• Title/Summary/Keyword: Acetone Vapor

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Uniaxial Compressive Strength of Rock under Non-atmospheric Environments

  • Jeong, Hae-Sik;Obara, Yuzo
    • Proceedings of the KSEG Conference
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    • 2003.04a
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    • pp.131-135
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    • 2003
  • In order to investigate the influence of surrounding environment on strength of rock, the uniaxial compression test under non-atmospheric environments was conducted on Kumamoto andesite. The environments used in this study are water vapor, organic vapor environments as methanol, ethanol and acetone and inorganic gas environments as oxygen, nitrogen and argon. From the experimental results, it is clarified that water is the most effective agent which promotes stress corrosion of rock. Furthermore, the strength of rock increases with decreasing water vapor pressure. From the relation between uniaxial compressive strength and water vapor pressure, the stress corrosion index of Kumamoto andesite is estimated 24.

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Thermal Performance of a Small-scale Loop Heat Pipe for Terrestrial Application (지상용 소형 루프히트파이프 성능에 관한 연구)

  • Chung, Won-Bok;Boo, Joon-Hong
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1052-1057
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    • 2004
  • A small-scale loop heat pipe with polypropylene wick was fabricated and tested for its thermal performance. The container and tubing of the system was made of stainless steel and several working fluids were used to see the difference in performance including methanol, ethanol, acetone, R134a, and water. The heating area was 35 mm ${\times}$ 35 mm and there were nine axial grooves in the evaporator to provide a vapor passage. The pore size of the polypropylene wick inside the evaporator was varied from 0.5 m to 25 m. The size of condenser was 40 mm (W) ${\times}$ 50 mm (L) in which ten coolant paths were provided. The inner diameter of liquid and vapor transport lines were 2.0 mm and 4.0 mm, respectively and the length of which were 0.5 m. The PP wick LHP was operated with methanol, acetone, and ethanol normally. R134a was not compatible with PP wick and water was unsuitable within operating limit of $100^{\circ}C$. The minimum thermal load of 10 W (0.8 W/cm2) and maximum thermal load of 80 W (6.5 W/cm2) were achieved using methanol as working fluid with the condenser temperature of $20^{\circ}C$ with horizontal position.

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VOLATILE CONSTITUENTS OF COOKED SQUID (피등어꼴뚜기의 자숙취에 관한 연구)

  • LEE Eung-Ho;KOIZUMI Chiaki;NONAKA Junsaku
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.4
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    • pp.183-188
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    • 1978
  • In this study, gas chromatographic analysis was carried out on volatile constituents of cooked squid for the object of obtaining information on the characteristic flavor of the cooked squid meat. The results obtained are as follows: 1) Methanol was the most effective solvent for the extraction of volatile constituents of squid meat. 2) Twenty five and thirty two peaks were detected from the condensate collected in cold traps which were immersed in ice water and dry ice-acetone, respectively. In these compounds, five kinds of volatile organic acids such as acetic acid, butyric acid, iso-valeric acid, valeric acid, and caproic acid were identified. 3) Eleven peaks were detected from the head space vapor collected in cold trap which is immersed in liquid nitrogen. Volatile amines identified in these components are as follows; methylamine, trimethylamine, dimethylamine, ethylamine, and iso-propylamine.

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A Vapor Sensor Based on a Porous Silicon Microcavity for the Determination of Solvent Solutions

  • Bui, Huy;Nguyen, Thuy Van;Nguyen, The Anh;Pham, Thanh Binh;Dang, Quoc Trung;Do, Thuy Chi;Ngo, Quang Minh;Coisson, Roberto;Pham, Van Hoi
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.301-306
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    • 2014
  • A porous silicon microcavity (PSMC) sensor has been made for vapors of solvent solutions, and a method has been developed in order to obtain simultaneous determination of two volatile substances with different concentrations. In our work, the temperature of the solution and the velocity of the air stream flowing through the solution have been used to control the response of the sensor for ethanol and acetone solutions. We study the dependence of the cavity-resonant wavelength shift on solvent concentration, velocity of the airflow and solution temperature. The wavelength shift depends linearly on concentration and increases with solution temperature and velocity of the airflow. The dependence of the wavelength shift on the solution temperature in the measurement contains properties of the temperature dependence of the solvent vapor pressure, which characterizes each solvent. As a result, the dependence of the wavelength shift on the solution temperature discriminates between solutions of ethanol and acetone with different concentrations. This suggests a possibility for the simultaneous determination of the volatile substances and their concentrations.

Selection of an Optimal Entrainer for Extractive Distillation of Azeotropic Acetone/Methanol System (Acetone/Methanol계 공비물의 추출증류를 위한 최적 Entrainer 선정)

  • Lee, JoonMan;Ahn, WonSool
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.539-546
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    • 2008
  • A study on the selection of an optimal entrainer as the third component among water, aniline, 1,3-diethylbenzene, furfural, and MEK, for the extractive distillation of an azeotropic acetone/methanol system was performed using both the entrainer effect vapor-liquid equilibrium (VLE) and the relative volatility. In the case of water as the entrainer, a VLE curve without azeotropic point in the range of water composition from 0.3 up to 0.7 mole fraction could be obtained by both the experiment and the calculation using modified-UNIFAC model. For aniline and 1,3-diethylbenzene, however, VLE curve without azeotropic point could be obtained only at compositions above 0.7 mole fraction, which exhibited that they could be hardly utilized as the entrainer. Moreover, both furfural and MEK were verified to be improper entrainer since they formed an azeotropic phase. Relative volatility of water showed greater than 1.0 and increased with compositions, while those of the others decreased non-linearly, exhibiting that only water could be utilized as the proper entrainer for the extractive distillation of azeotropic acetone/methanol system.

An Experimental Study on Heat Transfer Characteristics of the Heat Pipe with a Double Vapor Path (이중 증기통로를 가지는 히트파이프의 열전달특성에 관한 실험적 연구)

  • Jun, C.H.;Jang, Y.S.;Kim, O.G.;Noh, I.C.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.2
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    • pp.27-32
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    • 2002
  • The Characteristics of heat transport in the heat pipe with a double vapor path and different kinds of the working fluid were investigated experimentally. The Experiment was carried out with acetone/ethanol. ethanol/ethanol. and in the aluminium container of the double vapor path. Performance measurements can be operated at the high level by 24000 w/m2 heat flux in the 1000mm evaporator. They are each estimated at the high temperature and experimentally reviewed the characteric of the heat rejection. The results shew that they are stably operated under each condition and the fluid was complemented each other at the fluid's experiment and brought about the extention of operating temperature. In this study, The reliable basic data obtained by the teste in the heat pipe with a double vapor path can be used for thermal design, manufacture, and production etc.

Carrier Gas Assisted Solvent Vapor Treatment for Surface Nanostructuring of Molecular Thin Films

  • Gong, Hye-Jin;Kim, Jin-Hyun;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.825-827
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    • 2012
  • In this study, the variation in surface morphology of copper phthalocyanine (CuPc) thin films treated with a flow of acetone vapor assisted by nitrogen carrier gas was investigated. The CuPc nanorods with similar dimensions were well dispersed throughout the whole film surfaces after ~20 min. of treatment. However, the electronic absorption spectra only changed slightly, which indicates that molecular stacking was not altered during treatment. This treating method is simple and more advantageous compared to other solvent treating technologies such as mixed solvent spray treatment using organic solvents and water since it requires relatively mild treating conditions and does not need the presence of water.

흡착제의 세공크기분포에 따른VOCs의 흡${\cdot}$탈착특성

  • Kwon, Jun-Ho;Gu, Kyung-Ran;Gang, Jung-Hwa;Lee, Song-Woo;Na, Young-Su;An, Chang-Duk;Yoon, Young-Sam;Song, Seung-Gu
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.11a
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    • pp.94-96
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    • 2005
  • Acetone vapor흡착에서는 활성탄의 BJH 비표면적과 탈착량을 비교했을때 10${\AA}$이하에서는 다층흡착이 일어나며 그 이상의 세공크기에서는 단층 흡착이 일어나는 것으로 판단된다. 동일한 특성을 가진 MEK vapor흡착에서도 활성탄의 BJH 비표면적과 탈착량을 비교했을때 15 ${\AA}$이하에서는 다층흡착이 일어나며 그이상의 세공크기에서는 단층 흡착이 일어나는 것으로 판단된다. 위 실험을 통해 흡착질의 크기와 흡착제의 세공크기 분포에 Knudsen diffusion의 영역을 고려하여 흡착제를 사용하는 것이 좋은 것으로 판단된다.

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Fabrication and Characterization of Polymer Microlens using Solvent-vapor-assisted Reflow (솔벤트 증기처리 Reflow를 이용한 폴리머 마이크로 렌즈 제작 및 특성고찰)

  • Yang, Seung Woo;Kim, Sin Hyeong;Kim, Bo Hyun;Cho, Young Hak
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.3
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    • pp.299-305
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    • 2015
  • In this paper, we propose a simple and low-cost fabrication method of polymer microlens using solvent-vapor-assisted reflow (SVAR). Metal molds for replication of polymer were fabricated using micro milling and the cylindrical shape of polymer was imprinted using hot-embossing process. The cylindrical shape of polymer was changed to hemispherical lens shape by SVAR. The characteristics of fabricated microlens were evaluated according to the condition of SVAR such as temperature and time. The focal length of polymer microlens could be controlled more easily in low-temperature and long-time condition than in high-temperature and short-time condition. That is, the level of concentrated light to focal point could be improved through the control of temperature and time. Also, we confirmed that toluene was more appropriate solvent than acetone in fabrication of PMMA polymer microlens using SVAR.

Comparison of Surface Characteristics and Adsorption Characteristics of Activated Carbons Changed by Acid and Base Modification (산과 염기의 개질에 의해 변화된 활성탄의 표면특성과 흡착특성 비교)

  • Lee, Song-Woo;Lee, Min-Gyu;Park, Sang-Bo
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.565-571
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    • 2008
  • The surface properties of activated carbon modified by acids and base were studied. The influence of the surface chemistry on the adsorption of benzene and acetone vapor on modified activated carbons has been investigated The modified activated carbons were obtained by treatment with acetic acid ($CH_3COOH$), nitric acid ($HNO_3$) and sodium hydroxide (NaOH). The modified activated carbons had similar porosity but different surface chemistry and adsorption characteristics. The total surface acidity (sum of functional groups) of activated carbon (AC-AN) treated by nitric acid was 2.6 times larger than that of activated carbon (AC) before the acid treatment. Especially, carboxyl group was much developed by nitric acid treatment. The benzene equilibrium adsorption capacity of AC-AN decreased 20% more than that of AC. However, the acetone equilibrium adsorption capacity of AC-AN increased 20% more than that of AC because of the large increase of carboxyl group and acidity.