• Title/Summary/Keyword: Accelerated Aging

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The Effect of Alum and Metals on Paper Aging

  • Choi, Kyoung-Hwa;Yoon, Byung-Ho;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.5
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    • pp.42-46
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    • 2008
  • The papers in preserved books and archives experience aging which was affected by a variety of factors. Thus, the studies concerning impacts of those factors on paper aging are required. In this research, a simulation of a short-time accelerated paper aging was conducted in order to examine the effects of acid and metals (alum, copper (II) sulfate, copper (II) chloride, and iron (III) chloride) on the natural paper aging for a long time. As a result of experiments, it is found that both acid and metals have impacts on paper aging. Alum resulted in the significant decrease of pH, brightness, folding endurance, and viscosity of paper. Both copper (II) chloride and iron (III) chloride also resulted in the decrease of brightness, folding endurance, and viscosity of paper. In more detail, paper aging by iron (III) chloride showed much more significant than that by copper (II) chloride. The paper aging in case of copper (II) sulfate coexisting sulfate ion, where metal absorbed moisture was higher than in case of paper treated only by alum. This result indicated that metal catalyzes paper aging by acid. Based on these results, it was revealed that both alum and metal are the major factors in paper aging. In particular, paper aging was far more accelerated in case when acid and metals existed in paper at the same time.

Effect of Sintering Temperature on Electrical and Dielectric Behavior of Pr6O1-Based ZnO Varistors with DC Accelerated Aging Stress (Pr6O1계 ZnO 바리스터의 DC 가속열화 스트레스에 따른 전기적, 유전적 거동에 미치는 소결온도의 영향)

  • 남춘우;정영철;김향숙
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.3
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    • pp.244-252
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    • 2002
  • The electrical and dielectric behavior fort DC accelerated aging stress of P $r_{6}$ $O_{11}$-based Zno varistors cnsisting of ZnO-P $r_{6}$ $O_{11}$-CoO-C $r_2$ $O_3$-E $r_2$ $O_3$ were investigated with sintering temperature in the range of 1325~1345$^{\circ}C$. The varistor ceramics with increasing sintering temperature were more densified. A more densified varistors leaded to high stability for DC accelerated aging stress. Furthermore, the stability for DC accelerated aging stress was increased with the leakage current and dtan $\delta$/dV decreasing in order of 1325longrightarrow1335longrightarrow1345longrightarrow134$0^{\circ}C$ in sintering temperature. It was found that the stability for DC stress is affected more greatly by the leakage current and dtan $\delta$/dV than the densification. It is considered that the stability of varistors for DC stress can be estimated by considering the factors, such as the densification, leakage current, and dtan $\delta$/dV. As a result, the varistor sintered at 134$0^{\circ}C$ exhibited the highest stability, with %$\Delta$ $V_{lmA}$=-1.54%, %$\Delta$$\alpha$=-2.49%, %$\Delta$ $I_{\ell}$=+240.68%, 5%$\Delta$tan$\delta$=+29.96%.96%.96%.%.

Effect of Humid Cycling Accelerated Aging on Deterioration of Duplicated Beeswax-Treated Volume (밀랍본 시제품의 습식 순환인공열화 특성분석)

  • Choi, Kyoung-Hwa;Park, Ji-Hee;Jeong, Hye-Young;Seo, Jin-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.4
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    • pp.15-24
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    • 2010
  • Many efforts to understand the deterioration processes of the beeswax-treated volume of "The Annals of Joseon Dynasty" have been made. However, most previous studies have focused on individual sample sheet of the beeswax-treated paper but not book volume format. In this study, humid cycling accelerated aging for duplicated beeswax-treated book volume and Hanji book volume were carried out to examine differences in the deterioration of different parts of each volume as well as between the two book volumes during the aging. As results, it is found that the deterioration rate for the beeswax-treated volume is higher than that for the Hanji book volume. Different parts in each volume show different magnitude of deterioration. In particular, outer sides in both beeswax-treated and Hanji book volumes, which are directly exposed to the air, are deteriorated more seriously than inner sides. It is also observed that inner sides are considerably deteriorated during the aging, implying that inner deterioration may have different mechanisms from outer deterioration.

Accelerated Life Prediction of CPB(cold-pad-batch) Padder Roll Rubber to Chemical Degradation (CPB(Cold-Pad-Batch) 염색 패더롤 고무에서 화학적 노화로 인한 가속 수명예측)

  • Lim, Jee Young;Nam, Chang Woo;Lee, Woosung
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.155-161
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    • 2017
  • In CPB(Cold-Pad-Batch) dyeing, the rubber of the padder roll is influenced by the heat, chemical and mechanical influences and thus aging of the padder roll rubber occurs. This study presents an accelerated thermal aging test of the CPB padder roll rubber with strong alkali conditions. Using Arrhenius formula of the various property values for the various aging temperatures($80^{\circ}C$, $90^{\circ}C$, $100^{\circ}C$) of the padder roll, the accelerated life predictions could be calculated. The threshold value of the property was set at different values. The hardness was set at the point where 5% degradation occurs based on the actual use conditions, and the tensile strength was set at the point where 50% degradation occurs based on the general life prediction standards. From the results of the different physical properties at differing temperatures, the Arrhenius plot could be obtained. Through the usage of the Arrhenius Equation, significant duration expectation could be predicted, and the chemical aging behavior of the CPB padder roll could be found at the arbitrary and actual temperatures.

Properties of Electrical Performance on Stator Coil of Traction Motor by Accelerated lest using Transient Surge (과도서지를 이용한 가속열화 시험법에 따른 견인전동기 고정자 코일의 전기적 특성 변화)

  • 박현준;장동욱;이길헌;최종선;김저우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.783-789
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    • 2003
  • The winding problems of traction motor are the major determinant of motor's life. The root cause of winding failure is gradual deterioration of the insulation due to thermal, electrical, mechanical and environmental stresses. The aging of the insulation reduces the electrical and mechanical strength of the insulation. At same point, a voltage surge or mechanical shock from a traction motor start will fracture or break down the insulation. To achieve the expected life usually requires extensive laboratory evaluation of the insulation systems and the use of accelerated aging tests. There are several nondestructive test available for checking, the condition of motor insulation, the probable extent of aging, and the rate of which aging is taking place. So the insulation characteristics of stator coil were each analyzed by measurement of dielectric loss(tan$\sigma$), capacitance and partial discharge. The method of diagnosis is able to analyze the insulation condition and evaluate the life of the traction motor.

Analysis of Insulation Aging Mechanism in Generator Stator Windings (발전기 고정자 권선의 절연열화 메카니즘 분석)

  • 김희동
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.119-126
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    • 2002
  • The mica/epoxy composite used in generator(rated 22 kV and 500 MW) stator windings was aged at 180$\^{C}$ for up to 1000 hours in air and hydrogen. The degradation mechanism was investigated through the defect of evolution and microstructural analysis by performing SEM(Scanning Electron Microscope). As the thermal aging time increases, the number of voids per unit volume increases at the mica/epoxy interface of generator stator windings. The aged specimens in hydrogen showed retarded generation and growth of voids. Accelerated aging tests were conducted using the combination of thermal and electrical aging in air and hydrogen. The aging was carried out at a combined stress such as thermal aging at 110$\^{C}$, electrical aging at 5.5 kV/mm and frequencies 420 Hz in air, and electrical aging at 5.5 kV/mm and frequencies 420 Hz in hydrogen (pressure 4 kg/㎠). Thermal and electrical aging generates large voids at the mica/epoxy interface in air. Electrical aging in hydrogen also generates small voids, delaminations and cracks in mica tapes.

Accelerated Aging Characteristics of a Double Base Propellant (복기추진제의 가속 노화 특성 연구)

  • Go, Cheongah;Park, Youngchul;Seo, Taeseok;Moon, Youngtaek;Kim, Junhyung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.4
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    • pp.61-69
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    • 2019
  • Accelerated aging test for the double base propellant was carried out at three different temperatures (60, 70, and $75^{\circ}C$) for over a year. To evaluate the aging characteristics of the double base propellant, the stabilizer contents and thermal decomposition kinetics were analyzed by using high performance liquid chromatography (HPLC) and AKTS-Thermokinetics software. As a result, stabilizer contents in the double base propellant gradually decreased according to the aging temperature and aging duration. The consumption rate of 2-NDPA in the accelerated aged propellants showed that it was two times faster at $75^{\circ}C$ in compared with ther rate at $70^{\circ}C$. These experimental values were simulated by the SB kinetic model, and it was shown that the two-step model with constant reaction orders n1=1 and n2=0 best describes the process of the stabilizer depletion for the double base propellant.

Effects of Dried Days on Properties of Seawater and Freshwater Flooded CSPE in NPPs

  • Jeon, Hwang-Hyun;Lee, Jeong-U;Jeon, Jun-Soo;Lee, Seung-Hoon;Shin, Yong-Deok
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1162-1168
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    • 2015
  • Accelerated thermal aging of chlorosulfonated polyethylene (CSPE) was performed for 0 days, 80.82 days, and 161.63 days at 100℃, which is equivalent to 0 y, 40 y, and 80 y of aging, respectively, at 50℃. After freshwater flooding, the volume electrical resistivity of CSPE was highest after 180 days of drying, and its insulating property recovered when dried for more than 300 days. The dielectric constant of the CSPE was not measured after seawater flooding. The dielectric constant of the accelerated thermally aged CSPE was higher after freshwater flooding than that before seawater flooding. The bright, open pores of CSPE were converted into dark, closed pores after seawater flooding, and the dark, closed pores of the accelerated thermally aged CSPE samples were partly converted into bright, open pores after freshwater flooding. The apparent density of CSPE increased slightly whereas its elongation at break (EAB) decreased until 80 y of accelerated thermal aging before seawater flooding. The peak binding energies of oxygen in the non-accelerated and accelerated thermally aged CSPE for 40 y and 80 y were shifted by more than 1.0 eV after seawater and freshwater flooding. The CH2 content in the non-accelerated and accelerated thermally aged CSPE for 40 y and 80 y after seawater flooding for 5 days was lower than that before seawater flooding whereas atoms such as Cl, O, Pb, Al, Si, Sb, and S that are related to conducting ions such as Na+, Cl-, Mg2+, SO4 2-, and K+ were relatively increased.

Effect of Accelerated Aging on the Color Stability of Dual-Cured Self-Adhesive Resin Cements

  • Kim, Ah-Rang;Jeon, Yong-Chan;Jeong, Chang-Mo;Yun, Mi-Jung;Huh, Jung-Bo
    • Journal of Korean Dental Science
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    • v.8 no.2
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    • pp.49-56
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    • 2015
  • Purpose: The effect of accelerated aging on color stability of various dual-cured self-adhesive resin cements were evaluated in this study. Materials and Methods: Color stability was examined using three different brands of dual-cured self-adhesive resin cements: G-CEM LinkAce (GC America), MaxCem Elite (Kerr), and PermaCem 2.0 (DMG) with the equivalent color shade. Each resin cement was filled with Teflon mold which has 6 mm diameter and 2 mm thickness. Each specimen was light cured for 20 seconds using light emitting diode (LED) light curing unit. In order to evaluate the effect of accelerated aging on color stability, color parameters (Commission Internationale de l'Eclairage, CIE $L^*$, $a^*$, $b^*$) and color differences (${\Delta}E^*$) were measured at three times: immediately, after 24 hours, and after thermocycling. The $L^*$, $a^*$, $b^*$ values were analyzed using Friedman test and ${\Delta}E^*$ values on the effect of 24 hours and accelerated aging were analyzed using t-test. These values were compared with the limit value of color difference (${\Delta}E^*=3.7$) for dental restoration. One-way ANOVA and Scheff's test (P<0.05) were performed to analyze each ${\Delta}E^*$ values between cements at each test period. Result: There was statistically significant difference in comparison of color specification ($L^*$, $a^*$, $b^*$) values after accelerated aging except $L^*$ value of G-CEM LinkAce (P<0.05). After 24 hours, color difference (${\Delta}E^*$) values were ranged from 2.47 to 3.48 and $L^*$ values decreased and $b^*$ values increased in all types of cement and MaxCem Elite had high color stability (P<0.05). After thermocycling, color change's tendency of cement was varied and color difference (${\Delta}E^*$) values were ranged from 0.82 to 2.87 and G-CEM LinkAce had high color stability (P<0.05). Conclusion: Color stability of dual-cured self-adhesive resin cements after accelerated aging was evaluated and statistically significant color changes occurred within clinically acceptable range.

Clamping Voltage Characteristics and Accelerated Aging Behavior of CoCrTb-doped Zn/Pr-based Varistors with Sintering Temperature

  • Nahm, Ghoon-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.125-130
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    • 2009
  • The clamping voltage characteristics and accelerated aging behavior of CoCrTb-doped Zn/Pr-based varistors were investigated for different sintering temperatures. The best clamping voltage characteristics were obtained for the varistors sintered at $1330^{\circ}C$, with a clamping voltage ratio (K) of 1.63 at a surge current of 5 A and 1.75 at a surge current of 10 A. The varistors sintered at $1330^{\circ}C$ exhibited the highest stability, with -0.1% in $%{\Delta}E_{1\;mA}$, -0.2% in $%{\Delta}{\alpha}$, and +15.5% in $%{\Delta}J_L$ for E-J characteristics under a stress state of 0.90 $E_{1\;mA/120^{\circ}C$ /24 h. Furthermore, it exhibited $%{\Delta}{\varepsilon}_{APP}$' of -0.7% and $%{\Delta}tan{\delta}$ of +5.7% for dielectric characteristics under the same stress state.