• Title/Summary/Keyword: Accurate mass measurements

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The Measurements of the Resting Metabolic Rate (RMR) and the Accuracy of RMR Predictive Equations for Korean Farmers (농업인의 휴식대사량 측정 및 휴식대사량 예측공식의 정확도 평가)

  • Son, Hee-Ryoung;Yeon, Seo-Eun;Choi, Jung-Sook;Kim, Eun-Kyung
    • Korean Journal of Community Nutrition
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    • v.19 no.6
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    • pp.568-580
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    • 2014
  • Objectives: The purpose of this study was to measure the resting metabolic rate (RMR) and to assess the accuracy of RMR predictive equations for Korean farmers. Methods: Subjects were 161 healthy Korean farmers (50 males, 111 females) in Gangwon-area. The RMR was measured by indirect calorimetry for 20 minutes following a 12-hour overnight fasting. Selected predictive equations were Harris-Benedict, Mifflin, Liu, KDRI, Cunningham (1980, 1991), Owen-W, F, FAO/WHO/UNU-W, WH, Schofield-W, WH, Henry-W, WH. The accuracy of the equations was evaluated on the basis of bias, RMSPE, accurate prediction and Bland-Altman plot. Further, new RMR predictive equations for the subjects were developed by multiple regression analysis using the variables highly related to RMR. Results: The mean of the measured RMR was 1703 kcal/day in males and 1343 kcal/day in females. The Cunningham (1980) equation was the closest to measured RMR than others in males and in females (males Bias -0.47%, RMSPE 110 kcal/day, accurate prediction 80%, females Bias 1.4%, RMSPE 63 kcal/day, accurate prediction 81%). Body weight, BMI, circumferences of waist and hip, fat mass and FFM were significantly correlated with measured RMR. Thus, derived prediction equation as follow : males RMR = 447.5 + 17.4 Wt, females RMR = 684.5 - 3.5 Ht + 11.8 Wt + 12.4 FFM. Conclusions: This study showed that Cunningham (1980) equation was the most accurate to predict RMR of the subjects. Thus, Cunningham (1980) equation could be used to predict RMR of Korean farmers studied in this study. Future studies including larger subjects should be carried out to develop RMR predictive equations for Korean farmers.

A Study on the Concentration Characteristics of Atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) in Chongju

  • Lee, Hak-Sung;Kang, Byung-Wook;Kwon, Dong-Hyuk;Yeo, Hyun-Gu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E2
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    • pp.89-97
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    • 2003
  • Ambient polycyclic aromatic hydrocarbons (PAHs) were measured during the winter and summer of 2002 in Chongju. A filter pack and polyurethane foam (PUF) system was employed to collect simultaneously the particulate and gas phase PAHs. The samples were then analyzed using a gas chromatograph equipped with mass spectrometer detectors (GC/MSD). A total of 29 samples were collected and 11 PAH species were identified. The lower molecular weight PAH compounds (3∼4 rings) dominated the total PAH mass. The higher molecular weight PAH compounds (5∼6 rings) were less abundant. The PAHs were showed to exhibit seasonal variations. The concentrations of all com-pounds were significantly higher in winter than summer. The lower molecular weight PAHs were mostly found in the gas phase whereas the heavier ones were mainly associated with particulate phase. Vehicle emissions are likely to be the primary contributor of PAHs in Chongju. This study also demonstrated that it is necessary to perform simultaneously particulate and gas phase measurements to determine the accurate concentrations of ambient PAHs.

Theoretical and Experimental 31P NMR and ESI-MS Study of Hg2+ Binding to Fenitrothion

  • Koo, In-Sun;Ali, Dildar;Yang, Ki-Yull;vanLoon, Gary W.;Buncel, Erwin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1257-1261
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    • 2009
  • We present the theoretical and experimental results of $^{31}P$ NMR and low energy CID MS/MS study of $Hg^{2+}$ binding to fenitrothion (FN). The calculated $^{31}P$ NMR chemical shifts order for FN with $Hg^{2+}$ complex is in good agreement with experimental $^{31}P$ NMR chemical shifts order. The experimental and theoretical $^{31}P$ NMR study of organophosphorus pesticide with $Hg^{2+}$ gives to important information for organophosphorus pesticide metal complexes. ESI-MS and low energy CID MS/MS experiments of $Hg^{2+}$-FN complexes combined with accurate mass measurements give insight into the metal localization and allow unambiguous identification of fragments and hydrolysis products.

Evaluation of Pressure Drop in a Circular Pipe of Refuse Collecting System (쓰레기 관로이송 시스템에서의 관로 압력손실 평가)

  • Kim, Dong-Woo;Jang, Choon-Man
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2615-2620
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    • 2007
  • This paper describes on pressure drop in a circular pipe of refuse collecting system. The flow characteristics inside the circular pipe are analyzed by three-dimensional Navier-Stokes analysis. In numerical analysis, an organic waste is modeled using the data obtained by site survey. Pressure drop obtained by numerical simulation is compared to the value obtained by experimental measurements for the two kinds of pipe; straight and bended type. The pressure drop obtained by numerical simulation has a good agreement with that of experiments. It is noted that the accurate prediction of pressure drop in the waste pipe is very important to determine the performance of turbo blower used in making a suction pressure in the waste pipe. Especially, the pressure drop for an organic waste is analyzed according to the mass flow rate of waste.

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Development of a Dynamically Scaled Model of the Catenary for High Speed Railway (고속전철 가선계의 축소모델 개발에 관한 연구)

  • Kim, Jung-Soo
    • Journal of the Korean Society for Railway
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    • v.10 no.4
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    • pp.409-413
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    • 2007
  • A dynamically scaled model of the catenary with a nominal scaling factor of 18.5:1 is designed and constructed. The motivation for developing such a model is the great difficulty of making accurate measurements on the full-scale catenary and the difficulty of making experimental modifications to it. The scaled model is designed to be dynamically equivalent to the full scale catenary with respect to the mass and elastic strength. The scaled model is partially verified by comparing linear vibration and wave characteristics with those predicted by the simulation study.

Effects of Heat Shock Treatment on Enzymatic Proteolysis for LC-MS/MS Quantitative Proteome Analysis

  • Arul, Albert-Baskar;Han, Na-Young;Jang, Young-Su;Kim, Hyojin;Kim, Hwan-Mook;Lee, Hookeun
    • Mass Spectrometry Letters
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    • v.7 no.1
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    • pp.1-11
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    • 2016
  • Various efforts have been developed to improve sample preparation steps, which strongly depend on hands-on processes for accurate and sensitive quantitative proteome analysis. In this study, we carried out heating the sample prior to trypsin digestion using an instrument to improve the tryptic digestion process. The heat shock generated by the system efficiently denatured proteins in the sample and increased the reproducibility in quantitative proteomics based on peptide abundance measurements. To demonstrate the effectiveness of the protocol, three cell lines (A human lung cancer cell line (A549), a human embryonic kidney cell line (HEK293T), and a human colorectal cancer cell line (HCT-116)) were selected and the effect of heat shock was compared to that of normal tryptic digestion processes. The tryptic digests were desalted and analysed by LC-MS/MS, the results showed 57 and 36% increase in the number of identified unique peptides and proteins, respectively, than conventional digestion. Heat shock treated samples showed higher numbers of shorter peptides and peptides with low inter-sample variation among triplicate runs. Quantitative LC-MS/MS analysis of heat shock treated sample yielded peptides with smaller relative error percentage for the triplicate run when the peak areas were compared. Exposure of heat-shock to proteomic samples prior to proteolysis in conventional digestion process can increase the digestion efficiency of trypsin resulting in production of increased number of peptides eventually leading to higher proteome coverage.

THM analysis for an in situ experiment using FLAC3D-TOUGH2 and an artificial neural network

  • Kwon, Sangki;Lee, Changsoo
    • Geomechanics and Engineering
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    • v.16 no.4
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    • pp.363-373
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    • 2018
  • The evaluation of Thermo-Hydro-Mechanical (THM) coupling behavior is important for the development of underground space for various purposes. For a high-level radioactive waste repository excavated in a deep underground rock mass, the accurate prediction of the complex THM behavior is essential for the long-term safety and stability assessment. In order to develop reliable THM analysis techniques effectively, an international cooperation project, Development of Coupled models and their Validation against Experiments (DECOVALEX), was carried out. In DECOVALEX-2015 Task B2, the in situ THM experiment that was conducted at Horonobe Underground Research Laboratory(URL) by Japan Atomic Energy Agency (JAEA), was modeled by the research teams from the participating countries. In this study, a THM coupling technique that combined TOUGH2 and FLAC3D was developed and applied to the THM analysis for the in situ experiment, in which rock, buffer, backfill, sand, and heater were installed. With the assistance of an artificial neural network, the boundary conditions for the experiment could be adequately implemented in the modeling. The thermal, hydraulic, and mechanical results from the modeling were compared with the measurements from the in situ THM experiment. The predicted buffer temperature from the THM modelling was about $10^{\circ}C$ higher than measurement near by the overpack. At the other locations far from the overpack, modelling predicted slightly lower temperature than measurement. Even though the magnitude of pressure from the modeling was different from the measurements, the general trends of the variation with time were found to be similar.

The Measurements of Vibration Displacement of the Piezoelectric Exciter Using Mach-Zehnder Optical Fiber Interferometer (Mach-Zehnder 광섬유 간섭계를 이용한 압전형 진동발생기의 동특성 조사)

  • Cho, Seung-Il;Kim, Sung-Boo;Lee, Jong-Kyu;Lee, Yong-Bong;Lee, Doo-Hee
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.16 no.10 s.115
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    • pp.1044-1049
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    • 2006
  • The vibration exciter with the accurate calibration requires a low distortion along a single axis over a wide range of frequency. The fabricated piezoelectric exciter was composed of a base, piezoelectric element(Venitron PZT 5A), electrode and seismic mass. Its performance characteristics is evaluated the Mach-Zehnder optical fiber interferometer. The phase of the optical wave passing through the optical fiber around the piezoelectric element was related the vibrational amplitude with a change of the applied sinusoidal voltage on the piezoelectric element. The dynamic characteristics of vibration exciter can be obtained by measuring the vibrational amplitude with a sinusoidal applied voltage on the piezoelectric element. The sensitivity of the fabricated piezoelectric exciter had a 0.4 nm/V which was uniform up to 20 kHz.

Estimation of damping induced by taut mooring lines

  • Xiong, Lingzhi;Lu, Wenyue;Li, Xin;Guo, Xiaoxian
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.810-818
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    • 2020
  • A moored floating structure may exhibit resonant motion responses to low-frequency excitations. Similar to the resonant responses of many vibration systems, the motion amplitude of a moored floating structure is significantly affected by the damping of the entire system. In such cases, the damping contributed by the mooring lines sometimes accounts for as much as 80% of the total damping. While the damping induced by catenary mooring lines is well-investigated, few studies have been conducted on the damping induced by taut mooring lines, especially one partly embedded in soil. The present study develops a simple but accurate model for estimating the damping contributed by mooring lines. A typical type of taut mooring line was used as the reference and the hydrodynamic drag force and soil resistance were taken into consideration. The proposed model was validated by comparing its predictions with those of a previously developed model and experimental measurements obtained by a physical model. Case studies and sensitivity studies were also conducted using the validated model. The damping induced by the soil resistance was found to be considerably smaller than the hydrodynamic damping. The superposition of the wave frequency motion on the low-frequency motion was also observed to significantly amplify the damping induced by the mooring lines.

A Search for Exoplanets around Northern Circumpolar Stars. VII. Detection of Planetary Companion Orbiting the Largest Host Star HD 18438

  • Byeong-Cheol Lee;Jae-Rim Koo;Gwanghui Jeong;Myeong-Gu Park;Inwoo Han;Yeon-Ho Choi
    • Journal of The Korean Astronomical Society
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    • v.56 no.1
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    • pp.35-40
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    • 2023
  • We have been conducting a exoplanet search survey using Bohyunsan Observatory Echelle Spectrograph (BOES) for the last 18 years. We present the detection of exoplanet candidate in orbit around HD 18438 from high-precision radial velocity (RV) mesurements. The target was already reported in 2018 (Bang et al. 2018). They conclude that the RV variations with a period of 719 days are likely to be caused by the pulsations because the Lomb-Scargle periodogram of HIPPARCOS photometric and Hα EW variations for HD 18438 show peaks with periods close to that of RV variations and there were no correlations between bisectors and RV measurements. However, the data were not sufficient to reach a firm conclusion. We obtained more RV data for four years. The longer time baseline yields a more accurate determination with a revised period of 803 ± 5 days and the planetary origin of RV variations with a minimum planetary companion mass of 21 ± 1 MJup. Our current estimate of the stellar parameters for HD 18438 makes it currently the largest star with a planetary companion.