• Korean Chemical Engineering Research
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• 제46권6호
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• pp.1025-1028
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• 2008

본 논문에서는 탄화수소가스의 기체상 열분해과정에서 생성되는 탄소나노입자의 성장을 온도의 변화에 따라 체계적으로 관찰하였다. 탄화수소가스의 열분해온도가 상승할수록 최종적 산물인 탄소나노입자의 생성율과 물리적 크기가 증가하는 것을 확인하였다. 하지만, 다양한 탄화수소가스 중에서 아세틸렌($C_2H_2$)과 에틸렌($C_2H_4$)의 열분해과정 비교 실험 결과 탄소나노입자 생성률이 큰 차이를 보임을 관찰하게 되었고 이것은 탄화수소가스의 열분해과정에서 생성되는 수소의 영향이 아닐까 가정하게 되었다. 이러한 탄화수소의 열분해과정에서 수소의 역할을 규명하기 위해서 아세틸렌가스의 열분해과정에 정밀하게 제어된 양의 수소를 주입하면서 탄소나노입자의 생성을 실시간으로 모니터링한 결과 수소의 주입이 탄소나노입자의 생성 및 성장을 억제하는 역할을 함을 관찰하였다. 결국 탄화수소가스의 열분해과정에서 적절하게 수소의 양을 제어한다면 최종적으로 생성되는 탄소나노입자의 크기를 제어할 수 있을 것이다.

• 한국안전학회지
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• 제6권2호
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• pp.31-36
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• 1991

Quenching effects of acetylene and hydrogen into oxygen detonation by using detonation arrester ［DA］are studied in this paper. The experiments were carried out in cylinderical shock tube. 5m long, 30mm dia., with stolchlometric ratio ［SR］of each gas and 10-l20$\mu$ Cell Size of brass and Stainless Steel of DAs were installed in it To clarify arresting ability correlation with initial pressure, Pi, critical thickness, Tct, and shapes of supporting panel of DA are also investigated It is found that ­detonation velocities has most dependency on Pi, it shows notable changes around 0.5kgf/$\textrm{cm}^2$ for hydrogen, 0.15kgf/$\textrm{cm}^2$ for acetylen respectively, ­DA can be safety device able to arrest shock wave of detonation, ­over Tct flame transmission might be only the factor has to be considered, ­acetylene seems to be much more stronger detonation characteristics than hydrogen because of reaction heat.

• 한국자동차공학회논문집
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• 제10권6호
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• pp.80-89
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• 2002

The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1991년도 추계학술대회 논문집 학회본부
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• pp.261-264
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• 1991

Titanium carbide(TiC) films were deposited on stainless-steel sheets using HCD(Hollow Cathode Discharge) reactive ion plating. Acetylene gas was used as the reactant gas. The characteristics of TiC films were examined by X-Ray diffraction, $\alpha$-step, ESCA(Electron Spectroscopy for Chemical Analysis), and, AES(Auger Electron Spectroscopy). The results were discussed with regard to various deposition conditions(bias voltage, acetylene flow rate, temperature).

• 한국안전학회지
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• 제11권4호
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• pp.64-71
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• 1996

Detonation phenomena of $C_2H_2$were invesgated using the various shock tube. To study the detonation characteristics according to the composition of $C_2H_2-0_2$$_2$ and $C_2H_2$-air mixtures, the composition were varied from 5 to 90% and 5 to 50% of acetylene each other. A spiral ring was installed in the shock tube to study the effect of obstacles in DDT phenomena. Detonation velocities were measured using the photodiode, and the DDT phenomena was visualized using the high speed schlieren photograph. From the experimental result, it was found that the detonation velocity was most high near the 1. 8times the stoichiometric ratio of acetylene. And from the visualization of DDT phenomena, it was found that the detonation wave was strengthened throuth the pile up of small compression wave of burned gas. And the obstacles in shock tube accelerate the detonation reaction by turblent effect of flammable gas mixture.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2012년도 추계학술대회
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• pp.332-334
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• 2012

본 연구는 우리나라 선박 및 항해와 관련된 항로표지 업무를 관장하기 위해 설치된 국가제도 등에 관한 기록들을 주요 역사서를 통해 살펴보고, 삼국시대부터 봉수(烽燧)와 봉화(烽火) 같은 횃불을 밝혀 선박의 안전항해를 돕기 시작하여 근대 이후에는 석유등, 아세틸렌가스등, 전기등, LED 광원을 등대광원으로 사용한 변천과정을 알아본다.

• 한국표면공학회지
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• 제34권1호
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• pp.56-61
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• 2001

In this work, the surface treatment of aluminum/composites (graphite-epoxy composites) was investigated. The surface of composites was treated by $Ar^{+}$ ion beam under oxygen environment. The surface of aluminum was treated by DC plasma. The optimal condition of surface treatment for the composites was determined by measuring the contact angle as a function of ion dose. The optimal treatment condition of the aluminum was determined by measuring the contact angle and T-peel strength as a function of mixture ratio of acetylene gas to nitrogen gas. The mixture ratios used were 1:9, 3:7, 5:5, 7:3, and 9:1. The results showed that the contact angle of composites decreased from$ 81^{\circ}$ to $8^{\circ}$ as the ion dose increased from zero to $1$\times$10^{17}$ions/$\textrm{cm}^2$. The optimal condition of ion dose was $1$\times$10^{16}$ions/$\textrm{cm}^2$. The results also showed that the contact angle of aluminum was a minimum for the mixture ratio of 5:5. Similarly, the T-peel strength was a maximum for the mixture ratio of 5:5, which indicates that the optimal condition of mixture ratio of acetylene gas to nitrogen gas is 5:5.

• 동력기계공학회지
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• 제15권1호
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• pp.51-56
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• 2011

The various process parameters of thermal spray process affects on quality of Ni-based coatings. Thus, there is need to analyze the effect of process parameters on quality of Ni-based coatings. In this paper, the effects of process parameters on hardness and wear rate of Ni-based coatings were investigated using 4 design of experiments. First, the Ni-based coatings were fabricated according to $L_9(3^4)$ orthogonal array. The hardness tests and the wear tests were performed on the Ni-based coatings. The analysis of variance for the hardness and wear rate were carried out. As a results, the acetylene gas flow and the powder feed rate were identified as main factors effected on the hardness and the oxygen gas flow and the acetylene gas flow were identified as main factors effected on the wear rate. The full factorial experiments design with different levels was applied for investigation of effect of these main factors.

• 한국생산제조학회지
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• 제19권2호
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• pp.230-234
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• 2010

Hydrox gas which is the mixed gas of hydrogen and oxygen gained fromwater electrolysis is one of the new clean energy sources and thus is researched and commercialized actively. Especially, it can be replaced the fossil energy and shows the better quality compared to the conventional energy such as LPG or acetylene gas. The mixed gas of hydrogen and oxygen is gained from water electrolysis reaction. It has constant volume ratio 2:1 of hydrogen and oxygen, and it is used as a source of thermal energy by combustion reaction. Further, hydrox gas is nearly a mixed ideal gas combusting itself completely and its combustion shows anunique characteristics of implosion. In this study, temperature rise effects on hydrox gas content through mixed combustion test of kerosene and hydrox gas and LPG and hydrox gas are investigated. it is also confirmed that economy of mixed combustion of hydrox gas as effective energy is fairly probable.

• 해양환경안전학회지
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• 제20권6호
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• pp.768-773
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• 2014

본 연구에서는 메탄 대향류 확산 화염내 탄소나노튜브의 합성에 대하여 실험 및 수치적 연구를 수행하였다. 아세틸렌을 일정비율로 메탄에 혼합하여 연료 가스로 사용하였으며, 탄소나노튜브의 합성을 위한 촉매로서 페로센이 이용되었다. 주요 인자로는 메탄 연료에 대한 아세틸렌의 혼합비율이며, 2 %, 6 %, 10 %로 혼합하였다. 탄소나노튜브를 채취한 그리드 위의 탄소나노튜브 합성 특성은 SEM 이미지로 분석되었다. 수치해석에서 화학반응 메카니즘으로는 GRI-Mech 3.0 이 적용되었다. 수치결과로는 아세틸렌 혼합 비율이 증가할수록 화염 온도도 증가하며 CO 몰분율도 증가하는 것을 알 수 있다. 실험결과로는 2% 아세틸렌 혼합 화염이 6 % 및 10 % 혼합 화염과 비교해 탄소나노튜브 합성이 잘 이루어졌음을 알 수 있었다. 이것은 6 % 및 10 % 아세틸렌 혼합화염의 경우 과도한 카본 소스의 생성이 발생해 오히려 화염 내 카본소스가 촉매입자로의 공급을 방해하기 때문이라 생각한다. 이 결과로부터 양호한 질의 탄소나노튜브 생성을 위해서는 적정한 양의 카본소스가 생성되어야 한다는 것을 알 수 있었다.