• Title/Summary/Keyword: Absorption pattern

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Two-Dimensional Arrays of Gold Nanoparticles for Plasmonic Nanosensor

  • Sim, Brandon;Monjaraz, Fernando;Lee, Yong-Joong;Park, So-Yeun
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.525-531
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    • 2011
  • Two dimensional (2D) arrays of noble metal nanoparticles are widely used in the sensing of nanoscale biological and chemical events. Research in this area has sparked considerable interest in many fields owing to the novel optical properties, e.g., the localized surface plasmon resonance, of these metallic nanoarrays. In this paper, we report successes in fabricating 2D arrays of gold nano-islands using nanosphere lithography. The reproducibility and the effectiveness of the nano-patterning method are tested by means of spin coating and capillary force deposition. We found that the capillary force deposition method was more effective for nanospheres with diameters greater than 600 nm, whereas the spin coating method works better for nanospheres with diameters less than 600 nm. The optimal deposition parameters for both methods were reported, showing about 80% reproducibility. In addition, we characterize gold nano-island arrays both geometrically with AFM as well as optically with UV-VIS spectrometry. The AFM images revealed that the obtained nano-arrays formed a hexagonal pattern of truncated tetrahedron nano-islands. The experimental and theoretical values of the geometric parameters were compared. The 2D gold nano-arrays showed strong LSPR in the absorption spectra. As the nano-islands increased in size, the LSPR absorption bands became red-shifted. Linear dependence of the plasmon absorption maximum on the size of the gold nano-islands was identified through the increment in the plasmon absorption maximum rate for a one nanometer increase in the characteristic length of the nano-islands. We found that the 2D gold nano-arrays showed nearly seven-fold higher sensitivity of the absorption spectrum to the size of the nano-islands as compared to colloidal gold nano-particles.

The Relationship Between Intestinal Iron Absorption and Hepatic Parenchymal Cell Damage (간실질세포(肝實質細胞)의 손상(損傷)이 철흡수(鐵吸收)에 미치는 영향(影響)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Kim, Mok-Hyun;Hahn, Shim-Suck
    • The Korean Journal of Nuclear Medicine
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    • v.5 no.2
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    • pp.19-40
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    • 1971
  • Since the iron balance is maintained by regulated intestinal absorption rather than regulated excretion, there have been many reports concerning the factors which may influence the intestinal iron absorption. As the liver is the largest iron storage organ of the body, any hepatocellular damage may result in disturbances in iron metabolism, e,g., frequent co-existence of hemochromatosis and liver cirrhosis, or elevated serum iron level and increased iron absorption rate in patients with infectious hepatitis or cirrhosis. In one effort to demonstrate the influence of hepatocellular damage on intestinal iron absortion, the iron absorption rate was measured in the rabbits whose livers were injured by a single subcutaneous injection of carbon tetrachloride (doses ranging from 0.15 to 0.5cc per kg of body weight) or by a single irradiation of 2,000 to 16,000 rads with $^{60}Co$ on the liver locally. A single oral dose of $1{\mu}Ci\;of\;^{59}Fe$-citrate with 0.5mg of ferrous citrate was fed in the fasting state, 24 hours after hepatic damage had been induced, without any reducing or chelating agents, and stool was collected for one week thereafter. Serum iron levels, together with conventional liver function tests, were measured at 24, 48, 72, 120 and 168 hours after liver damage had been induced. All animals were sacrificed upon the completing of the one week's test period and tissue specimens were prepared for H-E and Gomori's iron stain. Following are the results. 1. Normal iron absorption rate of the rabbit was $41.72{\pm}3.61%$ when 0.5mg of iron was given in the fasting state, as measured by subtracting the amount recovered in stool collected for 7 days from the amount given. The test period of 7 days is adequate, for only 1% of the iron given was excreted thereafter. 2. The intestinal iron absorption rate and serum iron level were significantly increased when the animal was poisoned by a single subcutaneous injection of 0.15cc. per kg. of body weight of carbon tetrachloride or more, or the liver was irradiated with a single dose of 12,000 rads or more. The results of liver function tests which were done simultaneously remained within normal limit except SGOT and SGPT which were somewhat increased. 3. In each case, there has been good correlation between the extent of liver cell damage and degree of increased iron absorption rate or serum iron level. 4. The method of liver damage appeared to make no obvious difference in the pattern of iron deposit in liver. This may be partly due to the fact that tissue specimens were obtained too late, for by this time the elevated serum iron level had returned within normal range and the pathological changes were almost healed. 5. The possible factors and relationship between intestinal iron absorption and hepatic parenchymal cell damage has been discussed.

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Optical Absorption Enhancement for Ultrathin c-Si Solar Cells using Ag Nanoparticle and Nano-hole Arrays (Ag 나노입자와 나노홀 배열구조를 이용한 초박형 단결정 Si 태양전지의 광흡수 증진)

  • Kim, Sujung;Cho, Yunae;Sohn, Ahrum;Kim, Dong-Wook
    • Current Photovoltaic Research
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    • v.4 no.2
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    • pp.64-67
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    • 2016
  • We investigated the influences of Ag nanoparticle (NP) arrays and surface nanohole (NH) patterns on the optical characteristics of 10-${\mu}m$-thick c-Si wafers using finite-difference time-domain (FDTD) simulations. In particular, we comparatively studied the plasmonic effects of both monomer arrays (MA) and heptamer arrays (HA) consisting of identical Ag NPs. HA improved the optical absorption of the c-Si wafers in much wider wavelength range than MA, with the help of hybridized plasmon modes. The light trapping capability of the NH array pattern is superior to that of the Ag plasmonic NPs. We also found that the addition of the Ag HA on the wafers with surface NH patterns further enhanced optical absorption: the expected short-circuit current density was as high as $34.96mA/cm^2$.

Fluorescence Analysis of Harmful Food Colors -Establishment of Fluorescence Assay Method by the Use of Filter Paper Adsorption- (유해성(有害性) 식품착색료(食品着色料)의 형광검사(螢光檢査) -여지흡착(濾紙吸着)을 이용한 형광분석법(螢光分析法)의 확립-)

  • Lee, Mie-Soon
    • Korean Journal of Food Science and Technology
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    • v.13 no.2
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    • pp.114-120
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    • 1981
  • A rapid and simple method for detecting colors was attempted on the basis of absorption and emission spectra of reflected light at $45^{\circ}$ angle from color-adsorbed filter paper illuminated by ultraviolet light through interference filter. Absorption spectra of prepared samples revealed more characteristic patterns than emission spectra. Detection of colors was readily accomplished by the investigation of wave length range, distribution pattern, the number of absorption bands and the degree of quenching.

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Physuical characteristics of crushed aggregates in Korea (한반도 산림골재의 물성특성)

  • 양동윤
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.1-11
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    • 1999
  • In the last decade, the supply of natural aggregates has been continuously increased due to the other types of aggregates. In general, aggregates constitute 70-80% of the total volume of concrete, so the quality of aggregates is main factor controlling physical characteristics of concrete. For this reason, physical properties of aggregate according to different rock types were studied. The majority of crushed aggregates is taken out of granite, gneiss, sandstone, andesite, basalt and so forth. The physical properties of these rock types were tested and most of them fell within the acceptable limit on the base of Korean standard regulation. The major lithology of the crushed aggregates is granite and gneiss, both of which are marked for more than 50% of total lithology thpes in Korea. A to the physical properties of granite, the high specific gravity coincides with low porosity, low absorption ratio, while the abrasion and soundness index show, in general, no specific trend. It has been assumed that slight differences of the physical properties of granite aggregates are related with those of the mineral composition, grain size, and so on. In comparison to granite, the physical properties of gneiss have little correlation one after another. This trend is related to different mineral composition, grain size and typical sheet fractures typically prevailing in the texture of gneiss. Spatial pattern of physical properties shows that high specific gravity of granite coincides only with low porosity and absorption ratio in all provinces except Cheolla province, and high specific gravity of gneiss coincides with low porosity and absorption ratio only in Cheolla and Gandwon provinces.

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Dyeing of PTT Fiber(1) - Effect of Heat Setting on Dyeing and Physical Properties of PTT Fiber - (PTT 섬유의 염색성 (1) - 열처리한 PTT 섬유의 염색성 및 물성 -)

  • 이두환;정동석;이문철
    • Textile Coloration and Finishing
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    • v.14 no.5
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    • pp.268-276
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    • 2002
  • Poly(trimethylene terephthalate)(PTT) and Poly(ethylene terephthalate)(PET) fibers were annealed at various temperatures ranging from $100^\circ{C}$ to $230^\circ{C}$ for 10 min under tension and tension free. Dyeing rates and absorption isotherms of both fibers were obtained with C.I. Disperse Red 60 at 100, 120 and $130^\circ{C}$ in water system. Also X-ray diffraction pattern, moisture regain and water absorption were investigated. The dyeing rate of PTT fiber is faster than PET fiber, and dyeing of PTT fiber begin at lower temperature compared to PET fiber. The absorption isotherms from both fibers with disperse dye we nearly linear up to the saturation dye uptake, which increase with dyeing temperature. Equilibrium dye uptake of PTT fiber annealed under tension above $180^\circ{C}$ was remarkably decreased because of a changes in the fine structure of fiber. The intensities of X-ray diffraction peaks of both annealed fibers were increased with increasing in annealed temperature. The reflections observed at $2\theta$=$15.8^\circ$, $24^\circ$ and $25.2^\circ$ were assigned reflection of crystal at the planes of (010), $(1\bar02,\;\bar112),\;and\;(\bar13,\; \bar113)$ respectively, and the peak became sharp with heat setting temperature.

A Study on the Real-Time Temperature and Concentration Measurement of Combustion Pipe Flow Field (연소 배관 유동장의 실시간 온도, 농도 측정에 관한 연구)

  • Hong, Jeong Woong;Yoon, Sung Hwan;Jeon, Min Gyu
    • Journal of the Korean Society of Visualization
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    • v.20 no.2
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    • pp.86-92
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    • 2022
  • Pipe failure due to thermal fatigue and environmental regulations are increasing the importance of pipe monitoring systems in industrial plants. Since most pipe monitoring systems are focus on external crack inspected, it is necessary to temperature and concentration measuring monitoring system inside the pipe. These systems have spatial uncertainty due to sample inspection by one-point measurement. In addition, real-time measurement is not possible due to the limitation of time delay due to contact measurement. In this study, CT-TDLAS (Computed tomography-Tunable diode laser absorption spectroscopy) apply to overcome the limitations of existing methods. Lasers exhibiting an absorption response at a wavelength of 1395 nm were arranged in a lattice pattern on measuring cell. It showed that the inside of the pipe changed to an unstable combustion state over time.

Investigations of Accelerated Aged Polymeric Insulators Using Partial Discharge Signal Measurement and Analysis

  • Mekala, K.;Chandrasekar, S.;Ravindran, R. Samson
    • Journal of Electrical Engineering and Technology
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    • v.10 no.1
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    • pp.299-307
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    • 2015
  • Reduction in pollution performance of polymeric insulators, aged due to water absorption stress and thermal stress, is a major threat to the reliable operation of power transmission and distribution system. Formation of partial discharges on the surface of wet polluted insulator plays a major role in determining the life time and pollution performance of outdoor polymeric insulators. However, reports on partial discharge characteristics of water absorption stress aged and thermal aged polymeric insulators are scanty. This paper discusses the pollution performance characteristics of accelerated aged polymeric insulators using the advanced ultra wide band PD signal measurement and analysis. Laboratory experiments on accelerated aged polymeric insulators were carried out as per IEC 60507 under AC voltage, at different humidity and contamination levels using NaCl as a contaminant. PRPD pattern and Time-Frequency map analysis of PD signals were carried out. From the results, it can be speculated that PD analysis is a well suited technique to understand the pollution performance of aged polymeric insulators.

Dyeing Properties of Nylon 6 Ultramicrofiber (나일론 6 초극세 섬유의 염색성)

  • ;;;Tomiji Wakida
    • Textile Coloration and Finishing
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    • v.14 no.6
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    • pp.319-327
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    • 2002
  • Nylon 6 ultramicrofiber(UMF, monodenier 0.074d) and regular staple fiber(monodenier 2.05d) were dyed with acid and disperse dyes to investigate the effect of the difference of the fiber fineness. Also X-ray diffraction pattern, birefringence, DSC thermogram, moisture regain and water absorption of these fibers are measured. The dyeing rate of nylon UMF with acid dyes is increased compared with that of regular fiber, but not increased for disperse dyes. Also the saturation dye uptake of UMF with acid dyes is higher than that of regular fiber, while it is unchanged for disperse dyes. The moisture regain of UMF is similar to the regular fiber, whereas the water absorption of UMF is two times th그n that of the regular fiber. The crystallinity percentage of UMF is higher than that of regular fiber.

A Study on Crashworthiness for Motorized Trailer of High Speed Train (고속전철 동력객차에 대한 충돌특성 연구)

  • Kim, Heon-Youog;Han, Jae-Hyung;Lee, Jong-Keun
    • Journal of the Korean Society for Railway
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    • v.2 no.1
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    • pp.16-27
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    • 1999
  • The purpose of this study is to suggest the effective analytical procedure using finite element model for the crashworthiness of motorized trailer of high speed train. The static crush of rectangular section frame is analyzed by experiment and numerical simulation. The equivalent thickness distribution of the aluminum frame ensuring the same energy absorption as the steel frame is obtained. In the analysis of end-on collision of TGV-K, deformed pattern and section forces are obtained, and the effect of crushable zone are examined. The numerical results are applied to the design of motorized trailer of Korean high speed train.

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