• 제목/요약/키워드: Absorption enhancement

검색결과 280건 처리시간 0.03초

IMPROVEMENT OF MICROWAVE ABSORPTION CHARACTERISTICS BY COATING LAYER IN SUBSTITUTED U-TYPE FERRITES

  • KWANG-PIL JEONG;JEONG-GON KIM;SU-WON YANG;JIN-HYUK CHOI;SEUNG-YOUNG PARK
    • Archives of Metallurgy and Materials
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    • 제65권4호
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    • pp.1287-1291
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    • 2020
  • The U-type ferrite is a kind of hexagonal ferrite, and it is known as a microwave absorber in the X-band. The magnetic and dielectric loss of the U-type ferrite change to the composition and coating layer, etc. In this study, the silicon oxide layer was coated on the substituted U-type ferrites to improve microwave absorption characteristics. The complex permittivity and complex permeability were measured using toroidal specimens that were press-molded and the measured frequency range was set from 2-18 GHz. The improvement of the microwave absorption rate was different according to the type of the substituted U-type ferrites. Only in the substituted U-type ferrites with nickel and zinc, an improvement in the microwave absorption rate due to enhancement of magnetic loss was confirmed. The highest microwave absorption was 99.9% at 9.6 GHz, which was S_Z0.5U.

속 이온과 CFP 상호작용: 흡수 형광 분광법에 의한 금속 이온과 CFP의 착물 형성 (Interaction of CFP with Metal ions: Complex Formation of CFP with Metal ion by Absorption and Fluorescence Spectrophotometery)

  • Siddiqi, K.S.;Mohd, Ayaz;Khan, Aftab Aslam Parwaz;Bano, Shaista
    • 대한화학회지
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    • 제53권2호
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    • pp.152-158
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    • 2009
  • 산성 용액에서 $Ca^{2+},\;Mg^{2+},\;Mn^{2+},\;Fe^{3+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+}$$Zn^{2+}$와 Cefpodoxime proxetil (CFP)의 상 호작용을 분광학적으로 조사한 결과 1:1 착물이 형성됨을 알 수 있다. 순수한 약품의 흡수스펙트럼은 270과 345 nm에서 두 개의 현저한 봉오리를 보였다. 여러 pH에서 스펙트럼은 두 개의 isosbestic 점(305 과 330 nm)을 나타내었다. 이는 용액상에서 약품의 쯔비터 이온이 존재함을 의미한다. 다른 농도의 금 속이온에서 CFP의 형광방출 스펙트럼은 chelating enhancement fluorescence(CHEF)효과에 의해 형광강 도가 증가함을 알 수 있었다. 착체의 화학량론은 Job’'s 와 Benesi-Hildebrand 방법에 의해 결정되었다. 착 체의 안정도는 다음 순서와 같다. $Ca^{2+}\;<\;Mg^{2+}\;<\;Co^{2+}\;<\;Ni^{2+}\;<\;Zn^{2+}\;<\;Mn^{2+}\;<\;Cu^{2+}\;<\;Fe^{3+}$.

Dissolution Characteristics of Hydrophobic Drug-Soluble Carrier Coprecipitate (I)-Enhanced Dissolution Rates of Furosemide from Furosemide Polymer Coprecipitates-

  • 신상철;이민화;우종학
    • Journal of Pharmaceutical Investigation
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    • 제6권3호
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    • pp.48-57
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    • 1976
  • An enhancement in the dissolution rate of the drug should facilitate its GI absorption if the absorption process is dissolution rate limited. One of the need for the techniques that can potentially enhance the dissolution rate and extent of absorption of hydrophobic drugs is the formation of coprecipitates with pharmacologically inert, polymeric materials. The physicochemical modification offers the advantage of possibly enabling one to administer the drug orally in a form from which it is most available for GI absorption. Several $investigation^{1-15)}$ demonstrated that the formation of solid dispersions or coprecipitates of relatively water-insoluble drugs with various pharmacologically inert carriers can increase singnificantly their in vitro dissolution rates. However, little information is available in the literature related to the dissolution rate patterns of furosemide, a water-insoluble diurectices, with respect to the sort of copolymer and the ratio of coprecipitates as a function of time, respectively. The purpose of the present investigation was to ascertain, the general applicability of the copolymers to use fore more fast, enhanced dissolution techniques of furosemide. To accomplish the need for enhancement in the dissolution rate of furosemide, varying ratio coprecipitates with different water-soluble polymers, such as polyvinylpyrrolidone (PVP), polyethylene glycol 4000(PEG 4000), and polyethylene glycol 6000 (PEG 6000), were quantitatively studied by comparing their dissolution characteristics of furosemide. The dissolution patterns of pure furosemide, varying ratio furosemide-PVP coprecipitates, (1:2, 1:5, and 1:9(w/w)), furosemide-PEG 4000 coprecipitates (1:4, 1:9, and 1:19(w/w), furosemide-PEG 6000 coprecipitates(1:4, 1:9, and 1:19(w/w)), and the same ratio physical mixtures, respectively, were compared by the amount dissolved as a function of time.

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Plasmonic Enhanced Light Absorption by Silver Nanoparticles Formed on Both Front and Rear Surface of Polycrystalline Silicon Thin Film Solar Cells

  • Park, Jongsung;Park, Nochang;Varlamov, Sergey
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.493-493
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    • 2014
  • The manufacturing cost of thin-film photovoltics can potentially be lowered by minimizing the amount of a semiconductor material used to fabricate devices. Thin-film solar cells are typically only a few micrometers thick, whereas crystalline silicon (c-Si) wafer solar cells are $180{\sim}300\mu}m$ thick. As such, thin-film layers do not fully absorb incident light and their energy conversion efficiency is lower compared with that of c-Si wafer solar cells. Therefore, effective light trapping is required to realize commercially viable thin-film cells, particularly for indirect-band-gap semiconductors such as c-Si. An emerging method for light trapping in thin film solar cells is the use of metallic nanostructures that support surface plasmons. Plasmon-enhanced light absorption is shown to increase the cell photocurrent in many types of solar cells, specifically, in c-Si thin-film solar cells and in poly-Si thin film solar cell. By proper engineering of these structures, light can be concentrated and coupled into a thin semiconductor layer to increase light absorption. In many cases, silver (Ag) nanoparticles (NP) are formed either on the front surface or on the rear surface on the cells. In case of poly-Si thin film solar cells, Ag NPs are formed on the rear surface of the cells due to longer wavelengths are not perfectly absorbed in the active layer on the first path. In our cells, shorter wavelengths typically 300~500 nm are also not effectively absorbed. For this reason, a new concept of plasmonic nanostructure which is NPs formed both the front - and the rear - surface is worth testing. In this simulation Al NPs were located onto glass because Al has much lower parasitic absorption than other metal NPs. In case of Ag NP, it features parasitic absorption in the optical frequency range. On the other hand, Al NP, which is non-resonant metal NP, is characterized with a higher density of conduction electrons, resulting in highly negative dielectric permittivity. It makes them more suitable for the forward scattering configuration. In addition to this, Ag NP is located on the rear surface of the cell. Ag NPs showed good performance enhancement when they are located on the rear surface of our cells. In this simulation, Al NPs are located on glass and Ag NP is located on the rear Si surface. The structure for the simulation is shown in figure 1. Figure 2 shows FDTD-simulated absorption graphs of the proposed and reference structures. In the simulation, the front of the cell has Al NPs with 70 nm radius and 12.5% coverage; and the rear of the cell has Ag NPs with 157 nm in radius and 41.5% coverage. Such a structure shows better light absorption in 300~550 nm than that of the reference cell without any NPs and the structure with Ag NP on rear only. Therefore, it can be expected that enhanced light absorption of the structure with Al NP on front at 300~550 nm can contribute to the photocurrent enhancement.

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Enhancement of Heat and Mass Transfer by Insert Spring in a Vertical Absorber with Surfactant

  • Yoon, Jung-In;Choi, Kwang-Hwan;Moon, Choon-Geun;Sarker M.M.A;Kwon, Oh-Kyung
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권8호
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    • pp.1239-1250
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    • 2004
  • This research was concerned with the enhancement of heat transfer by surfactant added to the aqueous solution of LiBr. Different vertical tubes were tested with and without an additive of normal octyl alcohol. The test tubes are a bare inner surface. a groove inner surface, a corrugated inner surface and a spring inserted inner surface tubes. The additive concentration was about 0.08 mass%. The heat transfer coefficient was measured as a function of the film Reynolds number in the range of 20~200. Experiments were carried out at higher cooling water temperature of $35^{\circ}C$ to simulate an air cooling condition for several kinds of absorber testing tubes. The experimental results were compared with and without surfactant. The enhancement of heat transfer by Marangoni convection effect which was generated by addition of the surfactant is observed in each test tube. Especially, it is clarified that the tube with an inserted spring has the highest enhancement effect.

마랑고니 대류에 미치는 불응축성가스의 영향 (Noncondensable Gas Effects on the Marangoni Convection)

  • 이동호
    • 설비공학논문집
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    • 제8권4호
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    • pp.510-518
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    • 1996
  • The study presents experimental and theoretical analysis focusing on the infulence of a noncondensable gas upon the absorption enhancement that is obtained by Marangoni convection generated by the addition of the surfactant. The shadowgraph method is adopted in this visualization. As a result of absorption phenomena with shadowgraph photos, the different patterns of Marangoni convection cells are observed in accordance with the various amounts of noncondensable gas. Furthermore, non dimensional number K(Ma/Ra) is introduced to calculate the value of surface tension difference theoretically for the comparison with the various amount of non condensable gas in absorber.

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스프링삽입형 유하액막식 흡수기의 열 및 물질전달 특성 (Characteristics of Heat and Mass Transfer for a Falling Film Type Absorber with Insert Spring Tubes)

  • 윤정인;오후규;백목효부
    • 대한기계학회논문집
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    • 제19권6호
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    • pp.1501-1509
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    • 1995
  • It is known that the heat and mass transfer characteristics in the absorber are most sensitive of the temperature boost of all the heat exchangers and the development of a more efficient absorber should be highly important. This paper describes absorption experiments made with different inside tube diameters, tube length and tube shapes. The purpose of this study is to acquire basic knowledge about heat and mass transfer in a falling film type absorber with vertical inner tubes. Heat and mass transfer were measured for water vapor absorption into a Lithium Bromide-water solution flowing down an absorber of vertical inner tubes. As a result, insert spring tube compares bare tube and heat transfer improved by order of insert spring tube P2(pitch 20 mm) and P1(pitch 10 mm).

수직 흡수전열관의 흡수성능에 미치는 스프링의 영향 (Influence of Spring on The Absorption Performance of a Vertical Absorber Tube)

  • 김정국;조금남
    • 설비공학논문집
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    • 제14권10호
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    • pp.825-832
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    • 2002
  • The present study investigated the enhancement of the absorption performance by the spring wrapped around the outer surface of the vertical falling film absorber tube. Heat and mass transfer enhancements were experimentally investigated, and flow visualization was performed to observe the wettability and flow pattern of the solution. The key experimental parameters were spring diameter (0.5, 1.0 mm) and spring pitch (1, 3, 10 mm), film Reynolds number (50~150), and concentration of LiBr-$H_2O$ solution (55, 60, 65 wt%). As the spring diameter was increased, the absorption mass flux, Sherwood number, Nusselt number, heat flux, and heat transfer coefficient were increased The Nusselt and Sherwood numbers showed the maximum at the spring pitch of 3mm, and the ratio of pitch to diameter of approximately 3 and 6 for the spring diamter of 0.5 mm, respectively.

Enhancement of Dye-Sensitized Solar Cell Efficiency by Spherical Voids in Nanocrystalline ZnO Electrodes

  • Hieu, Hoang Nhat;Dao, Van-Duong;Vuong, Nguyen Minh;Kim, Dojin;Choi, Ho-Suk
    • 한국재료학회지
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    • 제24권9호
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    • pp.458-464
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    • 2014
  • Light scattering enhancement is widely used to enhance the optical absorption efficiency of dye-sensitized solar cells. In this work, we systematically analyzed the effects of spherical voids distributed as light-scattering centers in photoanode films made of an assembly of zinc oxide nanoparticles. Spherical voids in electrode films were formed using a sacrificial template of polystyrene (PS) spheres. The diameter and volume concentration of these spheres was varied to optimize the efficiency of dye-sensitized solar cells. The effects of film thickness on this efficiency was also examined. Electrochemical impedance spectroscopy was performed to study electron transport in the electrodes. The highest power conversion efficiency of 4.07 % was observed with $12{\mu}m$ film thickness. This relatively low optimum thickness of the electrode film is due to the enhanced light absorption caused by the light scattering centers of voids distributed in the film.