• Title/Summary/Keyword: Absorption performance

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Neutron Shielding Performance of Mortar Containing Synthetic High Polymers and Boron Carbide (합성 고분자 화합물 및 탄화붕소 혼입에 따른 모르타르의 중성자 차폐성능 분석)

  • Min, Ji-Young;Lee, Bin-Na;Lee, Jong-Suk;Lee, Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.28 no.2
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    • pp.197-204
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    • 2016
  • Concrete walls of neutron generating facilities such as fusion reactors and fission reactors become radioactive by neutron irradiation. Both low-activation and neutron shielding are a critical concern at the dismantling stage after the shutdown of facilities with a requirement of radioactive waste management. To tackle this, two types of additives were investigated in fabricating mortar specimens: synthetic high polymers and boron carbide. It is well known that a hydrogen atom is effective in neutron shielding by an elastic scattering because its mass is almost the same as that of the neutron. And boron is an effective neutron absorber with a big neutron absorption cross section. In this study, the effect of the type, shape, and size of polymers were investigated as well as that of boron carbide. Total 16 mix designs were prepared to reveal the effect of polymers on mechanical properties and neutron shielding performance. The neutron does equivalent of polymers-based mortar for fast neutrons decreased by 36 %, and the count rate of boron carbide-based mortar with regard to thermal neutrons decreased by 90 % compared to conventional mortar. These results showed that a combination of polymers and boron carbide compounds has potential to reduce the thickness of neutron shields as well as radioactive waste from reactors.

The Properties of Durability and Strength of Fiber-Reinforced Polymer-Modified Mortars Using Eco-Friendly UM Resin (친환경 UM수지를 사용한 섬유보강 폴리머 시멘트 모르타르의 내구성 및 강도 특성)

  • Kwon, Min-Ho;Seo, Hyun-Su;Lim, Jeong-Hee;Kim, Jin-Sup
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.313-320
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    • 2013
  • In this study, performance of fiber-reinforced polymer-modified mortar was studied for the development of eco-friendly materials for high performance repair and reinforcement. The general cement mortar and eco-friendly UM resin was mixed with a certain percentage for increased durability. To increase the strength of the polymer-modified mortar, PVA fiber, steel fiber and hybrid fiber were added at a constant rate. Hybrid fiber is contains the same percentage of PVA fiber and steel fiber. In order to determine the strength properties of fiber-reinforced polymer-modified mortar, the compressive strength test, the splitting tensile strength test and the flexural strength test were performed. And, in order to determine the durability properties of fiber-reinforced polymer-modified mortar, water absorption test and chemical resistance test were performed. From the experimental results, polymer-modified mortar using UM resin was improved durability. And the tensile strength and flexural strength increased, which were the vulnerability of fiber reinforced polymer-modified mortar. From this study, fiber-reinforced polymer-modified mortar using eco-friendly UM resin can be used to repair and reinforcement for the external exposure of concrete structures to improve the durability.

Quality Evaluation of Commercial Extruded Pellet Diet for Olive Flounder, Paralichtys olivaceus (시판 넙치용 배합사료의 품질평가)

  • JI Seung Cheol;MOON Gyeong Su;YOO Jin Huyng;LEE Si Woo;KIM Hong Beom;JEONG Gwan Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.5
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    • pp.291-297
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    • 2005
  • This study evaluated the quality of commercial extruded pellet (EP) diet of five companies (A, B, C, D and E) for olive flounder Paralichtys olivaceus by biochemical analyses, physical properties and growth performance. The proximate analyses of five EP diets showed $3.2-10.0\%$ of moisture, $49.3-55.5\%$ of crude protein, $4.6-14.7\%$ of crude lipid, $7.0-13.8\%$ of crude ash, $0.7-10.5\%$ of crude fiber, $10.0-27.3\%$ of itrogen free extract (NFE), 304.3-395.4kcal/100g of digestible energy (DE) and 6.1-7.1 of calorie/protein ratio (C/P). Peroxide value (POV) was highest in diet D (47.4 meq/kg) as compared to other diets which in the range of 4.0-11.7 meq/kg. Total amino acid contents were ranged from 46.54 to $55.46\%$ with the highest content in diet B and the lowest content in diet C. Essential amino acid of diet C was lowest $(7.43\%)$ as compared to other diets which in the range of $19.43-20.30\%$. Saturated fatty acid was higher in diet A $(37.65\%)$ followed by diet B $(36.32\%)$, diet E$(34.39\%)$, diet C$(30.95\%)$ and diet D$(30.10\%)$. EPA+DHA were highest in diet E$(30.78\%)$ and lowest in diet C$(15.48\%)$. The floating rate after 6 hours on the sea water was highest in diet C$(100\%)$ followed by diet B$(40\%)$ and A$(10\%)$. However, diets D and E were completely settled down after 1 and 2 hours, respectively. The range of relative expansion rate was $27.2-49.3\%$ for all diets and all reached the peak at 2-3 hours. The water absorption rate of diets C and D was lowest, and diet E was highest at 1 hour after deposition of sea water. Growth rate was higher in diet B$(22.3\%)$ and E$(21.3\%)$. Feed efficiency was higher in diet A$(109.7\%)$ and E$(105.3\%)$ and was significantly lowest in diet D$(80.7\%)$. The protein efficiency ratio was highest in diet E (2.72) and lowest in diet D (1.76). These results suggest that there is a necessity for improvement of nutrients balance and feed physical properties to fulfill the nutrient requirements and digestive characteristics of fishes in commercial EP diets.

The effect of heat input and PWHT on the mechanical properties and microstructure of HSB600 steel weldments with GMAW (HSB600강 가스메탈아크용접부에서 입열량과 용접후 열처리가 기계적 특성과 미세조직에 미치는 영향)

  • Ju, Dong-Hwi;Jang, Bok-Su;Lim, Young-Min;Koh, Jin-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.5
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    • pp.1939-1946
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    • 2012
  • High performance steel for bridges requires higher performance in tensile and yield strength, toughness, weldability, etc. The purpose of this study is to investigate the weldability of HSB 600 steel. The effects of heat input (1.4~3.2kJ/mm) and postweld heat treatment (PWHT, $600^{\circ}C$, 40hr.) on the TMCP HSB600 steel weldments made by GMAW process were investigated. The tensile strength and hardness of as-welded specimens decreased with increasing heat input. Charpy V-notch impact energy did not show any significant difference by postweld heat treatment. The fine-grained acicular ferrite was mainly formed in the 2.1kJ/mm of heat input while polygonal and side plate ferrites were dominated in the high inputs. Meanwhile, tensile strength and hardness of PWHT weldments decreased due to the coarsening and globularization of ferrite microstructure and reduction of residual stresses with increasing heat inputs. However, there was no significant difference in the impact energy absorption.

The Method for Evaluating Unsaturated Hydraulic Conductivity of the Bentonite-buffer Using Relative Humidity (상대습도를 이용한 벤토나이트 완충재의 불포화 수리전도도 평가방안)

  • Lee, Hang-Bok;Kim, Jin-Seop;Choi, Young-Chul;Choi, Heui-Joo;Kim, Kyungsu
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.69-77
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    • 2014
  • Unsaturated hydraulic conductivity of the bentonite-buffer was evaluated using the relative humidity data. The method for calculating unsaturated hydraulic conductivity was deduced from the general analytical equation representing the movement of water in unsaturated media, which was applied to the experimental results of water infiltration tests for identifying the behavior of unsaturated hydraulic conductivity according to the water saturation. Unlike the saturated condition, the hydraulic gradient and water flux were irregularly changed, and the unsaturated hydraulic conductivity was increased with increasing the experimental time. Swelling of bentonite grains due to the water absorption increased the volume and size of pore within bentonite, resulting in the increase of water velocity and unsaturated hydraulic conductivity. This result suggested the necessity of further investigation on the correlation between the swelling degree of bentonite-buffer and unsaturated hydraulic conductivity. The method used in this study can be useful technique for evaluating long-term hydraulic performance of bentonite-buffer in the radioactive waste disposal system.

High-Performance Liquid Chromatographic Determination of Phenothrin and Silafluofen Residues in Crops with Mass Spectrometric Confirmation (고성능 액체크로마토그래피와 질량분석법을 이용한 농산물 중 Phenothrin 및 Silafuofen의 정밀 잔류분석법 개발)

  • Lee, Young-Deuk;Oh, Jae-Ho;Jang, Sang-Won
    • The Korean Journal of Pesticide Science
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    • v.15 no.4
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    • pp.389-400
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    • 2011
  • A high-performance liquid chromatographic (HPLC) method was developed to determine residues of phenothrin and silafluofen, known as synthetic pyrethroids, in agricultural commodities. Insecticide residues were extracted with acetone from representative samples of four crops which comprised rice, apple, pepper and cabbage. The extract was purified serially by liquid-liquid partition and Florisil column chromatography. For rice and pepper samples, acetonitrile/n-hexane partition was additionally adopted to remove nonpolar interferences. Reversed phase HPLC using an octadecylsilyl column was successfully applied to separate two phenothrin isomers and silafluofen from sample co-extractives. Intact parent compounds were sensitively detected by ultraviolet absorption at 226 nm. Recovery experiment at the quantitation limit validated that the proposed method could apparently determine phenothrin and silafluofen residues at 0.02 and 0.01 mg/kg, respectively. Mean recoveries of phenothrin and silafluofen from four crop samples fortified at three levels in triplicate were in the range of 82.4~109.8% and 83.7~109.8%, respectively. Relative standard deviations of the analytical method were all less than 10%, irrespective of crop types and spiking levels. A selected-ion monitoring (SIM) LC/mass spectrometry (MS) with electrospray ionization was provided to confirm the suspected residue of phenothrin, even though no sufficient ionization of silafluofen was obtained. Both phenothrin and silafluofen could be successfully confirmed by gas chromatography/MS SIM with electron impact at 70 eV. The proposed method is sensitive, repeatable and rapid enough to apply to officially routine inspection of agricultural products.

Physiological Response and Growth Performance of Parasenecio firmus under Different Shading Treatments (차광처리에 따른 병풍쌈의 생리반응 및 생장특성)

  • Lee, Kyeong-Cheol;Lee, Hak-Bong;Park, Wan-Geun;Han, Sang-Sup
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.79-89
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    • 2012
  • This study was conducted to investigate the chlorophyll contents, photosynthetic characteristics, chlorophyll fluorescence, and growth performance of Parasenecio firmus under changing light environment. Parasenecio firmus was grown under non-treated (full sunlight) and three different shading conditions (88~93%, 65~75% and 45%~55% of full sunlight) for the experiment. Total chlorophyll content, photochemical efficiency (Fv/Fm), T/R ratio, specific leaf area (SLA), leaf area ratio (LAR), and leaf weight ratio (LWR) were increased with increasing shading level, but decreased dark respiration. Therefore, light absorption and light utilization efficiency were improved under the low intensity light. Plants under 65~75% of full sunlight had best maximum photosynthetic rate and net apparent quantum yield in May. On the other hand, the non-treated plants had lower maximum photosynthetic rate, photochemical efficiency, and chlorophyll content than the treated ones. Parasenecio firmus considered to be a sciophyte, is fairly sensitive to high intensity light. If 88-93% of full sunlight lasts for a long period, photosynthetic capacity will be sharply decreased, though limiting light. These results suggest that growth of Parasenecio firmus adapted to 65~75% of full sunlight.

An Experimental Study on the Performance of RC Beam according to the Rapid Freezing and Thawing Test Method in the Air (기중 급속 동결 융해 시험 방법에 따른 철근콘크리트 보의 성능 실험 연구)

  • Kim, Sang-Woo;Lee, Dong-Ju;Kim, Kyeong-Min;Kim, Jin-Sup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.4
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    • pp.46-55
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    • 2021
  • Concrete structures can cause various problems as the number of common years increases when exposed to external extreme climate conditions. Among these problems, freezing and thawing occur due to the action of extreme climate factors such as heavy rain and heavy snow, which have become the most problematic in recent years. In this study, we present a rapid freezing and thawing test method of concrete in the air, referring to KS F 2456, as Seoul exhibits very dry weather during the period of freezing and thawing. Concrete test specimens and RC beams were fabricated to perform rapid freezing and thawing of 0, 100, 200, and 300 cycles, and the performance evaluation confirmed the degradation of each subject in material and member units. The design strength of 24 MPa, which performs rapid freezing and thawing in the air up to 300 cycles, decreases by 5.24 MPa (21%), and as rapid freezing and thawing in the air increases the stress burden on reinforced concrete bending members, reducing the energy absorption (dissipation) ability of structures due to earthquakes.

Effects of Shading Treatments on Growth and Physiological Characteristics of Aruncus dioicus var. kamtschaticus (Maxim.) H. Hara Seedling (차광처리가 눈개승마 유묘의 생장 및 생리적 특성에 미치는 영향)

  • Lee, Kyeong Cheol;Han, Sang Kyun;Kwon, Young Hyoo;Jeon, Seong Ryeol;Lee, Chang Woo;Seo, Dong Jin;Park, Wan Geun
    • Korean Journal of Medicinal Crop Science
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    • v.27 no.1
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    • pp.30-37
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    • 2019
  • Background: This study was conducted to investigate the changes in the photosynthetic parameters, chlorophyll content, chlorophyll fluorescence, and growth characteristics of Aruncus dioicus var. kamtschaticus seedlings under different shading treatments. Methods and Results: The shading treatment was regulated with the shading level (non-shaded, 35%, 55%, and 75% shading). Photosynthetic activities, such as net photosynthetic rate, stomatal conductance, stomatal transpiration rate, and performance index on absorption basis ($PI_{ABS}$)were the highest under 35% shading ($4.36{\mu}mol\;CO_2{\cdot}m^{-2}{\cdot}s^{-1}$, $54.2mmol\;H_2O{\cdot}m^2{\cdot}s^{-1}$, $0.66mmol\;H_2O{\cdot}m^{-2}{\cdot}s^{-1}$, and 1.3, respectively), and the lowest under 75% shading. This implies that the decrease in net photosynthetic rate may be due to an inability to regulate water and $CO_2$ exchanged through the stomata. Thechlorophylla, b, and a + b contents were increased with elevating shading level and the chlorophyll a/b ratio showed non-significant differences. It was found that the dry weight (leaf, shoot, and whole) was the highest (1.14 g, 0.49 g, and 2.31 g, respectively) under 35% shading and the t/R ratio was the highest under 75% shading. Conclusions: It is concluded that 75% shading exhibited a strong reduction of photosynthetic activity, and 35% shading showed the best conditions for the early growth and cultivation of A. dioicus var. kamtschaticus.

Material Properties Evaluation of Cement Mortar Mixed with Organic/Inorganic Combined Water-repellent (유/무기 복합 발수제를 혼입한 모르타르의 재료특성 평가)

  • Kim, Wan-Su;Yoon, Chang-Bok;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.50-58
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    • 2020
  • When the concrete surface layer is damaged, The method of impregnating the concrete surface with a water repellent cannot secure the expected durability. Recently, various waterproofing and water-repellent materials were mixed into concrete or mortar to secure water repellency even inside cracks, but compressive strength was greatly reduced. In order to overcome the decrease in compressive strength, there has not yet been a study using the merits of organic and inorganic materials at the same time, so in this study, the physical properties and water repellency performance were evaluated by mixing an organic/inorganic composite water repellent appropriately mixed with an organic and inorganic material into the mortar. When mixed with organic/inorganic water repellent, the flow and air content were reduced by about 10% and 50% compared to the Liquid specimen. In the case of the P6L1 specimen, it was confirmed that the compressive strength decreased by about 3.5% compared to the non-mixed mortar at 39.5 MPa, the same as the existing water repellent, Powder. Water-repellent performance The organic-inorganic composite water repellent mixture specimen confirmed higher water repellency than the existing water repellent mixture powder, and the chloride penetration resistance evaluation result showed that the organic-inorganic composite water repellent mixture specimen reduced the passing charge by about 45% compared to the non-mixed mortar. In summary, it is judged that the P5L1 organic/inorganic composite water repellent mixed with a powder water repellent and a liquid water repellent in a ratio of 5:1 is the most reasonable to prevent the decrease in compressive strength and secure water repellency.