chronically Infected Wounds Using 1% Acetic Acid Irrigation

  • Jeong, Hii Sun;Lee, Byeong Ho;Lee, Hye Kyung;Kim, Hyoung Suk;Moon, Min Seon;Suh, In Suck
    • Archives of Plastic Surgery
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    • v.42 no.1
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    • pp.59-67
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    • 2015
  • Background Negative-pressure wound therapy (NPWT) induces angiogenesis and collagen synthesis to promote tissue healing. Although acetic acid soaks normalize alkali wound conditions to raise tissue oxygen saturation and deconstruct the biofilms of chronic wounds, frequent dressing changes are required. Methods Combined use of NPWT and acetic acid irrigation was assessed in the treatment of chronic wounds, instilling acetic acid solution (1%) beneath polyurethane membranes twice daily for three weeks under continuous pressure (125 mm Hg). Clinical photographs, pH levels, cultures, and debrided fragments of wounds were obtained pre- and posttreatment. Tissue immunostaining (CD31, Ki-67, and CD45) and reverse transcription-polymerase chain reaction (vascular endothelial growth factor [VEGF], vascular endothelial growth factor receptor [VEGFR]; procollagen; hypoxia-inducible factor 1 alpha [HIF-1-alpha]; matrix metalloproteinase [MMP]-1,-3,-9; and tissue inhibitor of metalloproteinase [TIMP]) were also performed. Results Wound sizes tended to diminish with the combined therapy, accompanied by drops in wound pH (weakly acidic or neutral) and less evidence of infection. CD31 and Ki-67 immunostaining increased (P<0.05) post-treatment, as did the levels of VEGFR, procollagen, and MMP-1 (P<0.05), whereas the VEGF, HIF-1-alpha, and MMP-9/TIMP levels declined (P<0.05). Conclusions By combining acetic acid irrigation with negative-pressure dressings, both the pH and the size of chronic wounds can be reduced and infections be controlled. This approach may enhance angiogenesis and collagen synthesis in wounds, restoring the extracellular matrix.

Free Amino Acid and Polysaccharide Content of Submerged Mycelial Culture of Fomitopsis pinicola (귤피 및 녹차추출물에서 배양한 소나무잔나비버섯(Fomitopsis pinicola) 균사체의 유리아미노산 및 다당류 함량)

  • Jang Kyung-Ho;Shin Kyung-Ok;Kim Soon-Dong
    • Food Science and Preservation
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    • v.12 no.4
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    • pp.379-386
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    • 2005
  • Free amino acids and polysaccharide content of submerged mycelial culture of Fomitopsis pinicola using $2\%$ citrus peel water extracts(CP), $2\%$ green tea water extracts(GT) and yeast-malt broth(YM) were investigated. Cultivations were conducted at $30^{\circ}C$ and 150 rpm for 10 days. Yields of the mycelium as fresh weight basis in GT-, CP- and YM-broth were $42.3\%,\;34.2\%\;and\;9.89\%$, and their turbidity(OD at 660 nm) of the broth without mycelium were 0.14, 0.16 and 0.22, respectively. Total free amino acid content in the mycelium were 928.19 $mg\%$ in YM, 1060.53 $mg\%$ in CP, 764.83 $mg\%$ in GT, and the major free amino acid was lysine in YM, glutamic acid in CP and GT. Total free exo-amino acid contents were 659.75 $mg\%$ in YM, 954.55 $mg\%$ in CP, 838.69 $mg\%$ in GT, and the major in the all broths was glutamic acid Total amino acid derivatives content of the mycelium were in order of CP>GT>YM, and the major was cystathionine in YM, hydroxy proline in CP and GT. The major among exo-amino derivatives was hydroxy proline in the all broth. Exo-AIS content was in order of CP>GT>YM. Acid soluble polysaccharide content of the mycelium was GT($0.69\%$)>YM($0.39\%$)>CP($0.18\%$). The exo-polysaccharide content was in order of GT($0.87\%$)>CP($0.69\%$)>YM($0.09\%$). Alkali soluble polysaccharide content of the mycelium was in order of CP($5.21\%$)>GT($5.18\%$)>YM($4.56\%$), and exo-polysaccharide was in order of GT($6.79\%$)>YM($3.57\%$)>CP($3.01\%$). The alkali soluble polysaccharide eluted from mycelium cultivated in CP broth was supposed to polysaccharide(about 500,000 daltons) composed of hexose and uronic acid bounded with protein(below 10,000 daltons).

A Clinical Study on Recent Causing Agents of Chemical Burns (화학 화상의 최근 원인 물질에 관한 임상적 연구)

  • Shin, Chi Ho;Yu, Sung Hoon;Kim, Ji Hoon;Kim, Dong Chul
    • Journal of the Korean Burn Society
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    • v.23 no.1
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    • pp.7-12
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    • 2020
  • Purpose: Due to rapid changes in the industrial structure in last decade, the wider various types of chemical agents were introduced. Burn surgeons should be well-informed with rapid changes of chemical burns. We present the recent incidence trends of causing agents of chemical burns. Methods: From 2010 to 2019, 92 chemical burn victims were included in this study. A retrospective study was made about the type, distribution and incidence of the causing agents of chemical burns. Initial treatments of most chemical burn wounds are copious saline irrigation by tap water, except hydrofluoric acid burn cases managed by 10% calcium gluconate injection. In alkali chemical burns on extremity, if thin eschars appear in postburn 2~3 days, acute early surgical escharectomy and split thickness skin graft were done. Results: More than 9 types of major chemicals causing chemical burns were surveyed, and the most common causing agent of chemical burns was Hydrofluoric acid (23.9%) followed by Acetic acid (19.6%) and Sodium hydroxide (8.7%). Conclusion: From 2010 to 2019, changes in the causing agent of chemical burns are that the types of major causing agents of chemical burns have increased and the distribution and incidence of causing agents have changed compared to previous reports. According to this study, more than 9 types of major chemicals causing chemical burns were surveyed, and the most common causing agent of chemical burns was Hydrofluoric acid (23.9%) followed by Acetic acid, Sodium hydroxide.

Studies on the Utilization of Keratins (경단백질(硬蛋白質)의 이용(利用)에 관(關)한 연구(硏究))

  • Suh, Hong-Kyl
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.5 no.1
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    • pp.75-80
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    • 1976
  • The development of protein utilization with keratin(cattle hair and human hair) have heen investigated. The include a) conditioning of hydrolysis of keratin, b) isolation of crude protein, c) pepsin HCl digestibility of isolated protein, d) the amino acid composition of isolated protein and amino acid concentrate. The results are obtained as follow ; 1. Human hair and cattle hair were softened and hydrolysed with hot dilute alkali(especially 1% NaOH) 2. Crude protein were isolated from hydrolysed keratin by means of different solubility and isoelectric point. 3. The protein isolated was of good quality on the point of color, protein content and pepsin digestibility. 4. The amino acid concentrate obtained by acids processing was of good quality on the point of color, taste and amino acid composition.

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A Study on the Synthesis of Carboxymethyl Chitin and Separation of Alkali-Earth Metal ions by Adsorption (Carboxymethyl Chitin의 합성 및 알칼리 토금속 이온의 흡착분리에 관한 연구)

  • Choi, Kyu-Suk;Chang, Byung-Kwon;Kim, Chong-Hee;Kim, Yong-Moon
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.270-278
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    • 1991
  • Carboxymethyl chitin(CM-chitin) was prepared by the reaction of alkali chitin with monochloroacetic acid in isopropyl alcohol. According to the pH variation, the adsorptivity of this chelating polymer to the alkali-earth metal ions such as $Ca^{2+},\;Mg^{2+}$, $Sr^{2+}$, $Ba^{2+}$ ions was determined by batch method. The adsorption tendency of this chelating polymer to most metal ions was increased with the increase of pH. The highest degree of adsorption was observed toward $Ca^{2+}$ ion among the alkali-earth metal ions. The selectivity adsorption property toward $Ca^{2+}$ ion was examined in the solution of $Ca^{2+}$ and $Mg^{2+}$ ions, and it was observed that CM-chitin showed excellent selectivity to $Ca^{2+}$ ion than $Mg^{2+}$ ion. $Mg^{2+}$ ion bound to CM-chitin molecule in the presence of $Ca^{2+}$ ion owing to low equilibrium constant. In the adsorption experiment of $Ca^{2+}$ and $Mg^{2+}$ ions to the CM-chitin under coexistence of $Na^+$ and $K^+$ ions, it observed that adsorptivity of only $Ca^{2+}$ ions was not affected by these monovalent cations.

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Alkalinity Supplement using Sea Shell for Sulfur-utilizing Autotrophic Denitrification (황-이용 독립영양 탈질에서의 패각을 이용한 알칼리도 공급)

  • Byun, Jung-Sup;Bum, Bong-Su;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1777-1787
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    • 2000
  • The purpose of this study was to select an effective and economical alkali source for sulfur-utilizing autotrophic denitrification. Tests on acid neutralization and denitrification at various alkali/sulfur mixing ratios were performed for charcoal, briquette ashes, sea shell, and limestone. The results of the experiments showed that sea shell was the most effective alkali source because it could provide more surface area than limestone, and the optimal alkali/sulfur mixing ratio was 1/1(V/V). In a sulfur/sea shell packed bed reactor, the denitrification efficiency was above 90% up to a loading rate of 116 g $NO_3{^-}-N/m^3-day$. but the denitrification efficiency deteriorated to 48% at the loading rate of 145 g $NO_3{^-}-N/m^3-day$. The average $SO_4{^{2-}}$ generation per g of $NO_3{^-}-N$ removed was 7.02 g, which is lower than the theoretical value of 7.54 g. Denitrification and sulfate generation appeared to be a first-order and a zero-order reaction with a reaction rate constant of 0.146 /hr and -53.1 mg/L-hr, respectively. According to nitrogen mass balance, 71~109%, with an average of 90%, of the removed nitrogen was recovered as $N_2$ gas.

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Preparation of Amino Acid by Chemical Synthetic Methods (화학합성법에 의한 아미노산의 합성)

  • Son, Tae-Il
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.254-263
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    • 1993
  • The industry of amino acids has developed for the synthetic methods, zymotechnics from the methods of extraction. In the present, part of amino acids (L-cystine, L-tyrosine, etc.) is manufactured by the methods of extraction, but most of amino acids is produced by synthetic methods, zymotechnics. Among the methods, the synthetic methods use of cyanic acid, which generate a large of waste water by acid or alkali in hydrolysis. In this point of view, improved new synthetic methods are demanded for being the influence of environment. This article Introduces new synthetic methods of phenyl alnine, further more, the recent of research results are introduced to prepare the derivative ${\alpha}-keto$ acids of precursor for preparing more than particular amino acids.

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Thermophilic Anaerobic Acid Fermentation of Food Wastes after NaOH Addition (NaOH 첨가에 따른 음식물찌꺼기 고온 혐기성 산발효)

  • Ahn, Chul-Woo;Lee, Chul-Seung;Seo, Jong-Hwan;Park, Jin-Sik;Moon, Choo-Yeon;Jang, Seong-Ho;Kim, Soo-Seung
    • Korean Journal of Environmental Agriculture
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    • v.23 no.4
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    • pp.220-227
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    • 2004
  • This study showed that thermophilic anaerobic acid fermentation of food wastes had an enhanced hydrolysis capability and improvement of acidification efficiency. Influence of pH on the anaerobic hydrolysis and acidogenesis was investigated to determine the proper alkalinity in the thermophilic fermentation of food wastes. The results of putting NaOH as alkali to evaluate hydrolysis and acid fermentation efficiency In acid fermentation process of food wastes showed that the food wastes pretreated with 0.05 g NaOH/g TS had the maximum 12,600 mg/L of VFAs concentration during HRT 3 days in $55^{\circ}C$ thermophilic condition and the maximum 9,700 mg/L of VFAs concentration during HRT 5 days in $35^{\circ}C$ mesophilic condition. The accomplishment of high VFAs concentration resulted from that the main component of food wastes such as cellulose, lignin and etc. is performed active chemical decomposition by alkali in thermophilic condition. The major components of VFAs produced from the thermophilic acid fermentation process of food wastes were the short chain fatty acids such as acetic acid, butyric acid, and propionic acid.