• Title/Summary/Keyword: Acid and Alkali

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Discoloration of Woods (2) - 36 Commercial Hardwoods Grown in Korea - (목재(木材)의 오염(汚染)에 의한 변색(變色) (2) - 한국산(韓國産) 활엽수재(闊葉樹材)의 화학적(化學的) 변색(變色) -)

  • Ahn, Kyung-Mo;Kong, Young-To;Jo, Jae-Myeong
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.1
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    • pp.55-60
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    • 1986
  • Discoloration sensitivities of woods grown in this country haven't reported yet. Therefore we examined discoloration sensitivities of domestic wood specimens to iron (0.1 %, $FeCl_3.6H_2O$), alkali (pH 12.0, NaOH). acid (pH 1.0, $C_2H_2O_4$) and exposing to sunlight (40 hrs), Thirty-six hardwood species were collected and examined. All specimens were prepared from heartwoods of the collected species. But the specimens of 4 Betula species were divided into sapwoods and heartwoods. By iron stain, the color differences (${\Delta}E$) of 21 wood specimens including one Betula sapwood showed above 12.0, which means strong discoloration sensitivities, and of 3 specimens including one Betula sapwood showed below 2.5, which means weak discolorations. The most strong iron discoloration species was Jungkukgulpi-namu (Pterocarya stenoptera). By alkali stain, the color differences (${\Delta}E$) of 3 wood specimens showed above 9.0, which means strong discoloration sensitivities, and of 18 wood specimens including 4 Berula sapwoods showed below 2.5, which means weak discolorations. By acid stain, the color differences (${\Delta}E$) of 6 wood specimens showed above 10.0 which means strong discoloration sensitivities, and of 12 wood specimens including one Betula sapwoods showed below 2.5, which means weak discolorations. By exposing to sunlight, the color differences (${\Delta}E$) of 31 wood specimens including one Betula sapwoods showed below 6.5, which means, strong discoloration sensitivities, and of only one specimens showed below 2.5, which means weak discoloration. The most strong discoloration species by exposing to sunlight was Guirung-namu (Prunus padus). In general, it was shown that hardwoods grown in Korea were most subject to change of color by exposing to sunlight and next were by iron stain. Domestic hardwoods showed some differences in discoloration sensitivities from domestic softwoods previously reported.

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A Study on Using Gray Color Dyeing from Gallapple (오배자에 의한 회색계열 염색에 관한 연구)

  • Shin, Nam-Hee;Kim, Sung-Yeon;Cho, Kuyung-Rae
    • Fashion & Textile Research Journal
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    • v.7 no.5
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    • pp.547-552
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    • 2005
  • The study has objective in raising value of the gray color as a meaningful color suiting sentiments of modern people by expressing the gray color in various perspective utilizing natural dyes that is natural at the same time having aesthetic color tones. For example, the main ingredient used for coloring black and gray color is the pyrogallol tannin and the gray tone dye can be acquired by combining the tannin with iron. In order to find the suitable condition for processing tannin, UV-Vis part absorption spectrum of Gallapple pyrogallol tannin, dye ability based on temperature and time, reflection rate based on concentration, color changes based on acid treatment and alkali treatment, changes on surface based on concentration or metal mordant condition, and lightfastness were measured. Maximum absorption wavelength (${\lambda}_{max}$) of Gallapple tannin was at around 273 nm, while strong absorption was also observed at below 350 nm. Dye ability of Gallapple tannin is done more easily on silk rather than cellulose fibers such as cotton, while the optimum condition for dyeing was observed to be at $60^{\circ}C$, for 20 minutes. As a result of acid treatment, the color of dye material consist highly of gray tones and showed red tone after the alkali treatment. While it was observed that as dye concentration and metal mordant concentration increased the color changed at counter-clockwise direction on the Y-scale of Munsell's scale of colors. Lightfastness was more on a normal fading. I hope this study opens up possibilities towards presenting gray color expressed from tannin as color with diversity and aesthetic value. In future, comparative study between dye expressed from catechol tannin dye materials will be helpful.

Studies on the Fermentative Utilization of Cellulosic Wastes (Part 7) Culture of Cellulolytic Bacteria from Miscanthus (폐섬유자원의 발효공학적 이용에 관한 연구 (제7보) 억새풀을 기쇄로 한 섬유소 자화세균의 배양)

  • 성낙기;윤한대;심기환;이천수
    • Microbiology and Biotechnology Letters
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    • v.5 no.3
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    • pp.127-131
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    • 1977
  • Various kinds of native herbage grasses like-Miscanthus sinensis, Arundinella hirta, Cymbopogen geirngii, Themeda japonica etc. are widely distributed in every Korean mountain. So we investigated the availability of native grass, Miscanthus sinensis as a substrate for the production of S. C. P. The results were obtained as follows. 1) At the alkali treatment, NaOH was the most effective with the exclusion of lignin, and pretreated Miscanthus with NaOH appeared to be a good substrate for the microbial growth. 2) When Miscanthus was treated with one to 10% NaOH, the microbial growth increased in proportion to the increased alkali concentration. Beyond 4% NaOH, a slight increase was observed. 3) Phosphoric acid, as a neutralizer, was the most effective in cell production after alkali treatment. 4) On the effect of incubation time, the productivity was best found at 60 hours, and the cell weight was 9.23 mg per 1 ml, and the microbial digestibility of substrate was 75.2%.

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Properties of the Alkali Activated Mortar According to Metakaolin Replacement Ratio (알칼리 활성화 모르타르의 메타카올린 치환율에 따른 특성)

  • Seo, Dong-Hyeon;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.313-320
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    • 2016
  • The aim of this study is to look into the metakaolin replacement ratio of blast furnace slag based alkali activated slag mortar and its mechanical characteristics according to changes in stimulant concentration. Metakaolin has high fineness, and therefore the fluidity becomes lower as the replacement ratio becomes higher. So in this study, a sufficient value of mixing water was provided to secure fluidity for the characteristic experiment, and a different W/B was derived for each specimen in order to make the fluidity identical. A characteristic experiment was conducted according to the mol concentration of NaOH, which was used as the mixing water that affects fluidity. Additionally, compressive strength measurement, observation of inner microstructure through SEM, acid resistance experiment, and neutralization resistance was conducted. The results of this study revealed that for a high concentration NaOH solution to have even fluidity, a high W/B is necessary, and the functions were enhanced, not degraded.

암석 용해방법에 따른 미량원소 분석결과 비교

  • 최만식;정창식;박계헌
    • The Journal of the Petrological Society of Korea
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    • v.3 no.1
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    • pp.41-48
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    • 1994
  • Three USGS rock standards (G-2, W-2, and BHVO-1) are decomposed by three different methods, such as open beaker, microwave oven, and alkali fusion method, to compare the effect of decomposition methods for trace elememt analysis in the rock samples. Solubilized trace elements are measured with inductively coupled plasma mass spectrometer (ICP-MS). Generally the analytical results of trace elements between open beaker and microwave digestion method are not different. In case of alkali fusion method, some volatile elements such as Pb, Cu, and Rb are considerably lost. Using acid digestion method, Zr and Hf concentrations are lowered in case that these elements are concentrated in refractory minerals. The concentrations of rare earth elements are generally consistent with the recommended values, but due to large dilution factor, there are some analytical problems in alkali fusion method.

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Dyeability and Enzymetic Treatment of Wool Pretreated with tert-Butoxide (tert-Butoxide 처리 양모의 효소처리 및 염색성에 관한 연구)

  • 윤남식;윤성도
    • Textile Coloration and Finishing
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    • v.9 no.6
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    • pp.87-95
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    • 1997
  • Wool samples were treated by potassium tert-Butoxide(t-BuOK) in anhydrous tert-butanol to remove the bound surface lipid-layer, and the weight loss behaviors in protease solution and dyeabilities of the samples were studies. The C/N ratio of the surface of the t-BuOK-treated wool was shown to be 4.3 from XPS analysis. From SEM pictures any remarkable change in the shape of surface curticle during the proteasw treatment was not observed regardless of prior t-BuOK treatment. Dyeing rate and equilibrium adsorption of Orange II, a typical levelling type acid dye, on wool were not changed by protease or t-BuOK treatment, but those of Milling Cyanine 5R, a typical milling type acid dye, on wool were greatly enhanced by t-BuOK treatment in spite that, from alkali and urea-bisulfite solubilities, no damage on the inner part of wool fiber was expected by t-BuOK treatment.

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A study on the Coating Structure and Printability of Coated Paper (I) - Effect of Ionic Monomer on Paper-coating Latex Properties - (도공층 구조 및 도공지의 인쇄적성에 관한 연구 (I) - 이온성 단량체가 도공용 라텍스의 물성에 미치는 영향 -)

  • Lee, Yong-Kyu
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.3
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    • pp.75-82
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    • 1997
  • To improve the quality of coated paper, the continuous research to the coating components and development of alternative latices is required. Recently, amphoteric latex is getting a great concern due to their changable properties of surface charge through controlling pH and some methods have been tried to prepare amphoteric latices. This study was carried out to synthesize amphoteric latex using seeding polymerization method with low concentration emulsifier. Styrene was used as a main monomer in addition to acrylonitrile for a hydrophilic comonomer. acrylic acid for a anionic comonomer and N,N-dimethylaminoethyl methacrylate for a cationic comonomer. Particle size and viscosity of latex were greatly affected by addition of acrylic acid and ammonium persulfate as an initiator. Negative charge of latex in alkali condition was changed to zero to positive charge in around pH 4.

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A study on the selectivity in Acid- and Alkali-Based optimization Electrolytes for Electrochemical Mechanical (ECMP 적용을 위한 Acid-와 Alkali-Based 최적화 전해액 선정에 관한 연구)

  • Lee, Young-Kyun;Kim, Young-Min;Park, Sun-Jun;Lee, Chang-Suk;Bae, Jae-Hyun;Seo, Yong-Jin;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.484-484
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    • 2009
  • 반도체 소자가 차세대 초미세 공정 기술 도입의 가속화를 통해 고속화 및 고집적화 되어 감에 따라 나노 (nano) 크기의 회로 선폭 미세화를 극복하고자 최적의 CMP (chemical mechanical polishing) 공정이 요구되어지고 있다. 최근, 금속배선공정에서 높은 전도율과 재료의 값이 싸다는 이유로 Cu를 사용하였으나, 디바이스의 구조적 특성을 유지하기 위해 높은 압력으로 인한 새로운 다공성 막(low-k)의 파괴와, 디싱과 에로젼 현상으로 인한 문제점이 발생하게 되었다. 이러한 문제점을 해결 하고자 본 논문에서는 Cu의 ECMP 적용을 위해 LSV (Linear sweep voltammetry)법을 통하여 알칼리 성문인 $NaNO_3$ 전해액과 산성성분인 $HNO_3$ 전해액의 전압 활성화에 의한 active, passive, transient, trans-passive 영역을 I-V 특성 곡선을 통해 알아보았고, 알칼리와 산성 성분의 전해액이 Cu 표면에 미치는 영향을 SEM (Scanning electron microscopy), EDS (Energy Dispersive Spectroscopy), XRD(X-ray Diffraction)를 통하여 전기화학적 특성을 비교 분석하였다.

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Testing Investigation of Protective Coatings for Downhole Oil Tube

  • Zhang, Liping;Zhang, Qibin;Zhang, Yanjun;Xie, Beibei;Zhang, Yingying
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.13-15
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    • 2008
  • Aiming at the corrosion circumstances and corrosion prevention needs of downhole oil tubes, series protective coatings for downhole oil tubes have been developed in the authors' laboratory, including a baked type coating YG-01 and an air curing type coating YG-03, etc. The performance investigation of the coatings has been done for testing their corrosion resistance, mainly including salt fog test, immersion test in oil-field waste water and various acid solutions, high temperature and high pressure test in alkali solution or $H_2S/CO_2$ environment, as well as some other performances. The investigation results show that oil tube anti-corrosion coatings developed here can endure over 4000 hrs salt fog test, over 1000 hrs immersion in various acid solutions at room temperature and in boiling oil-field waste water. In addition, the coatings can keep intact after experiencing test in alkali solution under 70 MPa pressure at $150^{\circ}C$ for 24 hrs, and in simulative sour gas environment under the total pressure of 32 MPa ($P_{H_{2}S}=3.2MPa$, $P_{CO_{2}}=3.2MPa$) at $90^{\circ}C$ for 168 hrs, which show that the coatings can be used for corrosion prevention in downhole environments with specific high temperature and high pressure, such as sour gas wells. The other testing results show the oil tube protective coatings have excellent comprehensive performance.

Study on pH Reducing Method of Recycled Fine Aggregate for Embanking or Covering (성복토용 순환잔골재의 pH 저감방법에 관한 연구)

  • Han, Min-Cheol;Han, Dongyeop
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.23-30
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    • 2017
  • The aim of the research is to suggest an economical and sustainable method of reducing pH of recycled aggregate as an embanking and a covering materials. Because of the unhydrated cement based materials on the surface of the recycled aggregate, it causes a severe problem on environment with leaked high alkali water from embankment and covering by using recycled aggregate. In this research, to reduce the pH of recycled aggregate, regarding the recycled fine aggregate, eight different methods were tested and analyzed with three different categorized: natural treatment, artificial treatment, and chemical treatment. From the results of experiment, it was considered that the most efficient method of reducing pH of recycled aggregate was the chemical treatment using acid such as $CO_2$ acceleration or monoammonium phosphate (MAP), and diammonium phosphate (DAP). Especially, using MAP and DAP, fertilizers, is the most efficient method of reducing pH with its time duration and performance.